Chemical composition and lead isotopy of copper and bronze from Nuragic Sardinia

2001 ◽  
Vol 4 (1) ◽  
pp. 43-85 ◽  
Author(s):  
Friedrich Begemann ◽  
Sigrid Schmitt-Strecker ◽  
Ernst Pernicka ◽  
Fulvia Lo Schiavo

We present data on the chemical and lead isotope composition of copper and bronze objects from Nuragic Sardinia. The sample suite comprises, inter alia, objects from the hoard finds at Arzachena (21 objects), Bonnanaro (10), Ittireddu (34), and Pattada (20), all in northern Sardinia. With one exception, all ingot fragments (49) consist of unalloyed copper; the exception comes from Ittireddu and contains 11 per cent tin. In contradistinction, all implements (21) are made from standard bronze with a mean tin content of 10.8 per cent. A dozen sword fragments from the Arzachena hoard, all of fairly uniform small size, are pieces of a large number of different swords. The low tin content of only about 1 per cent would have made for poor weapons, confirming the archaeological identification of the fragments as pieces of votive swords. Scrap metal from Arzachena is remarkable for its wide range of trace element contents and lead isotope abundance ratios. It is dissimilar to all other metal samples investigated, possibly representing metal from local smelting experiments using a variety of different copper ores. Lead isotope data and trace element patterns, alone or in conjunction, do not allow us to tell oxhide ingots from plano-convex (bun) ingots. Most ingot fragments have a lead isotope signature similar to those of Cypriot copper ores but there are also a number of ingots whose lead isotope fingerprints are fully compatible with them being local products. Of the bronzes, none has lead with an isotopic composition characteristic of copper ingots from Cyprus. All contain local lead, suggesting the bronze implements were manufactured locally. Isotopically-fitting lead is found in copper and lead ore deposits from the Iglesiente-Sulcis district in south-west Sardinia and from Funtana Raminosa in central Sardinia.

2001 ◽  
Vol 4 (1) ◽  
pp. 113-130
Author(s):  
Noel Gale

The current consensus is outlined about the application of lead isotope analyses to metal provenance studies and to the unravelling of the Mediterranean Bronze Age copper trade, with special reference to copper oxhide ingots. Various misconceptions, especially some of those contained in Knapp (1999, 2000), are corrected. It is shown that there is no need to fall back on hypotheses based upon the Mediterranean-wide mixing/recycling of copper metals to explain the lead isotope characteristics of post-1250 BC copper oxhide ingots, since there is a good isotopic coincidence between these ingots and the Apliki region ore deposits in Cyprus. Weaknesses are exposed in the hypotheses of direct or indirect pooling of Cypriot ores, and of the proposed widespread recycling of metals in a Mediterranean-widekoine, particularly since there is no evidence for a homogeneity of lead isotope composition in artefacts and no tin in the oxhide ingots.


Nature ◽  
1973 ◽  
Vol 244 (5412) ◽  
pp. 165-167 ◽  
Author(s):  
W. I. MANTON

Minerals ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 61 ◽  
Author(s):  
Marija Dmitrijeva ◽  
Nigel J. Cook ◽  
Kathy Ehrig ◽  
Cristiana L. Ciobanu ◽  
Andrew V. Metcalfe ◽  
...  

Pyrite is the most common sulphide in a wide range of ore deposits and well known to host numerous trace elements, with implications for recovery of valuable metals and for generation of clean concentrates. Trace element signatures of pyrite are also widely used to understand ore-forming processes. Pyrite is an important component of the Olympic Dam Cu–U–Au–Ag orebody, South Australia. Using a multivariate statistical approach applied to a large trace element dataset derived from analysis of random pyrite grains, trace element signatures in Olympic Dam pyrite are assessed. Pyrite is characterised by: (i) a Ag–Bi–Pb signature predicting inclusions of tellurides (as PC1); and (ii) highly variable Co–Ni ratios likely representing an oscillatory zonation pattern in pyrite (as PC2). Pyrite is a major host for As, Co and probably also Ni. These three elements do not correlate well at the grain-scale, indicating high variability in zonation patterns. Arsenic is not, however, a good predictor for invisible Au at Olympic Dam. Most pyrites contain only negligible Au, suggesting that invisible gold in pyrite is not commonplace within the deposit. A minority of pyrite grains analysed do, however, contain Au which correlates with Ag, Bi and Te. The results are interpreted to reflect not only primary patterns but also the effects of multi-stage overprinting, including cycles of partial replacement and recrystallisation. The latter may have caused element release from the pyrite lattice and entrapment as mineral inclusions, as widely observed for other ore and gangue minerals within the deposit. Results also show the critical impact on predictive interpretations made from statistical analysis of large datasets containing a large percentage of left-censored values (i.e., those falling below the minimum limits of detection). The treatment of such values in large datasets is critical as the number of these values impacts on the cluster results. Trimming of datasets to eliminate artefacts introduced by left-censored data should be performed with caution lest bias be unintentionally introduced. The practice may, however, reveal meaningful correlations that might be diluted using the complete dataset.


2017 ◽  
Vol 36 (3) ◽  
pp. 421-425 ◽  
Author(s):  
Guangliang Wu ◽  
Jian-Ming Zhu ◽  
Decan Tan ◽  
Guilin Han ◽  
Lixing Zhang ◽  
...  

1957 ◽  
Vol 52 (8) ◽  
pp. 914-922 ◽  
Author(s):  
J. Laurence Kulp ◽  
G. C. Amstutz ◽  
F. Donald Eckelmann

1973 ◽  
Vol 10 (5) ◽  
pp. 670-678 ◽  
Author(s):  
W. D. Small

Isotopic composition of ore leads from four districts in northeastern Washington has been measured with a precision in the ratios of about 0.1‰. Results indicate that the mineralization in the Marshall Diorites of Pend Oreille County is by a primary type lead with a model age of about 1300 to 1500 m.y. The remainder of the measured leads from Pend Oreille and Stevens Counties have a radiogenic component which could have developed in a closed system during the interval 1370 to about 250 m.y. ago. Leads from Ferry and Okanogan Counties have only slight variations in their isotopic abundances. These latter leads could have been produced by an homogenization of the leads from Pend Oreille and Stevens Counties through the mechanism of a late Mesozoic metamorphism of Mesozoic sedimentary structures in Ferry and Okanogan Counties, these latter sedimentary structures being the products of erosion of rocks in Pend Oreille and Stevens Counties. There is no evidence of an ancient basement structure under Ferry and Okanogan Counties from the data presented herein. The lead isotope composition of the ores from northeastern Washington is compatible with the current concepts of the crustal structure across the Canadian Cordillera.


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