Partial molal volumes of organic compounds in carbon tetrachloride. V. Cyclic alkanes, ethers, alcohols, ketones, and bromides
1979 ◽
Vol 57
(22)
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pp. 2892-2894
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The partial molal volumes [Formula: see text] or 47 mono- or polycyclic alkanes, ethers, alcohols, ketones, and bromides have been determined in carbon tetrachloride at 25 °C. [Formula: see text] of most of these compounds can be calculated with moderate (±1–2%) accuracy using an equation containing parameters previously developed for acyclic compounds, and an additional cyclization parameter C, which is roughly linear with the number n of atoms in the ring, from n = 3 (C = +5.3 mL mol−1) to n = 10 (C = −21.0 mL mol−1). Substituted cyclohexanols and some polyfunctional compounds had [Formula: see text] considerably lower than calculated.
1979 ◽
Vol 44
(6)
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pp. 950-953
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1978 ◽
Vol 82
(21)
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pp. 2310-2313
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1979 ◽
Vol 57
(19)
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pp. 2585-2592
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1979 ◽
Vol 57
(22)
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pp. 2887-2891
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1979 ◽
Vol 83
(3)
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pp. 419-422
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Keyword(s):
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