Relation Between Solid-State Cohesion of Metal Fluorides and the Electrochemical Behavior of Metals in Hydrogen Fluoride

1968 ◽  
Vol 115 (10) ◽  
pp. 1096 ◽  
Author(s):  
Ashok K. Vijh
Keyword(s):  
Solid State ◽  
Hydrogen Fluoride ◽  
Electrochemical Behavior ◽  
Metal Fluorides

Kinetic analysis and alloy designs for metal/metal fluorides toward high rate capability for all-solid-state fluoride-ion batteries

2021 ◽  
Vol 9 (11) ◽  
pp. 7018-7024
Author(s):  
Takahiro Yoshinari ◽  
Datong Zhang ◽  
Kentaro Yamamoto ◽  
Yuya Kitaguchi ◽  
Aika Ochi ◽  
...  
Keyword(s):  
Solid State ◽  
Rate Capability ◽  
High Rate ◽  
Fluoride Ion ◽  
Li Ion Batteries ◽  
High Rate Capability ◽  
Metal Fluorides ◽  
New Concepts ◽  
Metal Metal ◽  
Li Ion

A Cu–Au cathode material for all-solid-state fluoride-ion batteries with high rate-capability was designed as new concepts for electrochemical energy storage to handle the physicochemical energy density limit that Li-ion batteries are approaching.

Cationic tri(ferrocenecarbonitrile)silver(I)

2018 ◽  
Vol 73 (11) ◽  
pp. 759-764
Author(s):  
Frank Strehler ◽  
Tobias Rüffer ◽  
Julian Noll ◽  
Dieter Schaarschmidt ◽  
Alexander Hildebrandt ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Solid State ◽  
Electrochemical Behavior ◽  
Potential Range

AbstractThe synthesis of the tri-coordinated ferrocenecarbonitrile silver(I) complex [Ag(N≡CFc)3]OTf (3) is reported. Its electrochemical behavior shows that the three ferrocenyl units are oxidized in a very close potential range. In addition, the molecular structure of 3 in the solid state is discussed, showing that silver(I) is exclusively coordinated by three ferrocenecarbonitrile molecules.

Thiol end-capped titanium–copper complexes: Synthesis, solid state structure and electrochemical behavior

2008 ◽  
Vol 361 (6) ◽  
pp. 1659-1667 ◽  
Author(s):  
Heinrich Lang ◽  
Katrin Rößler ◽  
Deeb Taher ◽  
Rudolf Holze ◽  
Bernhard Walfort
Keyword(s):  
Solid State ◽  
Electrochemical Behavior ◽  
Copper Complexes ◽  
State Structure ◽  
Solid State Structure

Self-supported multidimensional Ni–Fe phosphide networks with holey nanosheets for high-performance all-solid-state supercapacitors

2019 ◽  
Vol 7 (29) ◽  
pp. 17386-17399 ◽  
Author(s):  
Shuo Li ◽  
Minghao Hua ◽  
Yuan Yang ◽  
Wei Huang ◽  
Xiaohang Lin ◽  
...  
Keyword(s):  
Solid State ◽  
Dft Calculations ◽  
Electrochemical Behavior ◽  
High Performance

Comprehensive research of the chemosynthesis, electrochemical behavior and DFT calculations of a multidimensional Ni–Fe–P electrode for all-solid-state supercapacitors.

Enabling Aspects of Metal Halide Nanocomposites for Reversible Energy Storage

2006 ◽  
Vol 972 ◽  
Author(s):  
Fadwa Badway ◽  
Azzam Mansour ◽  
Irene Plitz ◽  
Nathalie Pereira ◽  
Larry Weinstein ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Energy Density ◽  
Cell Formation ◽  
Alkali Halides ◽  
Nominal Composition ◽  
Metal Halides ◽  
Current Collectors ◽  
Metal Fluorides ◽  
Nanocomposite Structures

AbstractThe concept of reversible and non reversible conversion in high bandgap metal fluorides is expanded through the introduction of mixed conducting matrices to form dense nanocomposite structures capable of good transport to nanodomains of metal fluorides. Specific examples for BiF3 and especially CuF2 using matrices of nominal composition of MoO3 are discussed. The reversible conversion mechanism of the metal halides is expanded to enable a new concept of electrochemically self assembled microbatteries (ESAMs) based on alkali halides. Such technology enables the fabrication of a solid state microbattery between two current collectors of various configurations on the microscale. First examples demonstrated based on LiI have demonstrated cell formation, appreciable energy density, and preliminary reversibility.

Carbonyl-Nitrido Mixed-Metal Clusters: Synthesis, Reactivity, Electrochemical Behavior and Solid-State Structure of [Co5MoN(CO)14]2− and [Co5MoN(CO)14AuPPh3]−

2004 ◽  
Vol 2004 (19) ◽  
pp. 3901-3906 ◽  
Author(s):  
Roberto Della Pergola ◽  
Alessandro Fumagalli ◽  
Fabrizia Fabrizi de Biani ◽  
Luigi Garlaschelli ◽  
Franco Laschi ◽  
...  
Keyword(s):  
Solid State ◽  
Electrochemical Behavior ◽  
Metal Clusters ◽  
State Structure ◽  
Solid State Structure ◽  
Mixed Metal ◽  
Mixed Metal Clusters

Lithium transition metal pnictides – structural chemistry, electrochemistry, and function

2015 ◽  
Vol 35 (1) ◽  
pp. 1-24 ◽  
Author(s):  
Florian Winter ◽  
Rainer Pöttgen ◽  
Magnus Greiwe ◽  
Tom Nilges
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Crystal Structures ◽  
Chemical Bonding ◽  
Electrochemical Behavior ◽  
Solid State Nmr ◽  
Structural Chemistry ◽  
Covalently Bonded ◽  
Interesting Class ◽  
And Function

AbstractLithium-transition metal (T)-pnictides (Pn=P, As, Sb, Bi) are an interesting class of materials with greatly differing crystal structures. The transition metal and pnictide atoms build up covalently bonded networks that leave cavities or channels for the lithium atoms. Depending on the bonding of lithium to the polyanionic network, one observes mobility of the lithium atoms. The crystal chemistry, chemical bonding, 7Li solid-state NMR, and the electrochemical behavior of the pnictides are reviewed. The structural chemistry is compared with related tetrelides.

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