Molecular Analysis of Li Ion Transport Characteristics in Polymer Electrolytes of All Solid-State Lithium Ion Battery

2020 ◽  
Vol MA2020-02 (68) ◽  
pp. 3492-3492
Author(s):  
Koki Nakajima ◽  
Takashi Tokumasu ◽  
Takuya Mabuchi
Keyword(s):  
Solid State ◽  
Ion Transport ◽  
Lithium Ion Battery ◽  
Molecular Analysis ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Li Ion

scholarly journals Molecular Dynamics Study of Ion Transport in Polymer Electrolytes of All-Solid-State Li-Ion Batteries

Micromachines ◽  
2021 ◽  
Vol 12 (9) ◽  
pp. 1012
Author(s):  
Takuya Mabuchi ◽  
Koki Nakajima ◽  
Takashi Tokumasu
Keyword(s):  
Molecular Dynamics ◽  
Solid State ◽  
Ion Transport ◽  
Polyethylene Oxide ◽  
Polymer Electrolytes ◽  
Li Ion Batteries ◽  
Transport Mechanisms ◽  
Li Ion ◽  
Dynamics Simulations ◽  
The Relationship

Atomistic analysis of the ion transport in polymer electrolytes for all-solid-state Li-ion batteries was performed using molecular dynamics simulations to investigate the relationship between Li-ion transport and polymer morphology. Polyethylene oxide (PEO) and poly(diethylene oxide-alt-oxymethylene), P(2EO-MO), were used as the electrolyte materials, and the effects of salt concentrations and polymer types on the ion transport properties were explored. The size and number of LiTFSI clusters were found to increase with increasing salt concentrations, leading to a decrease in ion diffusivity at high salt concentrations. The Li-ion transport mechanisms were further analyzed by calculating the inter/intra-hopping rate and distance at various ion concentrations in PEO and P(2EO-MO) polymers. While the balance between the rate and distance of inter-hopping was comparable for both PEO and P(2EO-MO), the intra-hopping rate and distance were found to be higher in PEO than in P(2EO-MO), leading to a higher diffusivity in PEO. The results of this study provide insights into the correlation between the nanoscopic structures of ion solvation and the dynamics of Li-ion transport in polymer electrolytes.

Probing the Fast Lithium-Ion Transport in Small-Molecule Solid Polymer Electrolytes by Solid-State NMR

2020 ◽  
Vol 53 (22) ◽  
pp. 10078-10085
Author(s):  
Xiaobin Fu ◽  
Yiyang Liu ◽  
Wei Wang ◽  
Ling Han ◽  
Jing Yang ◽  
...  
Keyword(s):  
Solid State ◽  
Ion Transport ◽  
Small Molecule ◽  
Polymer Electrolytes ◽  
Solid State Nmr ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer

A lithium carboxylate grafted dendrite-free polymer electrolyte for an all-solid-state lithium-ion battery

2019 ◽  
Vol 7 (45) ◽  
pp. 25818-25823 ◽  
Author(s):  
Zhongke Zhao ◽  
Yingmeng Zhang ◽  
Shaojun Li ◽  
Suhang Wang ◽  
Yongliang Li ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Ion Battery ◽  
Polymer Electrolyte ◽  
Solid Polymer Electrolyte ◽  
Lithium Ion ◽  
Solid Polymer ◽  
Hybrid Copolymer ◽  
Li Ion ◽  
Copolymer Matrices ◽  
Branched Chains

A novel solid polymer electrolyte was designed and synthesized based on a hybrid copolymer matrices grafting with lithium carboxylate branched chains, which ensures a homogeneous Li ion deposition and successfully inhibits the Li dendrite growth.

Novel composite polymer electrolytes containing poly(ethylene glycol)-grafted graphene oxide for all-solid-state lithium-ion battery applications

2014 ◽  
Vol 2 (34) ◽  
pp. 13873-13883 ◽  
Author(s):  
Jimin Shim ◽  
Dong-Gyun Kim ◽  
Hee Joong Kim ◽  
Jin Hong Lee ◽  
Ji-Hoon Baik ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Solid State ◽  
Ethylene Glycol ◽  
Lithium Ion Battery ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Composite Polymer ◽  
Poly Ethylene Glycol ◽  
Composite Polymer Electrolytes ◽  
Poly Ethylene

A series of composite polymer electrolytes containing poly(ethylene glycol)-grafted graphene oxide fillers were prepared for all-solid-state lithium-ion battery applications.

Agent molecule modulated low-temperature activation of solid-state lithium-ion transport for polymer electrolytes

2021 ◽  
Vol 505 ◽  
pp. 229917
Author(s):  
Jiwon Yu ◽  
Myungsuk Lee ◽  
Yeonseo Kim ◽  
Hyung-Kyu Lim ◽  
Jonghyun Chae ◽  
...  
Keyword(s):  
Solid State ◽  
Low Temperature ◽  
Ion Transport ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Temperature Activation

A crystalline low molecular weight cyclic organoboron compound for efficient solid state lithium ion transport

2015 ◽  
Vol 51 (81) ◽  
pp. 15035-15038 ◽  
Author(s):  
Prerna Joshi ◽  
Raman Vedarajan ◽  
Noriyoshi Matsumi
Keyword(s):  
Molecular Weight ◽  
Solid State ◽  
Ion Transport ◽  
Lithium Ion ◽  
Organoboron Compound ◽  
Low Molecular Weight ◽  
Ion Conduction ◽  
Specific Composition ◽  
Li Ion

We report the synthesis of a crystalline cyclic organoboron compound that shows an anomalous Li-ion conduction behaviour with specific composition and method of insertion of a Li salt.

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