Specifies of tandem organic solar cells using optical spacers with recombination model

2015 ◽  
Vol 12 (1) ◽  
pp. 77-82 ◽  
Author(s):  
M.R. Merad Boudia ◽  
A Cheknane ◽  
B Benyoucef

A numerical simulation study of a Tandem solar cell is presented. The parameters of single and two-diodes lumped-circuit model are usually the saturation current, the series resistance, the ideality factor, the shunt resistance and the photocurrent. It is found that the influence of the distributed series resistance on electrical characteristics can be described numerically by the application of the two models to Tandem organic solar cells. A description of the efficiency, fill factor, open circuit voltage and short circuit current on the devices are marked with series resistance, temperature and ideality factor. This approach allows one to obtain a set of parameters which is reasonable and representative of the physical system.

Author(s):  
Nur Shakina Mohd Shariff ◽  
Puteri Sarah Mohamad Saad ◽  
Mohamad Rusop Mahmood

There has been an increasing interest towards organic solar cells after the discovery of conjugated polymer and bulk-heterojunction concept. Eventhough organic solar cells are less expensive than inorganic solar cells but the power conversion energy is still considered low. The main objective of this research is to investigate the effect of the P3HT’s thickness and concentration towards the efficiency of the P3HT:Graphene solar cells. A simulation software that is specialize for photovoltaic called SCAPS is used in this research to simulate the effect on the solar cells. The solar cell’s structure will be drawn inside the simulation and the parameters for each layers is inserted. The result such as the open circuit voltage (Voc), short circuit current density (Jsc), fill factor (FF), efficiency (η), capacitance-voltage (C-V) and capacitance-frequency (C-f) characteristic will be calculated by the software and all the results will be put into one graph.


2015 ◽  
Vol 25 (2) ◽  
pp. 139
Author(s):  
Tran Thi Thao ◽  
Vu Thi Hai ◽  
Nguyen Nang Dinh ◽  
Le Dinh Trong

By using spin-coating technique, a low bandgap conjugated polymer, poly[2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopen-ta[2,1-b;3,4-b′]dithiophene)-alt-4,7-(2,1,3-benzothiadiazole)] (PCPDTBT)  and its composite thin films have been prepared. The optical absorption and photoconductive properties with over a wide spectral range, from 350 to 950  nm, were characterized. The obtained results showed that PCPDTBT:10 wt% CdSe  composite is the most suitable for efficient light-harvesting in polymer-based photovoltaic cells. The photoelectrical conversion efficiency (PCE) of the device with  a multilayer structure of ITO/PEDOT/ PCPDTBT:CdSe /LiF/Al  reached a value as large as 1.34% with an open-circuit voltage (Voc) = 0.57 V, a short-circuit current density (Jsc) = 4.29 mA/cm2, and a fill factor (FF) = 0.27. This suggests a useful application in further fabrication of quantum dots/polymers based solar cells.


Author(s):  
Xiaosha Wang ◽  
Honggang Chen ◽  
Jun Yuan ◽  
Qingya Wei ◽  
Jing Li ◽  
...  

Three polymer donors named Qx-8F, Qx-10F, and Qx-12F, with similar chemical structures, was synthesized. The energy level of these donors is manipulated by precisely controlling the fluorination sites. We demonstrate...


2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Zhen Zhan ◽  
Jing Cao ◽  
Weiguang Xie ◽  
Lintao Hou ◽  
Qin Ye ◽  
...  

Vanadium pentoxideV2O5was inserted between the donor layer and the anode as a hole-extracting nanolayer. Compared with devices without a hole-extracting layer, short-circuit current density (JSC), open-circuit voltage (VOC), fill factor (FF), and power conversion efficiency (PCE) of rubrene/C70-based heterojunction solar cells with 3 nm V2O5nanolayer are enhanced by 99%, 73%, 20%, and 310%, respectively. We found that V2O5interlayer can effectively suppress the contact resistance and increase the hole transport capability. The dependence of the device performance on V2O5layer thickness as well as fill factor on exciton dissociation and charge transport was also investigated in detail.


RSC Advances ◽  
2015 ◽  
Vol 5 (27) ◽  
pp. 20724-20733 ◽  
Author(s):  
Daobin Yang ◽  
Youqin Zhu ◽  
Yan Jiao ◽  
Lin Yang ◽  
Qianqian Yang ◽  
...  

N,N-Diarylamino end-capping strategy for asymmetrical squaraines with simultaneously enhanced Voc, Jsc and FF in solution-processed small molecule organic solar cells.


2013 ◽  
Vol 665 ◽  
pp. 330-335 ◽  
Author(s):  
Ripal Parmar ◽  
Dipak Sahay ◽  
R.J. Pathak ◽  
R.K. Shah

The solar cells have been used as most promising device to convert light energy into electrical energy. In this paper authors have attempted to fabricate Photoelectrochemical solar cell with semiconductor electrode using TMDCs. The Photoelectrochemical solar cells are the solar cells which convert the solar energy into electrical energy. The photoelectrochemical cells are clean and inexhaustible sources of energy. The photoelectrochemical solar cells are fabricated using WSe2crystal and electrolyte solution of 0.025M I2, 0.5M NaI, 0.5M Na2SO4. Here the WSe2crystals were grown by direct vapour transport technique. In our investigations the solar cell parameters like short circuit current (Isc) and Open circuit voltage (Voc) were measured and from that Fill factor (F.F.) and photoconversion efficiency (η) are investigated. The results obtained shows that the value of efficiency and fill factor of solar cell varies with the illumination intensities.


Energies ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 450 ◽  
Author(s):  
Miron Krassas ◽  
Christos Polyzoidis ◽  
Pavlos Tzourmpakis ◽  
Dimitriοs M. Kosmidis ◽  
George Viskadouros ◽  
...  

A conjugated, ladder-type multi-fused ring 4,7-dithienbenzothiadiazole:thiophene derivative, named as compound ‘T’, was for the first time incorporated, within the PTB7:PC71BM photoactive layer for inverted ternary organic solar cells (TOSCs) realization. The effective energy level offset caused by compound T between the polymeric donor and fullerene acceptor materials, as well as its resulting potential as electron cascade material contribute to an enhanced exciton dissociation, electron transfer facilitator and thus improved overall photovoltaic performance. The engineering optimization of the inverted TOSC, ITO/PFN/PTB7:Compound T(5% v/v):PC71BM/MoO3/Al, resulted in an overall power conversion efficiency (PCE) of 8.34%, with a short-circuit current density (Jsc) of 16.75 mA cm−2, open-circuit voltage (Voc) of 0.74 V and a fill factor (FF) of 68.1%, under AM1.5G illumination. This photovoltaic performance was improved by approximately 12% with respect to the control binary device.


2020 ◽  
Vol 20 (6) ◽  
pp. 3703-3709 ◽  
Author(s):  
S. S. Rawat ◽  
Ashish Kumar ◽  
R. Srivastava ◽  
C. K. Suman

Cobalt phthalocyanine (CoPc) nano thin films have been introduced as a hole buffer layer in organic solar cells with active layer of Poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM). The surface morphology and opto-electrical properties of the CoPc thin films have made it an applicable materials for organic solar cells. The nano-thin films of CoPc are continuously distributed over the studied area and the roughness are around 5 to 7 nm for all thickness. The dominant optical absorptions are in the visible range of wavelengths 500 to 800 nm. The CoPc buffer layer is suitable for energy level matching in energy level diagram and enhances the absorption spectrum as well, which facilitate the charge carrier generation, increases charge transport, decreases charge recombination, hence enhance the all device parameters short circuit current density (Jsc), open circuit voltage (Voc) and fill factor (FF). The solar cells efficiency increases by ˜70% and the fill factor increases by ˜45% in comparison to the standard cells. The increase in efficiency and the fill factors of the solar cells may also be attributed to the increasing of shunt and lowering the series resistance of the cells. The cole–cole plots of the devices may be modeled in electrical circuit as a single parallel resistance Rb and capacitance Cb network with a series resistance Rc.


2011 ◽  
Vol 10 (04n05) ◽  
pp. 803-807
Author(s):  
T. S. KRISHNAN ◽  
S. SUNDAR KUMAR IYER

This work addresses the shelf life characteristics of P3HT: PCBM blend based organic solar cells (OSC) fabricated with Ca–Al and LiF–Al cathodes. Some of these devices are encapsulated in nitrogen ambient and some in room ambient. Device electrical characteristics are studied under both dark and light. In the analysis under dark ambient conditions, the degradation in peak dark current is monitored over time (in days) and an empirical model is postulated for the degradation based on statistical curve fitting techniques. In the analysis under light, degradation of parameters such as fill factor (FF), open circuit voltage (V oc ) and short circuit current density (J sc ) is monitored over time in these devices (for different cathodes and different ambients) and the results are analyzed and compared. Also, accelerated stress tests are conducted wherein the devices are subjected to continuous illumination for a period of 1.5 h under two different intensities (0.76 sun and 1 sun) and again, the results are analyzed and compared. A model is fitted to the observed degradation in normalized J sc and the degradation constants (k deg ) are obtained. It is seen that the devices fabricated with cathode as LiF–Al and being encapsulated in nitrogen ambient provide the best performance over time.


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