The modification of bitumen with styrene–butadiene–styrene, ethylene vinyl acetate and varying the amount of reactive ethylene terpolymer

2017 ◽  
Vol 50 (3) ◽  
pp. 241-255 ◽  
Author(s):  
Seyfullah Keyf
Keyword(s):  
Vinyl Acetate ◽  
Softening Point ◽  
Elastic Recovery ◽  
Ethylene Vinyl Acetate ◽  
Modified Bitumen ◽  
Penetration Index ◽  
Different Types ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

In this article, 50/70 penetration grade TUPRAS bitumen was modified. Reactive elastomeric terpolymer (Elvaloy RET; DuPont Company), ethylene vinyl acetate (EVA) and styrene–butadiene–styrene (SBS) polymers were used in bitumen modification. Set hours of the tests were applied to samples taken from the obtained modified bitumen mixture. Varying amount of reactive ethylene terpolymer with weight ratios of 0.5%, 1.0%, 1.5%, 2.0% and 2.5% were introduced to the mixture of raw bitumen with 1.0% SBS and 1.0% EVA. Penetration, penetration index, softening point, ductility and elastic recovery tests were performed with these modified bitumen and raw bitumen. The samples of raw bitumen and modified bitumens of 2.0% Elvaloy RET, 1.0% SBS and 1.0% EVA were investigated by means of IR spectroscopy. The raw bitumen was modified with SBS, EVA and RET, and it was determined that penetration and ductility values were decreased while penetration index, softening point and elastic recovery were increased. The purpose of this study is to research the improving properties of 50/70 penetration grade–modified bitumen used in highways of Turkey. The most important characteristics (such as softening point, penetration and % elastic recovery) of new polymer-modified bitumen (NPMB) containing 2.5% EVA, 1% RET and 1% SBS were compared with eight different types of polymer-modified bitumens in Turkey (TPMB). NPMB provided all required parameters (softening point, penetration and % elastic recovery) for five different types of TPMBs (TPMB 70-16, TPMB 70-22, TPMB 76-16, TPMB 76-22 and TPMB 82-16).

scholarly journals The Effect of Direct-to-Plant Styrene-Butadiene-Styrene Block Copolymer Components on Bitumen Modification

Polymers ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 140 ◽  
Author(s):  
Wengang Zhang ◽  
Zhirong Jia ◽  
Yixia Zhang ◽  
Kui Hu ◽  
Longting Ding ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Vinyl Acetate ◽  
Butylated Hydroxytoluene ◽  
Bituminous Mixture ◽  
Modified Bitumen ◽  
Ethyl Vinyl ◽  
Microscopic Images ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

Five types of material, styrene-butadiene-styrene block copolymer (SBS), ethyl-vinyl-acetate (EVA), naphthenic oil, maleic anhydride grafted ethylene-vinyl acetate copolymer (EVA-g-MAH) and butylated hydroxytoluene (BHT) were used as the raw ingredients for manufacturing direct-to-plant SBS in this paper. Thirteen kinds of direct-to-plant SBS with different EVA/SBS and naphthenic oil/SBS were prepared as well as the processes diagrammatic sketch of dispersion and swelling of direct-to-plant SBS modifier in bitumen were discussed. Microscopic images of direct-to-plant SBS modified bitumen with different components were obtained using fluorescence microscopy. The micro-images were analysed and quantified with MATLAB software. The influence of key components on the micro-morphology of direct-to-plant SBS-modified bitumen is discussed, followed with the tests on melting points and the melting indexes of direct-to-plant SBS with different EVA/SBS and naphthenic oil/SBS. The performances test of bitumen and bituminous mixture modified by these direct-to-plant SBS were also conducted. Results show that, with the ratio improvement of EVA/SBS or naphthenic oil/SBS, the number of the pixel dot number of area (SBS) in microscopic images increased. Enlargement of the pixel dot number of centre line elongate and the structure fineness was observed, indicating that the dispersion and swelling effect of the SBS modifier in bitumen had been improved. Meanwhile, the macro index, such as the melting point and melting index of direct-to-plant SBS, was also improved corresponding to the increase of EVA/SBS ratio or naphthenic oil/SBS ratio. With the addition of EVA or naphthene oil content, penetration and ductility of direct-to-plant SBS modified bitumen received gradual enhancement, but the softening point and viscosity were found out to be decreased. The high-temperature and low-temperature performances of direct-to-plant SBS modified bituminous mixture can be effectively improved by adding EVA or naphthenic oil. By meeting the required performances of direct-to-plant SBS, modified bitumen and bituminous mixture, the component of direct-to-plant SBS is recommended as, SBS:EVA:naphthenic oil:EVA-g-MAH:BHT is 1:0.1–0.5:0.05–0.2:0.03:0.05. For the compatibleness of SBS with different bitumen are different, necessary tests verification is recommended to be carried out prior to usage.

scholarly journals Assessment of the viscoelastic properties of modified bitumens containing styrene-butadiene-styrene copolymer

2015 ◽  
Vol 10 (4) ◽  
pp. 299-308 ◽  
Author(s):  
Mieczysław Słowik
Keyword(s):  
Tensile Test ◽  
Elastic Recovery ◽  
Asphalt Binders ◽  
Modified Bitumen ◽  
Styrene Copolymer ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Temperature Susceptibility ◽  
Butadiene Styrene

The viscoelastic behaviour of styrene-butadiene-styrene copolymer modified asphalt binders during tensile test and inverse creep test (retarded strain recovery after unloading) has been analysed in the presented paper. Laboratory tests have been conducted on two specimens of road bitumen: 20/30 and 50/70 penetration grade, which have been subjected to modification with the additive of 9% concentrate of SBS elastomer modified bitumen. When the two were mixed, the samples of polymer modified binders containing 3% or 6% by mass of the SBS elastomer were obtained. Force-ductility (tensile) test that has been followed by the extended procedure for the determination of elastic recovery, has been used as the research method. The results of the study have showed a significant improvement of the effect of modifications on the elastic properties and the temperature susceptibility reduction obtained only in the case of binders, where the polymer constitutes a dispersing phase forming a continuous network throughout the bitumen. Moreover, the temperature susceptibility coefficients, defined on the basis of the tensile test results, have been proposed as an alternative or extension to the previously widely used parameter, the Penetration Index.

scholarly journals Evaluation of the Additives’ Behaviour to Determine the Best Modifier for Improving Asphalt Performance at High Temperature

2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Ismail Bakheit Eldouma ◽  
Huang Xiaoming
Keyword(s):  
High Temperature ◽  
End Of Life ◽  
Vinyl Acetate ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Ethylene Vinyl Acetate ◽  
Positive Influence ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

The current study aims to examine the physical and rheological properties at the high-temperature range of 52, 58, 64, 70, 76, and 82°C, utilizing adjusted asphalt binders. Three kinds of asphalt modifiers were selected such as styrene-butadiene-styrene, ethylene vinyl acetate, and end of life tires. The selected additives were implemented with different contents ranging from 4% to 7% by the weight of neat asphalt. Various test methods have been established, such as ductility, viscosity, microscopic inspection, and dynamic shear rheometer experiments. Results proved that the percentage decrease in ductility was 93%, 91%, and 88% with regard to the adding of the end of life tires (ELTs), ethylene vinyl acetate (EVA), and styrene-butadiene-styrene (SBS) additives, respectively. Outcomes also confirmed that viscosity was boosted from 0.411 Pa.s to 1.249, 1.0986, and 0.9785 Pa.s after adding 7% of ELTs, 7% of EVA, and 7% of SBS, respectively. The rutting parameter and complex shear modulus increased after modification, indicating the excellent performance of asphalt. The conclusions confirmed that the ELTs have fewer agglomerates and have good compatibility before ageing and excellent compatibility after the ageing process. Thus, the ELTs are deemed as efficient dispersion additive for avoiding separation during the storage and handling of the asphalt binder. Lastly, ELTs were accepted as the best enhancer for their positive influence on physical and rheological characteristics, which means higher quality amended bitumen would give higher resistance to permanent deformation.

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