Synthesis, Crystal Structure, and DFT Calculations of 1,3-Diisobutyl Thiourea
Keyword(s):
X Ray
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1,3-Diisobutyl thiourea was synthesized and characterized by single crystal X-ray diffraction. It gives a monoclinic (α=γ= 90 andβ ≠90) structure with the space group P21/c. The unit cell dimensions area= 11.5131 (4) Å,b= 9.2355 (3) Å,c= 11.3093 (5) Å,α= 90°,β= 99.569° (2),γ= 90°,V= 1185.78 (8) Å3, andZ= 4. The crystal packing is stabilized by intermolecular (N–H⋯S) hydrogen bonding in the molecules. The optimized geometry and Mullikan's charges of the said molecule calculated with the help of DFT using B3LYP-6-311G model support the crystal structure.
2013 ◽
Vol 834-836
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pp. 515-518
2011 ◽
Vol 6
(11)
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pp. 1934578X1100601
2013 ◽
Vol 785-786
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pp. 424-427