Synthesis and Photoluminescence Characteristics of CaIn2O4:Dy3+ Phosphors Co-Doped with Gd3+, Zn2+ or Al3+ Ions

2016 ◽  
Vol 16 (4) ◽  
pp. 3973-3976 ◽  
Author(s):  
Jing Gou ◽  
Jing Wang ◽  
Binxun Yu ◽  
Dongyang Zhang

Novel warm-white emitting phosphors CaIn2O4:Dy3+ co-doped with Gd3+, Zn2+, or Al3+ ions were prepared by solid state reaction. In this paper, a strategy of co-doping with different ions was used with the aim of affecting the luminescence properties of CaIn2O4:0.6%Dy3+ under NUV excitation. The luminescence intensities of CaIn2O4:0.6%Dy3+ were enhanced by 0.2% Gd3+ or 0.2% Zn2+ ions co-doping under 367 nm excitation, but lowered by co-doping with 0.2% Al3+ ions. Furthermore, the chromaticity coordinates of CaIn2O4:0.6%Dy3+ can be tuned from the cold-white region to warmwhite region with Gd3+ or Zn2+ ions co-doping. These findings show that CaIn2O4:0.6%Dy3+, 0.2% Gd3+, and CaIn2O4:0.6%Dy3+,0.2% Zn2+ have potential application value as new warm-white LED phosphors.

RSC Advances ◽  
2017 ◽  
Vol 7 (83) ◽  
pp. 52995-53001 ◽  
Author(s):  
Ziyao Wang ◽  
Xifeng Hou ◽  
Yangai Liu ◽  
Zhuang Hui ◽  
Zhaohui Huang ◽  
...  

Eu2+, Eu3+ and Mn4+ co-doped Sr4Al14O25 phosphors were synthesized in air by high temperature solid-state reaction.


2010 ◽  
Vol 24 (15n16) ◽  
pp. 3221-3225 ◽  
Author(s):  
RUILI ZHANG ◽  
MANAKA NUMATA ◽  
TOMONORI MAEDA ◽  
YUJI AKAZAWA ◽  
KEI-ICHIRO MURAI ◽  
...  

A series of oxonitridosilicates phosphors Ba - Si x - O - N / Eu 2+ ( x = Si / Ba =1~8, 5atom% Eu 2+) were synthesized using traditional solid-state reaction. For x = 2~8, the main phase of the obtained samples was Ba 3 Si 6 O 12 N 2. All Ba - Si x - O - N / Eu 2+( x = 1~8) materials could be efficiently excited in the UV to visible region(310~450 nm ) and had a green emission at 508~522 nm , making them attractive as conversion phosphors for white LED applications. With increasing x values, the emission peaks shifted to the longer wavelength region, while the emission intensity had a maximum at x = 6. The influence of the firing times was also discussed, after twice fired, there was a tendency of single-phased formed of the obtained materials and the emission intensity was greatly improved.


2015 ◽  
Vol 1107 ◽  
pp. 53-58
Author(s):  
Siti Maisarah Aziz ◽  
Rosli Hussin ◽  
N.M. Yusoff

Lately, researchers have been considering the miscellaneous in the borophosphate crystalline’s luminescence as one of the important properties in hunt of the new functional material. In this study we discus the structural and luminescence properties of Eu3+/Dy3+ co-doped borophosphate ceramic. A series of ceramic samples based on B2O3-(65-)P2O5-25MgO-10TeO2 where (065) mol has successfully been prepared using solid state reaction method and sintered at 900°C. The crystalline phase of the powder samples was characterized using X-ray diffraction pattern. The diffraction patterns analysis indicated that the prepared samples were polycrystalline phase of B(PO4), Mg(PO3)2and Mg(BO3)(PO4). The local structure network structure has been investigated using Infrared Spectroscopy using KBr method. The FT-Infrared spectra reveal the presence of B-O-B vibrations, BO3 and BO4 bridging oxygen and P-O stretching modes of P-O-P, P=O and PO4 unit in the ceramics sample. Meanwhile, the luminescence properties of doped sample were measured based on analysis of emission spectra of photoluminescence spectroscopy. The emission peaks of Eu3+ doped sample were located at 593 nm, 613 nm, 652 nm, 685 nm due to the assigned transition 5D0-7FJ( J = 1, 2, 3, 4 ). The Dy3+ emission is due to 4F9/2 -5H15/2 and 4F9/2-6H13/2 transition. For Eu3+/Dy3+ co-doped sample consists of peaks belonging to the 4F9/2-6H15/2 (482 nm) and 4F9/2-6H13/2 (573 nm) transition while red emission 5D0-7F2 transitions appears at 611 nm. Improvement in the optical properties due to co-doping may be useful to discover a new highly efficient luminescent material that are very useful in optical devices and solid-state lighting.


RSC Advances ◽  
2017 ◽  
Vol 7 (25) ◽  
pp. 15222-15227 ◽  
Author(s):  
Baoxing Wang ◽  
Qiang Ren ◽  
Ou Hai ◽  
Xiulan Wu

The Ba2P2O7:Tb3+, Eu3+ phosphors were synthesized by a high temperature solid-state reaction method in air atmosphere and their crystal structures, lifetime, luminescence properties, and energy transfer mechanism were investigated in detail.


2016 ◽  
Vol 4 (16) ◽  
pp. 3396-3402 ◽  
Author(s):  
Huihong Lin ◽  
Ting Yu ◽  
Gongxun Bai ◽  
Ming-Kiu Tsang ◽  
Qinyuan Zhang ◽  
...  

The phosphors of Ca3Ga2Ge3O12 (CGGG) co-doped with Nd3+ and Cr3+ ions were synthesized using conventional solid-state reaction techniques.


RSC Advances ◽  
2019 ◽  
Vol 9 (42) ◽  
pp. 24305-24313 ◽  
Author(s):  
Yuhan Zhu ◽  
Wenjun Wang ◽  
Zefeng Xu ◽  
Qi Luo ◽  
Ling Li ◽  
...  

A series of novel Eu2+/3+, Ce3+ ion single- and co-doped BaZn2(PO4)2 samples were prepared via a high-temperature solid-state reaction.


RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42211-42217 ◽  
Author(s):  
Jia Ni ◽  
Qian Liu ◽  
Zhenzhen Zhou ◽  
Guanghui Liu

To reveal Mn2+ influence on emission of Ca-α-sialon:Eu2+, the Mn2+ and Eu2+ co-doped phosphors were synthesized by a solid state reaction method. The produced powders show an enhanced fluorescence thermostability and the roles of Mn2+ addition have been investigated.


2018 ◽  
Vol 47 (48) ◽  
pp. 17515-17524 ◽  
Author(s):  
Fengjun Chun ◽  
Binbin Zhang ◽  
Honggang Liu ◽  
Wen Deng ◽  
Wen Li ◽  
...  

A series of Na+ and Pr3+ co-doped orange-emitting CaYAl3O7 (CYAO) phosphors were prepared by a conventional high-temperature solid-state reaction method.


2014 ◽  
Vol 40 (8) ◽  
pp. 13151-13157 ◽  
Author(s):  
Zhong Chen ◽  
Xiao Xia Li ◽  
Guoping Du ◽  
Quanmao Yu ◽  
Bo Li ◽  
...  

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