scholarly journals The Surface of Copper-Nickel Catalyst. II. Adsorption of Hydrogen on Copper, Nickel, and Copper-Nickel Catalysts

1957 ◽  
Vol 30 (2) ◽  
pp. 182-186 ◽  
Author(s):  
Toyosaburo Takeuchi ◽  
Masakazu Sakaguchi
1998 ◽  
Vol 63 (11) ◽  
pp. 1945-1953 ◽  
Author(s):  
Jiří Hanika ◽  
Karel Sporka ◽  
Petr Macoun ◽  
Vladimír Kysilka

The activity of ruthenium, palladium, and nickel catalysts for the hydrogenation of 1,2-dihydroacenaphthylene in cyclohexane solution was studied at temperatures up to 180 °C and pressures up to 8 MPa. The GC-MS technique was used to identify most of the perhydroacenaphthylene stereoisomers, whose fractions in the product were found dependent on the nature of the active component of the catalyst. The hydrogenation was fastest on the palladium catalyst (3% Pd/C). The nickel catalyst Ni-NiO/Al2O3, which is sufficiently active also after repeated use, can be recommended for practical application. The activation energy of 1,2-dihydroacenaphthylene hydrogenation using this catalyst is 17 kJ/mol, the reaction order with respect to hydrogen is unity.


2017 ◽  
Vol 8 (18) ◽  
pp. 2785-2795 ◽  
Author(s):  
Xinxin Wang ◽  
Linlin Fan ◽  
Yanping Ma ◽  
Cun-Yue Guo ◽  
Gregory A. Solan ◽  
...  

Elastomeric polyethylenes, with good elastic recovery and high elongation at break, have been prepared using a new family of unsymmetrical α-diimino-nickel catalysts that display high activities and high thermal stability.


Materials ◽  
2019 ◽  
Vol 12 (18) ◽  
pp. 2918 ◽  
Author(s):  
Sanchis ◽  
García ◽  
Dejoz ◽  
Vázquez ◽  
Llopis ◽  
...  

Different nickel catalysts have been tested for the transformation of levulinic acid into γ-valerolactone using an easy hydrothermal method, taking advantage of the properties of the high temperature water. A metallic nickel catalyst derived from NiO synthesized by a nanocasting procedure can achieve a productivity to γ-valerolactone, which is two orders of magnitude higher than that obtained by a commercial nickel catalyst. This nanocasted metallic nickel catalyst has shown bifunctionality as it is capable of activating water as the source for hydrogen and undertaking the further hydrogenation step. In contrast with metallic nickel, nickel oxide has shown to be incapable of transforming levulinic acid into γ-valerolactone.


Author(s):  
George L. Bauerle ◽  
Lee L. C. Sorensen ◽  
Ken Nobe

2015 ◽  
Vol 278 ◽  
pp. 46-54 ◽  
Author(s):  
A. Kumar ◽  
A. Cross ◽  
K. Manukyan ◽  
R.R. Bhosale ◽  
L.J.P. van den Broeke ◽  
...  

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