Impedance Spectroscopy of Composite Materials

Author(s):  
Rosario A. Gerhardt
2012 ◽  
Vol 730-732 ◽  
pp. 367-372
Author(s):  
Robert Silva ◽  
Pedro M. Faia ◽  
Mario J. Santos ◽  
A.R. Ferreira ◽  
C.S. Furtado

With the study of composite materials based on the TiO2-ZnO pair, we look for better sensitivity and selectivity to the gases, than those of the sensors made out of only one of those metal oxides. This would be due to the fact that some of the interstitial positions that were initially occupied by the atoms of one of the metals are now occupied by atoms of the other metal: if the single covalent/ionic adsorption is decisive in the observed changes in the materials conductivity, then the electronegativity of the occupying metal atoms may be used to regulate the sensitivity and selectivity. We will present the results obtained for pelletized sensors of the pair TiO2-ZnO, with a 85:15 % volume mol ratio of Titanium and Zinc, sintered at 400º and 500°C. The rather involved behaviour of our sensors is understood by measuring their complex impedance subjected to an external sinusoidal varying electric field, which is being applied in the presence of different relative humidities, at various working temperatures. The main goal of this work here described is the study of the relative humidity influence on the sensing properties of the composite sensors, and the development of an electrical model for the sensor electrical response.


2020 ◽  
Vol 7 (1) ◽  
pp. 17-25
Author(s):  
A. A. Levina ◽  
N. O. Tadevosyan ◽  
S. A. Petrova ◽  
E. S. Buyanova ◽  
M. V. Morozova

During the study of the phase formation process in Ca-R-Nb-M-O systems (R=La, Bi, M=Mo, W), an attempt was made to obtain single-phase compounds of CaRNbMO8 composition by the standard ceramic technique. In addition, samples based on LaNbO4, CaWO4, BiNbO4 were also synthesized by the standard ceramic technique. The phase composition of the samples was studied by XRD analysis. The electrical conductivity of the obtained solid solutions and potential composite materials was investigated by impedance spectroscopy.


2012 ◽  
Vol 11 (6) ◽  
pp. 671-683 ◽  
Author(s):  
Matthieu Gresil ◽  
Lingyu Yu ◽  
Victor Giurgiutiu ◽  
Michael Sutton

Author(s):  
R.R. Russell

Transmission electron microscopy of metallic/intermetallic composite materials is most challenging since the microscopist typically has great difficulty preparing specimens with uniform electron thin areas in adjacent phases. The application of ion milling for thinning foils from such materials has been quite effective. Although composite specimens prepared by ion milling have yielded much microstructural information, this technique has some inherent drawbacks such as the possible generation of ion damage near sample surfaces.


Author(s):  
K.P.D. Lagerlof

Although most materials contain more than one phase, and thus are multiphase materials, the definition of composite materials is commonly used to describe those materials containing more than one phase deliberately added to obtain certain desired physical properties. Composite materials are often classified according to their application, i.e. structural composites and electronic composites, but may also be classified according to the type of compounds making up the composite, i.e. metal/ceramic, ceramic/ceramie and metal/semiconductor composites. For structural composites it is also common to refer to the type of structural reinforcement; whisker-reinforced, fiber-reinforced, or particulate reinforced composites [1-4].For all types of composite materials, it is of fundamental importance to understand the relationship between the microstructure and the observed physical properties, and it is therefore vital to properly characterize the microstructure. The interfaces separating the different phases comprising the composite are of particular interest to understand. In structural composites the interface is often the weakest part, where fracture will nucleate, and in electronic composites structural defects at or near the interface will affect the critical electronic properties.


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