Electrical Conductivity and Oxygen Diffusivity of Perovskite-Type Solid Solution La0.6Sr0.4Co1-yFeyO3-δ (y=0.2, 0.4, 0.5, 0.6, 0.8)

2019 ◽  
Vol 35 (1) ◽  
pp. 1899-1907 ◽  
Author(s):  
Keiji Yashiro ◽  
Issei Nakano ◽  
Melanie Kuhn ◽  
Shinichi Hashimoto ◽  
Kazuhisa Sato ◽  
...  
Keyword(s):  
Solid Solution ◽  
Electrical Conductivity ◽  
Oxygen Diffusivity ◽  
Perovskite Type

Effect of Heat Treatment on Microstructure and Properties of Cu-3Ti-1Al Alloy

2013 ◽  
Vol 749 ◽  
pp. 282-286
Author(s):  
Xian Hui Wang ◽  
Xiao Chun Sun ◽  
Xiao Hong Yang ◽  
Shu Hua Liang
Keyword(s):  
Heat Treatment ◽  
Solid Solution ◽  
Electrical Conductivity ◽  
Electron Microscope ◽  
Treatment Process ◽  
Intermetallic Phase ◽  
Strengthening Effect ◽  
Microstructure And Properties ◽  
Optimal Heat Treatment ◽  
Transmission Electron

The effect of heat treatment on the microstructure and properties of Cu-3Ti-1Al alloy was investigated. The microstructure was characterized by scanning electron microscope (SEM) and transmission electron microscope (TEM), and the hardness and electrical conductivity were tested as well. The results showed that the hardness and electrical conductivity of Cu-3Ti-1Al alloy increased significantly after solid solution and ageing treatment. The strengthening effect of Cu-3Ti-1Al alloy was attributed to the formation of intermetallic phase such as Ti3Al and fine precipitates of coherent β-Cu4Ti. With increase of the aging time and the temperature, the precipitates became coarse and incoherent with Cu matrix, and the discontinuous precipitate β started to grow from grain boundaries toward grain interior, which decreased hardness. As the formation of Ti3Al, β-Cu3Ti and β-Cu4Ti phase can efficiently reduce Ti concentration in Cu matrix. The electrical conductivity of Cu-3Ti-1Al alloy increases. In the range of experiments, the optimal heat treatment process for Cu-3Ti-1Al alloy is solid solution at 850°C for 4h and ageing 500°C for 2h, and the hardness and electrical conductivity are 227HV and 12.3%IACS, respectively.

Corrigendum to “Evaluation of electrical conductivity and oxygen diffusivity of the typical Ruddlesden-Popper oxide Sr3Fe2O7-δ” [Ceram. Int. 43 (2017) 16264–16269]

2018 ◽  
Vol 44 (2) ◽  
pp. 2632
Author(s):  
Yihan Ling ◽  
Tianmin Guo ◽  
Xiaozhen Zhang ◽  
Riyan Achmad Budiman ◽  
Yoshinobu Fujimaki ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Oxygen Diffusivity

scholarly journals Термоэлектрические свойства нанокомпозитного Bi-=SUB=-0.45-=/SUB=-Sb-=SUB=-1.55-=/SUB=-Te-=SUB=-2.985-=/SUB=- с микрочастицами SiO-=SUB=-2-=/SUB=-

2019 ◽  
Vol 53 (6) ◽  
pp. 751
Author(s):  
А.А. Шабалдин ◽  
П.П. Константинов ◽  
Д.А. Курдюков ◽  
Л.Н. Лукьянова ◽  
А.Ю. Самунин ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Solid Solution ◽  
Electrical Conductivity ◽  
Wide Temperature Range ◽  
Figure Of Merit ◽  
Nanostructured Material ◽  
Thermoelectric Figure Of Merit ◽  
Thermoelectric Efficiency ◽  
Thermoelectric Figure ◽  
P Type

AbstractNanocomposite thermoelectrics based on Bi_0.45Sb_1.55Te_2.985 solid solution of p -type conductivity are fabricated by the hot pressing of nanopowders of this solid solution with the addition of SiO_2 microparticles. Investigations of the thermoelectric properties show that the thermoelectric power of the nanocomposites increases in a wide temperature range of 80–420 K, while the thermal conductivity considerably decreases at 80–320 K, which, despite a decrease in the electrical conductivity, leads to an increase in the thermoelectric efficiency in the nanostructured material without the SiO_2 addition by almost 50% (at 300 K). When adding SiO_2, the efficiency decreases. The initial thermoelectric fabricated without nanostructuring, in which the maximal thermoelectric figure of merit ZT = 1 at 390 K, is most efficient at temperatures above 350 K.

scholarly journals Studying of dielectric spectra of YCu0.15Mn0.85O3 solid solution with the use of complex conductivity

2021 ◽  
pp. 2160013
Author(s):  
A. V. Nazarenko ◽  
A. V. Pavlenko ◽  
Y. I. Yurasov
Keyword(s):  
Solid Solution ◽  
Electrical Conductivity ◽  
Model Description ◽  
Complex Conductivity ◽  
Electrophysical Properties ◽  
Approximation Model ◽  
Frequency Range ◽  
Dielectric Parameters ◽  
Frequency Behavior ◽  
Complex Electrical Conductivity

This work presents the results of studying the electrophysical properties of the YCu[Formula: see text]Mn[Formula: see text]O3 solid solution in the range of temperatures of [Formula: see text] = 26–400[Formula: see text]C and frequency range of [Formula: see text] = 102–105 Hz. A model description of the revealed dispersion of dielectric parameters in the material is made. The nonclassical modified Havriliak–Negami model written for complex electrical conductivity was used as an approximation model. It is shown that the application of this model almost exactly describes the frequency behavior of the dielectric constant [Formula: see text]/[Formula: see text], the dielectric loss tangent tg[Formula: see text] as well as the real and imaginary parts of complex conductivity [Formula: see text] and [Formula: see text]. The results of this work are an important step in identifying the opportunities and understanding the applications of this model.

Production and Study of Ca/Sn(II) Metastable Fluoride Ion Conductors

1997 ◽  
Vol 481 ◽  
Author(s):  
Michael F. Bell ◽  
Georges Dénès ◽  
Zhimeng Zhu
Keyword(s):  
Solid Solution ◽  
Electrical Conductivity ◽  
High Temperature ◽  
Calcium Nitrate ◽  
Fluoride Ion ◽  
Conductivity Measurements ◽  
Ambient Conditions ◽  
Reaction Conditions ◽  
Density Measurements ◽  
Ion Conductors

ABSTRACTPrecipitation reactions from aqueous solutions of calcium nitrate and tin(II) fluoride result in the formation of two metastable phases, depending on the reaction conditions. Crystalline CaSn2F6 and the microcrystalline Ca1-xSnxF2 solid solution are obtained, the latter crystallizing in the cubic fluorite (CaF2) type with total Ca/Sn disorder. Both phases are fluoride ion conductors. Electrical conductivity measurements versus temperature and bulk density measurements show that both phases are far from thermodynamic equilibrium at ambient conditions, and thus are metastable. Both decompose to a mixture of SnF2 and CaF2 at high temperature. In addition, CaSn2F6 is chemically unstable in an aqueous medium, in which it looses SnF2 to give the microcrystalline Ca1-xSnxF2 solid solution.

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