Growth and luminescence properties of Pr3+-doped LaCl3 single crystal
A transparent LaCl3:Pr[Formula: see text] single crystal with a dimension of [Formula: see text] [Formula: see text][Formula: see text]mm was grown by vertical Bridgman method. The differential scanning calorimetry (DSC) shows that the melting point of LaCl3:Pr[Formula: see text] crystal is about 841.5[Formula: see text]C. The powder X-ray diffraction (XRD) pattern proves the crystal structure of LaCl3:Pr[Formula: see text] is hexagonal with space group P63/m. There is a dominant peak centered at 335[Formula: see text]nm and a weaker peak located at 400[Formula: see text]nm under X-ray excitation, while three peaks located at 335[Formula: see text]nm, 356[Formula: see text]nm and 400[Formula: see text]nm under ultra-violet. The peaks of 335[Formula: see text]nm and 356[Formula: see text]nm can be ascribed to the transition of 5d–4f of Pr[Formula: see text], while the 400[Formula: see text]nm maybe related to LaCl3 host. Decay times were fitted to be about 14.5[Formula: see text]ns for 335[Formula: see text]nm, 14.6[Formula: see text]ns for 356[Formula: see text]nm and 1.3[Formula: see text]ns for 400[Formula: see text]nm. The experimental results show that the LaCl3:Pr[Formula: see text] crystal will be a promising scintillator.