Mechanochemical synthesis of Li2OHI with enhanced lithium ionic conductivity

2021 ◽  
pp. 2150012
Author(s):  
Yaqi Jing ◽  
Runtao Yang ◽  
Zhi Deng ◽  
Lei Gao ◽  
Shuai Li ◽  
...  
Keyword(s):  
High Temperature ◽  
Ball Milling ◽  
Eutectic Reaction ◽  
Lithium Ion ◽  
Phase Segregation ◽  
Lithium Hydroxide ◽  
Melting Points ◽  
Mechanochemical Method ◽  
Conductive Materials ◽  
Lithium Ion Conductivity

Lithium hydroxide halides, as a family of lithium-ion conductive materials, have a promising potential on the application of solid state electrolytes. In this work, we have synthesized orthohombic Li2OHI through a facile mechanochemical method. The obtained sample exhibits a higher lithium-ion conductivity than solid sintering, which can be attributed to the high purity and crystallinity obtained from ball milling. Ball milling can avoid the phase segregation of Li2OHI at high temperature and promote the sufficient eutectic reaction of binary system, which can be widely used in the synthesis of other materials with low melting points.

Cationic covalent organic framework based all-solid-state electrolytes

2020 ◽  
Vol 4 (4) ◽  
pp. 1164-1173 ◽  
Author(s):  
Zhen Li ◽  
Zhi-Wei Liu ◽  
Zhen-Jie Mu ◽  
Chen Cao ◽  
Zeyu Li ◽  
...  
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolytes ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Li Ion Battery ◽  
Covalent Organic Framework ◽  
Li Ion ◽  
Lithium Ion Conductivity ◽  
Organic Framework

Two new imidazolium-based cationic COFs were synthesized and employed as all-solid electrolytes, and exhibited high lithium ion conductivity at high temperature. The assembled Li-ion battery displays preferable battery performance at 353 K.

Preparation of Regenerated Cathode Material Lithium Nickel Cobalt Oxide LiNi0.7Co0.3O2 Form Spent Lithium-Ion Battery

2019 ◽  
Vol 944 ◽  
pp. 1179-1186 ◽  
Author(s):  
Yue Hua Wang ◽  
Li Wen Ma ◽  
Yun He Zhang ◽  
Zhao Jie Huang ◽  
Xiao Li Xi
Keyword(s):  
High Temperature ◽  
Cathode Material ◽  
Lithium Ion Battery ◽  
Cathode Materials ◽  
Lithium Ion ◽  
Lithium Hydroxide ◽  
Nickel Cobalt ◽  
Aluminum Ions ◽  
Nickel Cobalt Oxide ◽  
Lithium Nickel Cobalt Oxide

With the development of new energy vehicles, urgent issues have attracted considerable attention. Some power batteries have entered the scrapping period, with the imperative recycling of used power batteries. Some studies have predicted that by 2020, the amount of power lithium battery scrap will reach 32.2 GWh, corresponding to ~500,000 tons, and by 2023, the scrap will reach 101 GWh, corresponding to ~1.16 million tons. In this study, nickel-cobalt-lithium LiNi0.7Co0.3O2cathode materials are regenerated from spent lithium-ion battery cathode materials as the raw material, which not only aids in the reduction of pressure on the environment but also leads to the recycling of resources. First, extraction is employed using extracting agent p204 to remove aluminum ions from an acid leaching solution. Extraction conditions for aluminum ions are: include a phase ratio of 1:2,a pH of 3, an extractant concentration of 30%, and a saponification rate of 70%.Next, the precursor was prepared by co-precipitation using sodium hydroxide and ammonia water as the precipitant and complexion agents, respectively; hence, the cathode material can be uniformly mixed at the atomic level. The precursor and lithium hydroxide were subjected to calcination at high temperature using a high-temperature solid-phase method. The Calcination conditions include an air atmosphere ; a calcination temperature of 800° °C ; a calcination time of 15 h, an n (precursor): n (lithium hydroxide) ratio of 1:1.1.The Thermogravimetric analysis revealed that the synthesis temperature should not exceed 850°C. X-ray diffraction analysis, scanning electron microscopy, and energy spectrum analysis of the cathode material revealed a composition comprising Li, Ni, and Co oxides. After analysis, the material obtained is lithium nickel-cobalt-oxide, LiNi0.7Co0.3O2, which is a positive electrode material with good crystallinity and a regular layered structure.

scholarly journals Influence of Temperature on the Performance of LiNi1/3Co1/3Mn1/3O2 Prepared by High-Temperature Ball-Milling Method

2018 ◽  
Vol 2018 ◽  
pp. 1-6 ◽  
Author(s):  
Ming Tian ◽  
Xuetian Li ◽  
Zhongbao Shao ◽  
Fengman Shen
Keyword(s):  
High Temperature ◽  
Electrochemical Performance ◽  
Ball Milling ◽  
Raw Materials ◽  
Retention Rate ◽  
Lithium Ion ◽  
Lithium Carbonate ◽  
Milling Process ◽  
Milling Method ◽  
Milling Temperature

Aiming at the preparation of high electrochemical performance LiNi1/3Co1/3Mn1/3O2 cathode material for lithium-ion battery, LiNi1/3Co1/3Mn1/3O2 was prepared with lithium carbonate, nickel (II) oxide, cobalt (II, III) oxide, and manganese dioxide as raw materials by high-temperature ball-milling method. Influence of ball-milling temperature was investigated in this work. It was shown that the fine LiNi1/3Co1/3Mn1/3O2 powder with high electrochemical performance can be produced by the high-temperature ball-milling process, and the optimal ball-milling temperature obtained in the current study was 750°C. Its initial discharge capacity was 146.0 mAhg−1 at the rate of 0.1 C, and over 50 cycles its capacity retention rate was 90.2%.

scholarly journals Stabilization of Superionic-Conducting High-Temperature Phase of Li(Cb9h10) via Solid Solution Formation with Li2(B12H12)

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 330
Author(s):  
Sangryun Kim ◽  
Kazuaki Kisu ◽  
Shin-ichi Orimo
Keyword(s):  
High Temperature ◽  
Solid Solutions ◽  
Ionic Conduction ◽  
Lithium Ion ◽  
High Temperature Phase ◽  
Temperature Phase ◽  
Solid Solution Formation ◽  
Low X ◽  
T Phase ◽  
Complex Anions

We report the stabilization of the high-temperature (high-T) phase of lithium carba-closo-decaborate, Li(CB9H10), via the formation of solid solutions in a Li(CB9H10)-Li2(B12H12) quasi-binary system. Li(CB9H10)-based solid solutions in which [CB9H10]− is replaced by [B12H12]2− were obtained at compositions with low x values in the (1−x)Li(CB9H10)−xLi2(B12H12) system. An increase in the extent of [B12H12]2− substitution promoted stabilization of the high-T phase of Li(CB9H10), resulting in an increase in the lithium-ion conductivity. Superionic conductivities of over 10−3 S cm−1 were achieved for the compounds with 0.2 ≤ x ≤ 0.4. In addition, a comparison of the Li(CB9H10)−Li2(B12H12) system and the Li(CB9H10)−Li(CB11H12) system suggests that the valence of the complex anions plays an important role in the ionic conduction. In battery tests, an all-solid-state Li–TiS2 cell employing 0.6Li(CB9H10)−0.4Li2(B12H12) (x = 0.4) as a solid electrolyte presented reversible battery reactions during repeated discharge–charge cycles. The current study offers an insight into strategies to develop complex hydride solid electrolytes.

Lithium ion conductivity of oriented Li0.33La0.56TiO3 solid electrolyte films prepared by a sol–gel process

2016 ◽  
Vol 284 ◽  
pp. 1-6 ◽  
Author(s):  
Takashi Teranishi ◽  
Yuki Ishii ◽  
Hidetaka Hayashi ◽  
Akira Kishimoto
Keyword(s):  
Solid Electrolyte ◽  
Sol Gel ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Sol Gel Process ◽  
Lithium Ion Conductivity

scholarly journals Correction to: Lithium ion conductivity of solid solutions based on Li8ZrO6

2018 ◽  
Vol 22 (9) ◽  
pp. 2965-2965
Author(s):  
Mariya S. Shchelkanova ◽  
Georgi Sh. Shekhtman ◽  
Anastasia V. Kalashnova ◽  
Olga G. Reznitskikh
Keyword(s):  
Solid Solutions ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Lithium Ion Conductivity

Scalable synthesis of silicon nanoplate-decorated graphite toward advanced lithium-ion battery anodes

Nanoscale ◽  
2021 ◽  
Author(s):  
Haimei Li ◽  
Xianglong Li ◽  
Denghui Wang ◽  
Siyuan Zhang ◽  
Wenqiang Xu ◽  
...  
Keyword(s):  
Lithium Ion Battery ◽  
Ball Milling ◽  
Lithium Battery ◽  
High Capacity ◽  
Lithium Ion ◽  
Milling Process ◽  
Cyclic Stability ◽  
Graphite Electrodes ◽  
Ball Milling Process ◽  
Scalable Synthesis

A silicon nanoplate-decorated graphite design is developed for lithium battery anodes via a simple ball milling process. The resultant silicon-graphite electrodes show high cyclic stability with high capacity, superior rate...

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