Thermodynamic behaviour of adenosine in water–DMSO mixtures in the presence of K+ and Ca2+ ions at 25, 30, 35, and 40 °C

1985 ◽  
Vol 63 (6) ◽  
pp. 1180-1184 ◽  
Author(s):  
Anil K. Puri
Keyword(s):  
Transition State ◽  
Viscous Flow ◽  
Molar Volume ◽  
Partial Molar Volume ◽  
Activation Parameters ◽  
Volume Formula ◽  
Thermodynamic Behaviour ◽  
Partial Molar Compressibility ◽  
Viscosity B Coefficient ◽  
B Coefficients

Partial molar volume [Formula: see text] partial molar compressibility [Formula: see text] Jones–Dole viscosity B coefficient, and solute activation parameters of adenosine in water–DMSO mixtures in the presence of Ca2+ and K+ ions have been calculated from ultrasonic, volumetric, and viscometric studies at 25, 30, 35, and 40 °C(± 0.01° C). The results are discussed in terms of the Jones–Dole viscosity B coefficients and the transition state parameters for viscous flow.

scholarly journals Apparent molar volume and coefficients of Jones-Dole equation for the evaluation of ion- solvent interactions of barium chloride in aqueous 1, 4-dioxane and ethylene glycol solutions at T= (298.15 K to 313.15) K and at atmospheric pressure

2020 ◽  
Vol 10 (4) ◽  
pp. 5901-5909 ◽  
Keyword(s):  
Ethylene Glycol ◽  
Molar Volume ◽  
Apparent Molar Volume ◽  
Activation Parameters ◽  
Barium Chloride ◽  
State Theory ◽  
Viscosity Data ◽  
Solvent Interactions ◽  
Viscosity B Coefficient ◽  
The Given

The viscosity and density of barium chloride have been measured at T= (298.15-313.15) K in aqueous solutions of 1, 4-Dioxane (1,4-DO) and Ethylene glycol (EG). Jones–Dole equation was used to analyze the viscosity data. The apparent molar volume, V_ϕ limiting apparent molar volume, V_ϕ^0 are calculated from the density data. Limiting apparent molar expansibilities, E_ϕ^0 have been used to describe the temperture dependency of V_ϕ^0. The standard volume of transfer, ΔtV_ϕ^0 and viscosity B-coefficient of transfer, ΔtB of barium chloride from water to aqueous 1, 4-DO and EG solutions were systematizing the different types of interactions in the given solutions. The structure making and breaking capacity of solute in solutions was interpreted with the help of Helper equation. The positive value of (∂2V_ϕ^0/∂T2)p suggests the structure making nature for BaCl2 in given solution. It is observed that Friedman-Krishnan co-sphere model explains the increase in the transfer volume of BaCl2 with an increase in 1,4-DO and EG concentrations. The activation parameters of the viscous flow of the given solutions were calculated and interpreted using transition state theory.

scholarly journals Effect of 1-Octyl-3-Methylimidazolium Salicylate as an Active Pharmaceutical Ingredient (API-IL) on the Thermodynamic Behavior of Aqueous Glycine Solutions at T= 298.15 K

2019 ◽  
Vol 25 (2) ◽  
pp. 154-164
Author(s):  
Hemayat Shekaari ◽  
Mohammed Taghi Zafarani-Moattar ◽  
Seyyedeh Narjes Mirheydari ◽  
Elnaz Mazaher Haji Agha
Keyword(s):  
Ionic Liquid ◽  
Molar Volume ◽  
Partial Molar Volume ◽  
Speed Of Sound ◽  
Active Pharmaceutical Ingredient ◽  
Isentropic Compressibility ◽  
Refractive Indices ◽  
Partial Molar Isentropic Compressibility ◽  
Volume Of Transfer ◽  
B Coefficients

Background: The thermophysical properties of 1-octyl-3-methylimidazolium salicylate as an active pharmaceutical ingredient based on ionic liquid have been investigated in the presence of aqueous solutions of glycine. Therefore, the scope of this article was to determine these properties by measuring the densities, speeds of sound, viscosities, electrical conductances and refractive indices for ternary (glycine + 1-octyl-3-methylimidazolium salicylate + water) soloutions at T = 298.15 K. Methods: A commercial density and speed of sound measurement apparatus was used to measure the density and speed of sound data. Viscosities, electrical conductivities and refractive indices of the studied solutions were measured using digital viscometer, conductivity meter and refractometer, respectively. Results: Variety of properties such as partial molar volume of transfer ∆traV0ϕ, partial molar isentropic compressibility of transfer ∆traK0ϕ, viscosity B-coefficients of transfer ∆traB, ion association constants (KA) and molar refraction RD were determined to investigate the solute-solute and solute-solvent interactions in these systems. Conclusion: The positive values of transfer properties including partial molar volume of transfer (∆traV0ϕ), partial molar isentropic compressibility of transfer (∆traK0ϕ), and viscosity B-coefficients of transfer (∆traB) indicated that in these systems, the ion-polar and polar-polar interactions are dominant. The calculated hydration number showed that dehydration of glycine occurs in presence of this ionic liquid.

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