Robust and Highly Stretchable Chitosan Nanofiber/Alumina-Coated Silica/Carboxylated Poly (Vinyl Alcohol)/Borax Composite Hydrogels Constructed by Multiple Crosslinking

We investigated the mechanical and structural properties of composite hydrogels composed of chitosan nanofiber (ChsNF), positively charged alumina-coated silica (ac-SiO2) nanoparticles, carboxylated poly (vinyl alcohol) (cPVA), and borax. ChsNF/cPVA/borax hydrogels without ac-SiO2 exhibited high Young’s modulus but poor elongation, whereas cPVA/ac-SiO2/borax hydrogels without ChsNF had moderate Young’s modulus but high elongation. ChsNF/ac-SiO2/cPVA/borax hydrogels using both ChsNF and ac-SiO2 as reinforcement agents exhibited high extensibility (930%) and high Young′s modulus beyond 1 MPa at a high ac-SiO2 concentration. The network was formed by multiple crosslinking such as the complexation between borate and cPVA, the ionic complexation between ac-SiO2 and cPVA, and the hydrogen bond between ChsNF and cPVA. Structural analysis by synchrotron small-angle X-ray scattering revealed that the nanostructural inhomogeneity in ChsNF/ac-SiO2/cPVA/borax hydrogel was suppressed compared to those of the ChsNF/cPVA/borax and cPVA/ac-SiO2/borax hydrogels.

Modulation of Multiple Precipitates for High Strength and Ductility in Al-Cu-Mn Alloy

The category and morphology of precipitates are essential factors in determining the mechanical behaviors of aluminum alloys. It is a great challenge to synthetically modulate multiple precipitates to simultaneously improve strength and ductility. In the present work, by optimizing the precipitations of the GP zone, θ’-approximant and θ’ phase for an Al-Cu-Mn alloy, a high tensile strength of 585 MPa with large elongation of 12.35% was achieved through pre-deformation and aging. The microstructure evolution pattern was revealed by detailed characterizations of scanning electron microscopy and transmission electron microscopy. It was found that such high tensile strength of the samples was due to a combination of strengthening by the high density of dispersive fine precipitates and dislocations, and the high elongation to failure was primarily attributed to the multimodal precipitates and elimination of precipitation-free zones along the grain boundaries. The strategy proposed here is a promising way of preparing ultra-strong Al-Cu-Mn alloys.

Studying of a sensitive material based on Ecoflex and CNTs for flexible strain sensors

Nowadays there is a great need for the development of flexible strain sensors that can register human body’s movements. In the field of wearable and smart electronics such sensors are actively being developed. Resistive-type flexible sensors are the easiest to manufacture. Their mechanism of sensitivity to deformations is based on a change in electrical resistance during deformations. In this work, we have developed the functional material for strain sensor with high tensile properties, strength and electrical conductivity. This material based on a matrix of silicone elastomer and a multi-walled carbon nanotubes (MCNTs) filler. The material showed a high elongation of 950 % with a tensile strength of 1.437 MPa. The manufacturing process included laser structuring of MCNTs to form an electrically conductive network. The linear gauge factor was 3.4, and the angular gauge factor was 0.26.

Microstructural Evolution and Tensile Testing of a Bi–Sn (57/43) Alloy Processed by Tube High-Pressure Shearing

Tube high-pressure shearing (t-HPS) processing was performed on a eutectic Bi–Sn (57/43) alloy for 0.25, 1, 5 and 20 turns. The selected samples were stored at room temperature for up to 56 days to examine the strain weakening and self-annealing behavior of the alloy. The results showed that t-HPS processing gradually refined the microstructure and led to decreasing of microhardness, but microhardness increased slowly during the subsequent storage at room temperature. Shear localization of the eutectic structure during t-HPS processing was observed as large amounts of narrow dense lamellar zones were visible in the deformed microstructures. The Bi–Sn (57/43) alloy processed by t-HPS exhibited significantly enhanced superplastic properties with elongations up to >1800% in a sample after t-HPS processing for 20 turns. This high elongation is attributed to the breaking of the lamellar structure and the very small grain size.

Durability of Road and Bridge Concrete and Spray-Coating Waterproof Material

Different from traditional waterproof methods for road and bridge concrete, the spray-coating waterproof material can effectively prevent rainwater and other corrosive liquids from entering the concrete structure, and it has a few functional advantages such as anti-carbonization, resistance to sulfate attack, and high elongation. Existing studies have discussed the impact of the microstructure of waterproof material on the structure of waterproof coating, the optimization of the mix ratios of waterproof material, and the influencing factors of the waterproof performance of waterproof material, etc., however, few researches have concerned about the mechanical properties of concrete after coated with the spray-coating waterproof material. Therefore, to fill in this research gap, this paper researched the durability of road and bridge concrete and the spray-coating waterproof material. At first, it analyzed the bridge deck water pressure and the internal force of the drain pipe structure under multiple drainage methods, and calculated the water pressure at the gutter inlet, the stress, and the permeability coefficient of the waterproof coating. Then, this paper elaborated on the experimental methods for measuring the durability of the road and bridge before and after coated with the spray-coating waterproof material, and introduced the methods for testing the waterproof material and the concrete. At last, this paper gave the corresponding experimental results, the analysis, and the conclusion.

Ballistic performance of composite structure configurations with high elongation calendered rubber layer laminated to AA5083-H112 aluminum alloy

This study aims to determine the ballistic performances of laminated composite plates produced with AA5083-H112 series aluminum and rubber material with high elongation capacity under impact loading. To investigate the effect of rubber compounds, two types of rubber with calendered and damping were prepared. Thanks to the surface treatment applied to the aluminum plates, the rubber–metal adhesion strength was adjusted, and four different laminated composite plate samples were prepared. Calendered rubber was used on the bullet impact surface of all samples, and damping rubber was used on the back. It has been observed that the pressure barrier created by the calendered rubber bullet on the front face provides high performance to absorb energy. A detailed study was carried out on the total thickness of laminated composite plates, the interface adhesion strength between rubber and aluminum layers, and the ballistic performance of aluminum-rubber combinations. It was concluded that the laminated composite plate’s energy absorption would increase, especially by increasing the thickness of the dumping rubber layer on the back of the aluminum sheets. In the strong metal-rubber interface interaction between the rubber and aluminum layer, the bullet is stopped before the pressure barrier is formed. The penetration depth and bulging height increase, and most of the energy are transmitted through the aluminum plate. In the weak metal-rubber interface interaction, a significant portion of the energy is absorbed by the rubber and air thanks to the pressure barrier.

Water-Induced Breaking of Interfacial Cohesiveness in a Poly(lactic acid)/Miscanthus Fibers Biocomposite

The impact of the immersion in water on the morphology and the thermomechanical properties of a biocomposite made of a matrix of poly (lactic acid) (PLA) modified with an ethylene acrylate toughening agent, and reinforced with miscanthus fibers, has been investigated. Whereas no evidence of hydrolytic degradation has been found, the mechanical properties of the biocomposite have been weakened by the immersion. Scanning electron microscopy (SEM) pictures reveal that the water-induced degradation is mainly driven by the cracking of the fiber/matrix interface, suggesting that the cohesiveness is a preponderant factor to consider for the control of the biocomposite decomposition in aqueous environments. Interestingly, it is observed that the loss of mechanical properties is aggravated when the stereoregularity of PLA is the highest, and when increasing the degree of crystallinity. To investigate the influence of the annealing on the matrix behavior, crystallization at various temperatures has been performed on tensile bars of PLA made by additive manufacturing with an incomplete filling to enhance the contact area between water and polymer. While a clear fragilization occurs in the material crystallized at high temperature, PLA crystallized at low temperature better maintains its properties and even shows high elongation at break likely due to the low size of the spherulites in these annealing conditions. These results show that the tailoring of the mesoscale organization in biopolymers and biocomposites can help control their property evolution and possibly their degradation in water.

Balancing Strength and Ductility in Al Matrix Composites Reinforced by Few-Layered MoS2 through In-Situ Formation of Interfacial Al12Mo

In this work, few-layered MoS2 (FLM) nanosheet-reinforced Al matrix composites are developed through powder metallurgy and hot extrusion. The microstructure, mechanical properties, and strengthening mechanisms have been systematically investigated. It is found that Al12Mo and Al2S3 can be formed in-situ during the sintering process, resulting in the improvement of interfacial bonding between FLM and Al matrix. With 1.5 wt.% of FLM addition, an improved tensile strength of 234 MPa with a high elongation of 17% can be obtained. Moreover, the strengthening mechanisms are also demonstrated to be grain refinement, dislocation strengthening, and load transfer, and the calculation indicates that load transfer is the main contribution factor. This work will inspire more new designs of metal matrix composites with balanced strength and ductility.