On-Chip Optical Anodic Stripping Voltammetry with Closed-Cell Bipolar Electrode Arrays for Heavy Metals Detection in Water

2008 ◽  
Vol 6 (1) ◽  
pp. 71-79 ◽  
Author(s):  
Jana Dytrtová ◽  
Ivana Šestáková ◽  
Michal Jakl ◽  
Jiřina Száková ◽  
Daniela Miholová ◽  
...  

AbstractIn the soil solutions obtained in situ with suction cups from soils (Cambisol and Fluvisol) of pot experiment with Salix smithiana Smith, Lolium perenne L. and Thlaspi caerulescens J. & C. Presl heavy metals species (Cd, Pb and Cu) were assayed by differential pulse anodic stripping voltammetry and diffusive gradient in thin films. Prediction of accumulation performed best at free metal ion concentrations in unchanged pH (in 10−3 mol L−1 NaClO4 base electrolyte). The speciation provided by differential pulse anodic stripping voltammetry according to pH can provide a detailed description of the soil solution matrix. The concentration of free metals in unchanged pH represents a small part of the total content and varied from 0.04 to 0.75% with two exceptions found for accumulating plants (the content of Cd2+ in the soil solution from T. caerulescens was about 6% and the content of Cu2+ in the soil solution from S. smithiana was about 30%). The available concentration as determined by diffusive gradient in thin films was not in correlation with the heavy metals concentration in plant biomass.


2020 ◽  
Vol 44 (15) ◽  
pp. 5739-5745
Author(s):  
Lijuan Bu ◽  
Qingji Xie ◽  
Hai Ming

A dual-channel anodic stripping voltammetry protocol is proposed for the simultaneous detection of trace heavy metals in one experiment with high sensitivity.


1989 ◽  
Vol 219 ◽  
pp. 19-26 ◽  
Author(s):  
Salvatore Daniele ◽  
Maria-Antonietta Baldo ◽  
Paolo Ugo ◽  
Gian-Antonio Mazzocchin

2015 ◽  
Vol 1092-1093 ◽  
pp. 795-798
Author(s):  
Ying Hua Li ◽  
Lu Bai ◽  
Feng Gu ◽  
Hong Wang ◽  
Chun Ying Wu ◽  
...  

The analysis index of the portable metal analyzer for trace heavy metals in natural water based on anodic stripping voltammetry (ASV) were performed. Simultaneous determination and monovariated analysis of trace heavy metals were investigated both subsequently. The reasons of disturbance in analysis were also discussed. The addition of Ga (II) was testified that can eliminate the formation of the Cu-Zn intermetallic compound.


Sign in / Sign up

Export Citation Format

Share Document