Mild Steel Marine Corrosion: Corrosion Rates in Atmospheric and Seawater Environments of a Peruvian Port (N.W. Farro, L. Veleva and P. Aguilar)

2020 ◽  
Vol 3 (2) ◽  
pp. 33-36
Author(s):  
Rosliza Ramli ◽  
Mohamed Ali Syed Sultan Ibrahim

Numerous extensive efforts have been done to acquire the applicable green corrosion inhibitors in order to decrease the corrosion rate of the materials. The corrosion inhibition of mild steel is vital for technology due to the increased industrial applications of these materials. In this report, the inhibitive action of Cymbopogon Citratus on the marine corrosion of mild steel was evaluated. The inhibition efficiency was calculated using weight loss measurement method, electrochemical measurement and inhibitor mechanism analysis. It was found that, Cymbopogon Citratus exhibited a very good performance as a green corrosion inhibitor for mild steel corrosion in seawater. All the experimental methods used for this project show that the presence of Cymbopogon Citratus in the seawater significantly decreases the corrosion rates and further decreasing the corrosion rates as the concentration of Cymbopogon Citratus increases. To sum it up, the inhibition efficiency increases with an increase in Cymbopogon Citratus concentration.


CORROSION ◽  
2005 ◽  
Vol 61 (9) ◽  
pp. 895-906 ◽  
Author(s):  
R. E. Melchers

CORROSION ◽  
1960 ◽  
Vol 16 (6) ◽  
pp. 260t-264t ◽  
Author(s):  
O. L. RIGGS ◽  
J. D. SUDBURY ◽  
MERLE HUTCHISON

Abstract A summary study of oxygen corrosion of mild steel in brine is presented. Corrosion rates were determined for oxygen pressures ranging from atmospheric to 515 psia and over a pH range of 1-13.5. All tests were conducted at room temperature (24 C). It is shown that corrosion rates are generally increased with increasing oxygen pressure and decreasing pH; however, when tests exceeded 6 hours duration, an accelerated corrosion developed over the pH range 8–12. An unusual filamentary type corrosion product develops and grows in the 300–500 psi oxygen pressure range in pH 12 system. The identification and proposed mechanism of growth are given. 3.4.6


2019 ◽  
Vol 11 (1) ◽  
pp. 26-32 ◽  
Author(s):  
Muhammad Sohail ◽  
Fayaz Hussain ◽  
Ali Dad Chandio ◽  
Maryam Sheikh

Corrosion is one of the major problems of mild steels in acidic medium. This can be minimized by the application of corrosion inhibitors, however; the most of inhibitors are toxic in nature. Therefore inhibitors from green sources are highly desirable to maintain the sustainability of the environmental system. Consequently, in this study ginger was selected; its juice extracted mechanically and used as an inhibitor. The different concentrations of ginger extract such as 0.25ml, 0.5ml, 0.75ml and 1ml were mixed in 0.1 M HCl solution to record the effect of inhibitor on corrosion rate at room temperature and at an elevated temperature of 50ᵒC. Electrochemical linear polarization resistance (LPR) tests were carried out to determine the corrosion rates at both temperatures with different additions of the inhibitor respectively. The LPR test uses three electrodes, first electrode of AISI 1019 (mild steel), second electrode is standard electrode of saturated calomel while the third electrode consists of graphite, which is called counter electrode, to measure potential difference. The whole assembly was dipped in the solution having varying concentration of inhibitors. The corrosion rate was found to be higher in the absence of ginger- extract. Conversely, the corrosion rate was dramatically reduced more prominently at 50oC but was less effective at Troom; with the trace-additions of ginger-inhibitor. So this research would be the good contribution to overcome the deterioration of mild steel and increase its life at ambient temperatures, by using economically available environmentally-friendly organic compound specially the use of locally available raw material should be focused.


2022 ◽  
Author(s):  
K. C. Suresh ◽  
S. Surendhiran ◽  
A. Benham ◽  
M. Sudha ◽  
B. Gopinath ◽  
...  

CORROSION ◽  
1958 ◽  
Vol 14 (4) ◽  
pp. 57-59 ◽  
Author(s):  
NORMAN HACKERMAN ◽  
RAY M. HURD ◽  
EARL S. SNAVELY

Abstract Corrosion rates of mild steel in mixtures of NH4NO3-NH3-H2O were measured at temperatures of 30, 45 and 60 C. The effects of various sulfur and arsenic-containing inhibitors were studied, with particular emphasis on NH4CNS. The corrosion reaction was found to be markedly affected by stresses in the metal to the extent that completely stress-relieved coupons would not corrode at all. The rate of the uninhibited reaction was much lower at 45 and 60 C than at 30 C, indicating a change in the mechanism of the corrosion reaction. The uninhibited corrosion rate of 3700 mdd at 30 C was decreased to approximately 25 mdd with NH4CNS concentrations greater than 0.1 percent. At 45 C, the most effective inhibitor was found to be 0.05 percent 2-mercapto-ethanol + 0.05 percent sodium arsenite, followed closely by 0.1 percent NH4CNS + 0.05 percent sodium arsenite. Thio-cyanate and thiourea alone at concentrations of 0.1 percent were somewhat less effective. Simple potential measurements using a platinum reference electrode showed the corroding coupons to be about 0.9 volt more anodic than the stress-relieved coupons. 4.3.4


2020 ◽  
Vol 45 (4) ◽  
Author(s):  
G.J. Okore ◽  
E.U. Elenwoke ◽  
J.S. Okore ◽  
E.E. Oguzie

The inhibition effect of Pterocarpus osun on the corrosion of mild steel and aluminium in acidic medium was studied using gravimetric techniques. Weight loss measurements were determined on metal coupons in 0.1M and 1M HCl acid within the immersion time of 24-h for 5 consecutive days. Inhibition efficiency was determined by comparing the corrosion rates of mild steel and aluminium in 0.1M and 1M HCl in the presence and absence of additives. The trend of inhibition efficiency was used to propose the mechanism of inhibition. It was found that the plant extract act as inhibitor for acid-induced corrosion of mild steel and aluminium in 0.1M and 1M HCl. Inhibition efficiency of 94.5% and 94.9% were obtained for P. osun for aluminium in 0.1M and 1M HCl and 98.9%and 96.9% for mild steel in 0.1M and 1M HCl respectively. The inhibition efficiency was found to increase with increase in inhibitor concentrations. The adsorption of the inhibitor obeyed Langmuir Adsorption Isotherm. Based on the findings, P. osun stem extract is highly recommended as an alternative to synthetic, toxic chemical inhibitors.


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