scholarly journals Cinétique de la formation de la métalloporphyrine Cu(II) – hématoporphyrine IX dans l'acide acétique aqueux

1975 ◽  
Vol 53 (16) ◽  
pp. 2375-2380 ◽  
Author(s):  
Guy Paquette ◽  
Miklos Zador
Keyword(s):  
Acetic Acid ◽  
Reactive Species ◽  
Acid Water ◽  
First Order ◽  
Water Solvent ◽  
Acetic Acid Water ◽  
Kinetics Of ◽  
Hematoporphyrin Ix ◽  
Mechanism Of The Reaction

The kinetics of interaction of hematoporphyrin IX with Cu(II) has been studied in an acetic acid – water solvent (50%–50% v/v). The reaction is of first order with respect to the porphyrin whereas the order with respect to copper(II) perchlorate is smaller than one. This is explained by taking into account the interaction between Cu2+ and acetic acid. The reactive species are Cu2+, CuOAc+, and free porphyrin. The mechanism of the reaction is compared to those proposed for similar systems.

Solubilities of Benzoic Acid and Phthalic Acid in Acetic Acid + Water Solvent Mixtures

2007 ◽  
Vol 52 (3) ◽  
pp. 936-940 ◽  
Author(s):  
Qinbo Wang ◽  
Linxi Hou ◽  
Youwei Cheng ◽  
Xi Li
Keyword(s):  
Acetic Acid ◽  
Benzoic Acid ◽  
Phthalic Acid ◽  
Acid Water ◽  
Solvent Mixtures ◽  
Water Solvent ◽  
Acetic Acid Water

ChemInform Abstract: KINETICS OF OXIDATION OF XYLENES BY CERIC AMMONIUM NITRATE IN ACETIC ACID-WATER MIXTURES

1979 ◽  
Vol 10 (14) ◽  
Author(s):  
R. KULANDAIVEL ◽  
S. NARASIMHAN ◽  
S. SUNDARAM ◽  
N. VENKATSUBRAMANIAN
Keyword(s):  
Acetic Acid ◽  
Ammonium Nitrate ◽  
Ceric Ammonium Nitrate ◽  
Acid Water ◽  
Kinetics Of Oxidation ◽  
Acetic Acid Water ◽  
Kinetics Of

Solubilities of 2,5-Furandicarboxylic Acid in Binary Acetic Acid + Water, Methanol + Water, and Ethanol + Water Solvent Mixtures

2018 ◽  
Vol 63 (6) ◽  
pp. 1987-1993 ◽  
Author(s):  
Heng Ban ◽  
Teng Pan ◽  
Youwei Cheng ◽  
Lijun Wang ◽  
Xi Li
Keyword(s):  
Acetic Acid ◽  
Acid Water ◽  
Solvent Mixtures ◽  
Water Solvent ◽  
Acetic Acid Water ◽  
Furandicarboxylic Acid

Solubility ofN-Hydroxyphthalimide in Binary Acetic Acid + Water Solvent Mixtures at (293.2 to 363.2) K

2007 ◽  
Vol 52 (3) ◽  
pp. 1025-1027 ◽  
Author(s):  
Youwei Cheng ◽  
Qinbo Wang ◽  
Lijun Wang ◽  
Xi Li
Keyword(s):  
Acetic Acid ◽  
Acid Water ◽  
Solvent Mixtures ◽  
Water Solvent ◽  
Acetic Acid Water

The Kinetics of an Acid Catalyzed Aromatic Cyclodehydration Reaction in Acetic Acid-Water Mixtures

1960 ◽  
Vol 82 (11) ◽  
pp. 2669-2670 ◽  
Author(s):  
L. K. Brice ◽  
R. D. Katstra
Keyword(s):  
Acetic Acid ◽  
Acid Water ◽  
Acetic Acid Water ◽  
Acid Catalyzed ◽  
Kinetics Of

Kinetics and Mechanism of Ligand Substitutionin Triglycinatovanadium(III) by EDTA and NTA in Aqueous Solutions

1994 ◽  
Vol 59 (5) ◽  
pp. 1077-1085
Author(s):  
Yasuhisa Ikeda ◽  
Refat M. Hassan ◽  
Moustafa M. Abd El-Fattah ◽  
Yul Y. Park ◽  
Hiroshi Tomiyasu
Keyword(s):  
Ionic Strength ◽  
Aqueous Solutions ◽  
Kinetic Parameters ◽  
Ligand Substitution ◽  
Reactive Species ◽  
Constant Ionic Strength ◽  
Substitution Reactions ◽  
First Order ◽  
Kinetics Of ◽  
Mechanism Of The Reaction

The kinetics of ligand substitution reactions in triglycinatovanadium(III) by EDTA and NTA as multidentate ligands were investigated at a constant ionic strength of 2.5 mol dm-3 spectrophotometrically. The substitutions were second-order reactions, first order in both reactants. Their rate could be expressed in the form r = k [V(gly)3] [EDTA(NTA)] where k = 2.62 .10-2 and 6.96 .10-2 mol-1 dm3 s-1 at 25 °C for EDTA and NTA, respectively. The results obtained at different pH indicated that [H2edta]2- and [Hnta]2- ions were the most reactive species in the substitution. Kinetic parameters have been evaluated and a tentative mechanism of the reaction has been proposed.

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