Modeling the Electric Field Effect in Dye-Sensitized Solar Cells Composed of Nanowire Arrays

Crystals ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 325
Author(s):  
Liqing Liu ◽  
Hui Wang ◽  
Dehao Wang ◽  
Yongtao Li ◽  
Xuemin He ◽  
...  

The ZnO@TiO2 core/shell nanowire arrays with different thicknesses of the TiO2 shell were synthesized, through depositing TiO2 on the ZnO nanowire arrays using the pulsed laser deposition process. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images show that these core/shell nanowires were homogeneously coated with TiO2 nanoparticles with high crystallinity, appearing to be a rather rough surface compared to pure ZnO nanowires. The efficiency of ZnO@TiO2 core/shell structure-based dye-sensitized solar cells (DSSCs) was improved compared with pure ZnO nanowires. This is mainly attributed to the enlarged internal surface area of the core/shell structures, which increases dye adsorption on the anode to improve the light harvest. In addition, the energy barrier which formed at the interface between ZnO and TiO2 promoted the charge separation and suppressed the carrier recombination. Furthermore, the efficiency of DSSCs was further improved by increasing the thickness of the TiO2 shell. This work shows an efficient method to achieve high power conversion efficiency in core/shell nanowire-based DSSCs.


RSC Advances ◽  
2015 ◽  
Vol 5 (107) ◽  
pp. 88052-88058 ◽  
Author(s):  
Zhisheng Chai ◽  
Jiuwang Gu ◽  
Javid Khan ◽  
Yufei Yuan ◽  
Lianhuan Du ◽  
...  

Thin, lightweight and flexible dye-sensitized solar cells (DSSCs) using three different kinds of TiO2 nanostructures grown on Ti meshes as photoanodes have been fabricated.


2016 ◽  
Vol 4 (47) ◽  
pp. 11118-11128 ◽  
Author(s):  
Wenwu Liu ◽  
Hui-gang Wang ◽  
Xiaofei Wang ◽  
Mei Zhang ◽  
Min Guo

TiO2 nanowire arrays/2.4 mol% Nb-doped TiO2 nanoparticles composites were synthesized on Ti-mesh substrates using a hydrothermal approach for fully flexible dye-sensitized solar cells that exhibited good 7.20% conversion efficiency.


2016 ◽  
Vol 4 (42) ◽  
pp. 10130-10145 ◽  
Author(s):  
Miao Xie ◽  
Fu-Quan Bai ◽  
Hong-Xing Zhang ◽  
Yue-Qing Zheng

It is well-known that the inner electric field formed between the counter electrode and the semiconductor surface has a substantial effect on the efficiencies of dye-sensitized solar cells (DSSCs).


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