scholarly journals Rotational Coherence Spectroscopy and Excited-State Dynamics of Tolane and its Van Der Waals Complexes with Argon and Nitrogen

1994 ◽  
Vol 14 (1-3) ◽  
pp. 45-59 ◽  
Author(s):  
Shane M. Ohline ◽  
Joann Romascan ◽  
Peter M. Felker

We report the results of rotational coherence spectroscopy on tolane, tolane–Ar, and tolane–N2. The results on tolane are consistent with a planar geometry for the species. They also provide information about the symmetries of excited vibronic states in the species. The results on the van der Waals complexes provide significant experimental constraints on where the small species bind to tolane. In addition, we report the observation of a rapid excited-state decay process in the complexes and discuss the possible nature of this process.

RSC Advances ◽  
2020 ◽  
Vol 10 (23) ◽  
pp. 13442-13450
Author(s):  
Aimin Duan ◽  
Suosuo An ◽  
Jiadan Xue ◽  
Xuming Zheng ◽  
Yanying Zhao

The excited state decay process of N-heterocyclic compounds is attracting increasing attention due to their fundamental applications in pharmaceutical and biological sciences.


Author(s):  
Elisabeth Gruber ◽  
Ricky Teiwes ◽  
Christina Kjær ◽  
Steen BrOndsted Nielsen ◽  
Lars Henrik Andersen

Excited-state dynamics plays a key role for light harvesting and energy transport in photosyntheticproteins but it is nontrivial to separate the intrinsic photophysics of the light-absorbers (chlorophylls)from interactions with the...


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