Microstructures in Non-precious Alloys Near the Porcelain-Metal Interaction Zone

1979 ◽  
Vol 58 (10) ◽  
pp. 1987-1993 ◽  
Author(s):  
Robert D. Ringle ◽  
Carl W. Fairhurst ◽  
Kenneth J. Anusavice
Keyword(s):  
Interfacial Reaction ◽  
Reaction Zone ◽  
Elemental Concentration ◽  
Concentration Profiles ◽  
Dental Alloys ◽  
Interaction Zone ◽  
Dental Porcelain ◽  
Metal Interaction ◽  
Reaction Zones ◽  
Second Phases

The chemistry of microstructures near the interfacial reaction zones of four non-precious alloys and two different brands of dental porcelain has been analyzed. It was found that most non-precious dental alloys contain second phases which can alter elemental concentration profiles. Recommendations for assessing interfacial reaction zone chemistry in dental non-precious alloys are offered.

The Structure of Two-Stage Counterflow n-Heptane-Air Flames

2000 ◽  
Author(s):  
S. K. Aggarwal ◽  
H. S. Xue
Keyword(s):  
Strain Rate ◽  
Reaction Zone ◽  
Equivalence Ratio ◽  
Flame Structure ◽  
Premixed Combustion ◽  
Premixed Flame ◽  
Partially Premixed Combustion ◽  
Reaction Zones ◽  
Partially Premixed ◽  
Partially Premixed Flame

Partially premixed flames are formed by mixing air (in less than stoichiometric amounts) into the fuel stream prior to the reaction zone, where additional air is available for complete combustion. Such flames can occur in both laboratory and practical combustion systems. In advanced gas turbine combustor designs, such as a lean direct injection (LDI) combustor, partially premixed combustion represents an impotent mode of burning. Spray combustion often involves partially premixed combustion due to the locally fuel vapor-rich regions. In the present study, the detailed structure of n-heptane/air partially premixed flame in a counterflow configuration is investigated. The flame is computed by employing the Oppdif code and a detailed reaction mechanism consisting of 275 elementary reactions and 41 species. The partially premixed flame structure is characterized by two-stage burning or two distinct but synergistically coupled reaction zones, a rich premixed zone on the fuel side and a ‘nonpremixed zone on the air side. The fuel is completely consumed in the premixed zone with ethylene and acetylene being the major intermediate species. The reactions involving the consumption of these species are found to be the key rate-limiting reactions that characterize interactions between the two reaction zones, and determine the overall fuel consumption rate. The flame response to the variations in equivalence ratio and strain rate is examined. Increasing equivalence ratio and/or strain rate to a critical value leads to merging of the two reaction zones. The equivalence ratio variation affects the rich premixed reaction zone, while the variation in strain rate predominantly affects the nonpremixed reaction zone. The flame structure is also characterized in terms of a modified mixture fraction (conserved scalar), and laminar flamelet profiles are provided.

scholarly journals DIRECT OBSERVATION OF HIGH-TEMPERATURE AREAS OF METAL MELT AT OXYGEN CONVERTER BLOWING WITH LOW VOLTAGE APPLICATION

2021 ◽  
Vol 17 (4) ◽  
pp. 44-54
Author(s):  
Sergiy Semykin ◽  
Tetiana Golub ◽  
Sergiy Dudchenko
Keyword(s):  
High Temperature ◽  
Reaction Zone ◽  
Potential Application ◽  
Low Voltage ◽  
Video Recording ◽  
Negative Polarity ◽  
Visual Observation ◽  
Reaction Zones ◽  
Voltage Potential ◽  
Bottom Blowing

Introduction. The process of oxygen conversion, despite the existing improvements, can be supplemented by physical methods of influence, including the unconventional method of applying low-voltage potential developed at the Iron and Steel Institute of the NAS of Ukraine.Problem Statement. The studies of the method of low-voltage potential application on 60, 160 and 250 ton converters have shown that the technology intensifies thermophysical and hydrodynamic processes in the gasslag-metal system and increases the converter process efficiency.Purpose. The purpose of this research is to study the features of the influence on the reaction zones of the low voltage potential application at four blowing options with the use of high-temperature physical model.Materials and Methods. A physical model that simulates the top, bottom and combined oxygen blowing under low-voltage potential application of different polarity on the lance has been used. An insert of a transparent quartz plate is made in one of the walls for visual observation and video recording. The top blowing is conductedwith two nozzle lance (nozzle diameter 1.7 mm with an angle of 30 ° to the lance). The bottom blowing is conducted with a bottom tuyere with a 1.5 mm diameter central nozzle. Combined blowing is realized by a combination ofthese options.Results. The visual observation of the reaction zones with different blowing options has shown that the highest temperature and the largest dimensions of the brightest parts of the bath correspond to the combined blowing, while the lowest ones are reported for the bottom blowing. While applying the low-voltage potential method it has been established that the reaction zone is longer at the positive polarity on the lance, during the period of silicon oxidation, and at the negative polarity on the lance, during the period of intense carbon oxidation. The video of gas bubbles flotation, probably CO, has shown that the bubbles are formed more intensively in thecase of negative polarity on the lance.Conclusions. The applied technique has allowed estimating the influence of low-voltage potential application on the geometric parameters of the reaction zone.

Effects of drought stress and severe pruning on the reaction zone induced by single inoculations with a bark beetle associated fungus (Ophiostoma ips) in the phloem of young Scots pines

1998 ◽  
Vol 28 (12) ◽  
pp. 1814-1824 ◽  
Author(s):  
Luc Croisé ◽  
Erwin Dreyer ◽  
François Lieutier
Keyword(s):  
Water Stress ◽  
Reaction Zone ◽  
Bark Beetle ◽  
Severe Water Stress ◽  
Reaction Zones ◽  
Maximum Water ◽  
Ips Sexdentatus ◽  
Effects Of Drought ◽  
Two Parameters ◽  
Needle Water Potential

The objective of this study was to test the effect of water stress and pruning on the resistance of young Scots pines (Pinus sylvestris L.) to a bark beetle associated fungus. Six-year-old potted trees were either pruned (70% of needles removed) or subjected to several successive episodes of severe water stress, prior to inoculation of inner bark with the fungus Ophiostoma ips (Rumb.) Nannf., which is usually associated with the bark beetle Ips sexdentatus Boern. Well-watered, nonpruned trees served as controls. Predawn needle water potential reached -2.5 MPa and net CO2 assimilation rates were reduced to almost zero during each water stress episode. The length of the reaction zones around inoculation points reached 3-4 cm after 3 weeks. It was higher during Spring than during Autumn. Impact of water stress on the length of the reaction zone was very limited and independent of the number of drought episodes that had been imposed prior to inoculation. The only visible change was a slight decrease when the inoculation was done during the period of maximum water stress intensity. Growth of the pathogen in the phloem was not affected by water stress. Correspondingly, pruning had no effect on either of these two parameters. Induced reaction zones accumulated monophenolic compounds that were undetectable in unwounded phloem. These included pinocembrin and pinosylvin and its monomethylether known to contribute to the defence against the fungus. Neither drought nor severe pruning induced any change in the nature or concentrations of these compounds in the unwounded phloem or in the reaction zone.

The turbulent burning velocity for large-scale and small-scale turbulence

1999 ◽  
Vol 384 ◽  
pp. 107-132 ◽  
Author(s):  
N. PETERS
Keyword(s):  
Level Set ◽  
Reaction Zone ◽  
Large Scale ◽  
Burning Velocity ◽  
Small Scale ◽  
Constant Density ◽  
Flame Surface ◽  
Reaction Zones ◽  
Scale Turbulence ◽  
Turbulent Burning Velocity

The level-set approach is applied to a regime of premixed turbulent combustion where the Kolmogorov scale is smaller than the flame thickness. This regime is called the thin reaction zones regime. It is characterized by the condition that small eddies can penetrate into the preheat zone, but not into the reaction zone.By considering the iso-scalar surface of the deficient-species mass fraction Y immediately ahead of the reaction zone a field equation for the scalar quantity G(x, t) is derived, which describes the location of the thin reaction zone. It resembles the level-set equation used in the corrugated flamelet regime, but the resulting propagation velocity s*L normal to the front is a fluctuating quantity and the curvature term is multiplied by the diffusivity of the deficient species rather than the Markstein diffusivity. It is shown that in the thin reaction zones regime diffusive effects are dominant and the contribution of s*L to the solution of the level-set equation is small.In order to model turbulent premixed combustion an equation is used that contains only the leading-order terms of both regimes, the previously analysed corrugated flamelets regime and the thin reaction zones regime. That equation accounts for non-constant density but not for gas expansion effects within the flame front which are important in the corrugated flamelets regime. By splitting G into a mean and a fluctuation, equations for the Favre mean [Gtilde]and the variance [Gtilde]″2 are derived. These quantities describe the mean flame position and the turbulent flame brush thickness, respectively. The equation for [Gtilde]″2 is closed by considering two-point statistics. Scaling arguments are then used to derive a model equation for the flame surface area ratio [rhotilde]. The balance between production, kinematic restoration and dissipation in this equation leads to a quadratic equation for the turbulent burning velocity. Its solution shows the ‘bending’ behaviour of the turbulent to laminar burning velocity ratio sT/sL, plotted as a function of v′/sL. It is shown that the bending results from the transition from the corrugated amelets to the thin reaction zones regimes. This is equivalent to a transition from Damköhler's large-scale to his small-scale turbulence regime.

Controlling of Grain Boundary Structure and Interface Structure of Advanced Materials and their Joints

2007 ◽  
Vol 127 ◽  
pp. 3-8
Author(s):  
Masaaki Naka
Keyword(s):  
Grain Size ◽  
Interfacial Reaction ◽  
Reaction Zone ◽  
Amorphous Alloys ◽  
Advanced Materials ◽  
Boundary Structure ◽  
Dissimilar Joints ◽  
Petch Relation ◽  
Chemical Potentials ◽  
Grain Boundary Structure

Strength of nanostructured Cr-B and Cr-Ni alloys prepared by sputtering was related with grain size. The alloying of B or Ni to Cr reduces the grain size of the alloys. The increase in volume of grain boundaries or amorphous phase induced by alloying elements causes the departure of strength of nanostructured Cr alloys from the values estimated by the Hall-Petch relation. The formation and microhardness of Cr or Ti base amorphous alloys could be discussed by the chemical bonding between elements. The strength of dissimilar joints was dominated by the thickness and structure of the interfacial reaction zone between SiC and metal. The formation of interfacial reaction zone is discussed by the change of chemical potentials of elements between ceramics and metal.

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