Investigating the mechanisms of rubber, styrene-butadiene-styrene and ethylene-vinyl acetate in asphalt binder based on rheological and distress-related tests

2020 ◽  
Vol 262 ◽  
pp. 120744
Author(s):  
Aboelkasim Diab ◽  
Zhanping You ◽  
Sanjeev Adhikari ◽  
Lingyun You ◽  
Xuelian Li ◽  
...  
Keyword(s):  
Vinyl Acetate ◽  
Asphalt Binder ◽  
Ethylene Vinyl Acetate ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

scholarly journals Evaluation of the Additives’ Behaviour to Determine the Best Modifier for Improving Asphalt Performance at High Temperature

2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Ismail Bakheit Eldouma ◽  
Huang Xiaoming
Keyword(s):  
High Temperature ◽  
End Of Life ◽  
Vinyl Acetate ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Ethylene Vinyl Acetate ◽  
Positive Influence ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

The current study aims to examine the physical and rheological properties at the high-temperature range of 52, 58, 64, 70, 76, and 82°C, utilizing adjusted asphalt binders. Three kinds of asphalt modifiers were selected such as styrene-butadiene-styrene, ethylene vinyl acetate, and end of life tires. The selected additives were implemented with different contents ranging from 4% to 7% by the weight of neat asphalt. Various test methods have been established, such as ductility, viscosity, microscopic inspection, and dynamic shear rheometer experiments. Results proved that the percentage decrease in ductility was 93%, 91%, and 88% with regard to the adding of the end of life tires (ELTs), ethylene vinyl acetate (EVA), and styrene-butadiene-styrene (SBS) additives, respectively. Outcomes also confirmed that viscosity was boosted from 0.411 Pa.s to 1.249, 1.0986, and 0.9785 Pa.s after adding 7% of ELTs, 7% of EVA, and 7% of SBS, respectively. The rutting parameter and complex shear modulus increased after modification, indicating the excellent performance of asphalt. The conclusions confirmed that the ELTs have fewer agglomerates and have good compatibility before ageing and excellent compatibility after the ageing process. Thus, the ELTs are deemed as efficient dispersion additive for avoiding separation during the storage and handling of the asphalt binder. Lastly, ELTs were accepted as the best enhancer for their positive influence on physical and rheological characteristics, which means higher quality amended bitumen would give higher resistance to permanent deformation.

The modification of bitumen with styrene–butadiene–styrene, ethylene vinyl acetate and varying the amount of reactive ethylene terpolymer

2017 ◽  
Vol 50 (3) ◽  
pp. 241-255 ◽  
Author(s):  
Seyfullah Keyf
Keyword(s):  
Vinyl Acetate ◽  
Softening Point ◽  
Elastic Recovery ◽  
Ethylene Vinyl Acetate ◽  
Modified Bitumen ◽  
Penetration Index ◽  
Different Types ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

In this article, 50/70 penetration grade TUPRAS bitumen was modified. Reactive elastomeric terpolymer (Elvaloy RET; DuPont Company), ethylene vinyl acetate (EVA) and styrene–butadiene–styrene (SBS) polymers were used in bitumen modification. Set hours of the tests were applied to samples taken from the obtained modified bitumen mixture. Varying amount of reactive ethylene terpolymer with weight ratios of 0.5%, 1.0%, 1.5%, 2.0% and 2.5% were introduced to the mixture of raw bitumen with 1.0% SBS and 1.0% EVA. Penetration, penetration index, softening point, ductility and elastic recovery tests were performed with these modified bitumen and raw bitumen. The samples of raw bitumen and modified bitumens of 2.0% Elvaloy RET, 1.0% SBS and 1.0% EVA were investigated by means of IR spectroscopy. The raw bitumen was modified with SBS, EVA and RET, and it was determined that penetration and ductility values were decreased while penetration index, softening point and elastic recovery were increased. The purpose of this study is to research the improving properties of 50/70 penetration grade–modified bitumen used in highways of Turkey. The most important characteristics (such as softening point, penetration and % elastic recovery) of new polymer-modified bitumen (NPMB) containing 2.5% EVA, 1% RET and 1% SBS were compared with eight different types of polymer-modified bitumens in Turkey (TPMB). NPMB provided all required parameters (softening point, penetration and % elastic recovery) for five different types of TPMBs (TPMB 70-16, TPMB 70-22, TPMB 76-16, TPMB 76-22 and TPMB 82-16).

Compatibility and Storage Stability of Asphalt Binder Modified by Styrene-Butadiene-Styrene (SBS) Graft Copolymer

2021 ◽  
Vol 1036 ◽  
pp. 459-470
Author(s):  
Hong Gang Zhang ◽  
Qiang Huai Zhang ◽  
Xue Ting Wang ◽  
Hua Tan ◽  
Li Ning Gao ◽  
...  
Keyword(s):  
Triblock Copolymer ◽  
Storage Stability ◽  
Asphalt Binder ◽  
Solubility Parameters ◽  
Suitable Alternative ◽  
Modified Asphalt ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
Butadiene Styrene

A styrene-butadiene-styrene triblock copolymer (SBS) was grafted with an unsaturated polar monomer (monomer A) composed of maleic anhydride (MAH) and methoxy polyethylene (MPEG) via a ring-opening reaction after epoxidizing styrene-butadiene-styrene triblock copolymer (ESBS). The microscopic changes of SBS before and after grafting has been characterized with Fourier transform infrared spectrum (FT-IR), X-ray photoelectron spectroscopy (XPS) and gel permeation chromatography (GPC). The results revealed that the monomer A was successfully grafted on SBS backbone, and the maximum graft ratio (GR) was 20.32%. To verify the compatibility between SBS and asphalt, solubility parameters and surface free energy (SFE) of SBS, grafted SBS and asphalt were measured. It was found that the solubility parameter and SFE of grafted SBS were closer to asphalt compared with SBS. It also has been confirmed from storage stability that the temperature susceptibility of grafted SBS modified asphalt was reduced in compare with SBS modified asphalt binder. As consequence, the use of grafted copolymer can be considered a suitable alternative for modification of asphalt binder in pavement.

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