Using aromatic polyamines with high proton affinity as “proton sponge” dopants for electrospray ionisation mass spectrometry

2017 ◽  
Vol 23 (2) ◽  
pp. 49-54
Author(s):  
Marisa A Wirth ◽  
Christopher P Rüger ◽  
Martin Sklorz ◽  
Ralf Zimmermann
Keyword(s):  
Mass Spectrometry ◽  
Proton Affinity ◽  
Proton Sponge ◽  
Electrospray Ionisation ◽  
High Proton Affinity ◽  
Electrospray Ionisation Mass Spectrometry ◽  
High Proton ◽  
Ionisation Mass Spectrometry ◽  
Ionisation Mass

Synthesis, structure, and condensed-phase reactivity of [Ag3(μ3-H)(μ3-BH4)LPh3](BF4) (LPh = bis(diphenylphosphino)amine) with CS2

2018 ◽  
Vol 47 (41) ◽  
pp. 14713-14725 ◽  
Author(s):  
Howard Z. Ma ◽  
Jonathan M. White ◽  
Roger J. Mulder ◽  
Gavin E. Reid ◽  
Allan J. Canty ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Condensed Phase ◽  
Esi Ms ◽  
Electrospray Ionisation ◽  
Electrospray Ionisation Mass Spectrometry ◽  
Ionisation Mass Spectrometry ◽  
Ionisation Mass

Electrospray ionisation mass spectrometry (ESI-MS) was used to monitor the reaction of AgBF4, bis(diphenylphosphino)amine (dppa = (Ph2P)2NH = LPh) and NaBH4 in acetonitrile.

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