Improved Storage Stability of LDPE/SBS Blends Modified Asphalts

2002 ◽  
Vol 10 (3) ◽  
pp. 229-236 ◽  
Author(s):  
Guangtao Gao ◽  
Yong Zhang ◽  
Yinxi Zhang ◽  
Kang Sun ◽  
Yongzhong Fan
Keyword(s):  
High Temperature ◽  
Storage Stability ◽  
Optical Microscope ◽  
Low Density Polyethylene ◽  
Low Density ◽  
High Shear ◽  
High Shear Stress ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

In this paper, Low Density Polyethylene (LDPE) / Styrene-Butadiene-Styrene (SBS) blends prepared under high shear stress were used as asphalt modifiers. Compared to the asphalts modified by LDPE and SBS added directly, the blend modified asphalts showed much better storage stability in the presence of sulfur at high temperature. No visible phase separation was observed under an optical microscope at high temperature and the morphology analysis indicated that the phase structure of the LDPE/SBS blend modified asphalts was unchanged with time at high temperature. After storage at 163°Ê for 48h, the LDPE/SBS blend modified asphalts had no evidence of coalescence of polymer particles. The rheological properties of the asphalts were also improved by the addition of polymers in all cases.

Compatibility and Storage Stability of Asphalt Binder Modified by Styrene-Butadiene-Styrene (SBS) Graft Copolymer

2021 ◽  
Vol 1036 ◽  
pp. 459-470
Author(s):  
Hong Gang Zhang ◽  
Qiang Huai Zhang ◽  
Xue Ting Wang ◽  
Hua Tan ◽  
Li Ning Gao ◽  
...  
Keyword(s):  
Triblock Copolymer ◽  
Storage Stability ◽  
Asphalt Binder ◽  
Solubility Parameters ◽  
Suitable Alternative ◽  
Modified Asphalt ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
Butadiene Styrene

A styrene-butadiene-styrene triblock copolymer (SBS) was grafted with an unsaturated polar monomer (monomer A) composed of maleic anhydride (MAH) and methoxy polyethylene (MPEG) via a ring-opening reaction after epoxidizing styrene-butadiene-styrene triblock copolymer (ESBS). The microscopic changes of SBS before and after grafting has been characterized with Fourier transform infrared spectrum (FT-IR), X-ray photoelectron spectroscopy (XPS) and gel permeation chromatography (GPC). The results revealed that the monomer A was successfully grafted on SBS backbone, and the maximum graft ratio (GR) was 20.32%. To verify the compatibility between SBS and asphalt, solubility parameters and surface free energy (SFE) of SBS, grafted SBS and asphalt were measured. It was found that the solubility parameter and SFE of grafted SBS were closer to asphalt compared with SBS. It also has been confirmed from storage stability that the temperature susceptibility of grafted SBS modified asphalt was reduced in compare with SBS modified asphalt binder. As consequence, the use of grafted copolymer can be considered a suitable alternative for modification of asphalt binder in pavement.

Effect of Shear Time and the Crumb Rubber Percentage on the Properties of Composite Modified Asphalt

2013 ◽  
Vol 848 ◽  
pp. 26-30
Author(s):  
Fu Qiang Dong ◽  
Wen Zhe Zhao ◽  
Yu Zhen Zhang ◽  
Hua Dong Sun ◽  
Wei Yu Fan ◽  
...  
Keyword(s):  
High Temperature ◽  
Crumb Rubber ◽  
Rubber Content ◽  
Step Method ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Important Measurement ◽  
Butadiene Styrene

This paper presents a laboratory study of Styrene-Butadiene-Styrene (SBS)/ crumb rubber modified asphalt by the two-step method. The conventional properties of the modified asphalt were determined. The effects of crumb rubber content and shearing time on the performance of the crumb rubber modified asphalt and composite modified asphalt. The results show that the crumb rubber contents and shearing time have significant impacts on the performance of the modified asphalt. With the crumb rubber content increasing, the high temperature performance was improved and the low temperature chanethe softening point increases and penetration decrease, and the ductility change little. It is comfortable for workability at the crumb rubber content of 20%. The viscosity is an important measurement for the workability of the modified asphalt. After adding the stabilizer, the viscosity increases until the shearing time reaching 1.5h, then it will decrease gradually.

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