IN SITU SYNTHESIS OF CORAL-LIKE MELAMINE FORMALDEHYDE RESINS/CARBON NANOTUBES MICROPARTICLES

2017 ◽  
Vol 24 (Supp02) ◽  
pp. 1850021
Author(s):  
SHAOYAN MOU ◽  
YONG JIANG
Keyword(s):  
Carbon Nanotubes ◽  
Thermal Stability ◽  
Growth Process ◽  
In Situ Polymerization ◽  
In Situ Synthesis ◽  
Composite Particles ◽  
The Novel ◽  
Melamine Formaldehyde ◽  
Good Thermal Stability

A kind of coral-like melamine formaldehyde resins/carbon nanotubes (MF/CNTs) composite particles were prepared via in situ polymerization, which showed good thermal stability under 450[Formula: see text]C. To illustrate the mechanism of the polymer growth process, silica/CNTs were also prepared via the same method to achieve a contrast. Generally, two models were used to illustrate silica growth mechanism, the monomer addition one and the controlled aggregation one. We preferred that the monomer addition model could explain the growth of the novel coral-like MF/CNTs particles.

Preparation and Properties of Polyimide/MWNTs-COOH Antistatic Composites

2014 ◽  
Vol 893 ◽  
pp. 241-244
Author(s):  
Yong Hui Lv ◽  
Bao Xiang Deng
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Thermal Stability ◽  
Acid Treatment ◽  
In Situ Polymerization ◽  
Composite Films ◽  
Good Thermal Stability ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

The acidified multi-walled carbon nanotubes (MWNTs-COOH) was obtained by nitric acid treatment on multi-walled carbon nanotubes (MWNTs).The PI/MWNTs-COOH composite films were synthesized by in situ polymerization. The thermal stability, resistance and mechanical properties of PI/MWNTs-COOH composite were evaluated. The results showed that: the composites maintained a good thermal stability with the addition of the MWNTs-COOH; the resistance of the composite film dropped at first, and rose up later. While the tensile strength increased at first and then decreased. In conclusion, the PI/MWNTs-COOH composite films exhibited better thermal, antistatic and mechanical properties compared with neat PI.

Improved dispersion of multi-wall carbon nanotubes in poly(butylene terephthalate) using benzimidazolium surfactants

e-Polymers ◽  
2009 ◽  
Vol 9 (1) ◽  
Author(s):  
Martino Colonna ◽  
Corrado Berti ◽  
Enrico Binassi ◽  
Maurizio Fiorini ◽  
Francesco Acquasanta ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Thermal Stability ◽  
In Situ Polymerization ◽  
Nucleation Process ◽  
Imidazolium Salt ◽  
Butylene Terephthalate ◽  
Multi Wall Carbon Nanotubes ◽  
Benzimidazolium Salt

AbstractMulti-wall carbon nanotubes/poly(butylene terephthalate) nanocomposites have been prepared by in-situ polymerization. Benzimidazolium tetrafluoroborate salts improve the dispersion of carbon nanotubes in the polymer matrix due to the formation of “π-cation” interactions of the imidazolium salt with the surface of the carbon nanotubes. An improved dispersion of the nanotubes in butanediol was also observed using the benzimidazolium salt. The presence of the compatibilization agent gives rise to improved thermo-mechanical properties and electrical conductivity for the nanocomposite. The presence of the nanotubes also consistently increases the thermal stability and enhances the nucleation process on PBT crystallization.

In-situ synthesis of a novel CaO·4B2O3 · 2H2O–SiO2 nanocomposite and its influence on mechanical property and flame retardancy of polypropylene

2020 ◽  
Vol 10 (2) ◽  
pp. 225-230
Author(s):  
Ping Li ◽  
Hong-Hong Yan ◽  
Zhi-Hong Liu
Keyword(s):  
Mechanical Property ◽  
Thermal Stability ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
In Situ Synthesis ◽  
Physical Mixture ◽  
Fire Performance ◽  
Good Thermal Stability ◽  
Ft Ir

A novel CaO·4B2O3·2H2O–SiO2 nanocomposite with good thermal stability has been in situ synthesized, in which the SiO2 nanospheres are supported on the CaO·4B2O3·2H2O nanosheets. As a comparison, single CaO·4B2O3 ·2H2O nanosheet with the thickness of 100 nm, single SiO2 nanosphere with the diameter of about 100 nm, and their physical mixture were also prepared, respectively. On the basis of characterizations of XRD, FT-IR, TGA, SEM and TEM, the fire performance of CaO·4B2O3 ·2H2O–SiO2 nanocomposite to polypropylene was studied. It is demonstrated that the flame retardancy of prepared sample was prominently stronger than those of single CaO·4B2O3 ·2H2O nanosheet and their physical mixture. Furthermore, the mechanical property of polypropylene/CaO·4B2O3·2H2O–SiO2 composite was also assessed. The possible formation mechanism of the nanocomposite and its flame-retardant mechanism were put forward. It has prospect as possible flame retardant to polypropylene and other polymers.

In situ synthesis of iron-filled nitrogen-doped carbon nanotubes and their magnetic properties

Carbon ◽  
2013 ◽  
Vol 61 ◽  
pp. 647-649 ◽  
Author(s):  
Qingze Jiao ◽  
Liang Hao ◽  
Qingyan Shao ◽  
Yun Zhao
Keyword(s):  
Carbon Nanotubes ◽  
Magnetic Properties ◽  
In Situ Synthesis ◽  
Nitrogen Doped ◽  
Nitrogen Doped Carbon

scholarly journals In situ synthesis of metal embedded nitrogen doped carbon nanotubes as an electrocatalyst for the oxygen reduction reaction with high activity and stability

RSC Advances ◽  
2018 ◽  
Vol 8 (44) ◽  
pp. 25051-25056 ◽  
Author(s):  
Yanhong Yin ◽  
Hengbo Zhang ◽  
Rongzhen Gao ◽  
Aili Wang ◽  
Xinxin Mao ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
High Activity ◽  
Reduction Reaction ◽  
In Situ Synthesis ◽  
Nitrogen Doped ◽  
Nitrogen Doped Carbon

In this work, a Co–N doped carbon nanotube (CNT) catalyst was fabricated via a simple pyrolysis approach.

scholarly journals In situ synthesis of MWCNT-graft-polyimides: thermal stability, mechanical property and thermal conductivity

RSC Advances ◽  
2020 ◽  
Vol 10 (23) ◽  
pp. 13517-13524
Author(s):  
Chunbo Wang ◽  
Bing Cong ◽  
Junyu Zhao ◽  
Xiaogang Zhao ◽  
Daming Wang ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Mechanical Property ◽  
Thermal Stability ◽  
In Situ Synthesis ◽  
Enhanced Thermal Conductivity

In situ synthesis of MWCNT-graft-polyimides enhanced thermal conductivity at a relatively low loading.

Synthesis of superhydrophobic silica nanofibrous membranes with robust thermal stability and flexibility via in situ polymerization

Nanoscale ◽  
2012 ◽  
Vol 4 (20) ◽  
pp. 6581 ◽  
Author(s):  
Liping Yang ◽  
Aikifa Raza ◽  
Yang Si ◽  
Xue Mao ◽  
Yanwei Shang ◽  
...  
Keyword(s):  
Thermal Stability ◽  
In Situ Polymerization ◽  
Nanofibrous Membranes ◽  
Superhydrophobic Silica

scholarly journals Thermodynamically stable [4 + 2] cycloadducts of lanthanum-encapsulated endohedral metallofullerenes

2014 ◽  
Vol 10 ◽  
pp. 714-721 ◽  
Author(s):  
Yuta Takano ◽  
Yuki Nagashima ◽  
M Ángeles Herranz ◽  
Nazario Martín ◽  
Takeshi Akasaka
Keyword(s):  
Thermal Stability ◽  
Material Science ◽  
Molecular Structures ◽  
Spectroscopic Methods ◽  
Dynamic Nmr ◽  
The Novel ◽  
Endohedral Metallofullerenes ◽  
Derivatives Of ◽  
Paramagnetic Properties

The [4 + 2] cycloaddition of o-quinodimethanes, generated in situ from the sultine 4,5-benzo-3,6-dihydro-1,2-oxathiin 2-oxide and its derivative, to La metal-encapsulated fullerenes, La2@C80 or La@C82, afforded the novel derivatives of endohedral metallofullerenes (3a,b, 4a,b and 5b). Molecular structures of the resulting compounds were elucidated using spectroscopic methods such as MALDI–TOF mass, optical absorption, and NMR spectroscopy. The [4 + 2] adducts of La2@C80 (3a,b, and 4a,b) and La@C82 (5b), respectively, retain diamagnetic and paramagnetic properties, as confirmed by EPR spectroscopy. Dynamic NMR measurements of 4a at various temperatures demonstrated the boat-to-boat inversions of the addend. In addition, 5b revealed remarkable thermal stability in comparison with the reported [4 + 2] cycloadduct of pentamethylcyclopentadiene and La@C82 (6). These findings demonstrate the utility of sultines to afford thermodynamically stable endohedral metallofullerene derivatives for the use in material science.

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