scholarly journals Dowex 50W: A Green Mild Reusable Catalyst for the Synthesis of 2-Aryl Benzoxazole Derivatives in Aqueous Medium

2021 ◽  
Vol 37 (2) ◽  
pp. 341-347
Author(s):  
Arup Datta

In this work simple efficient, one pot and environmentally friendly method was developed for the synthesis of 2-Aryl-1H-benzoxazole derivatives at 80º C using ortho-aminophenol and various aldehydes. It has been found that Dowex50W is an effective catalyst to prepare moderate to high yield of a variety of benzoxazole derivatives through a clean and simple process. Aqueous medium, green methodology, rapid reaction, reusability of heterogeneous catalyst are the great advantages of this protocol.

ChemInform ◽  
2014 ◽  
Vol 45 (41) ◽  
pp. no-no
Author(s):  
Swarbhanu Sarkar ◽  
Nivedita Chatterjee ◽  
Manas Roy ◽  
Rammyani Pal ◽  
Sabyasachi Sarkar ◽  
...  

RSC Advances ◽  
2019 ◽  
Vol 9 (50) ◽  
pp. 29405-29413
Author(s):  
María Sol Ballari ◽  
Natividad Herrera Cano ◽  
Daniel A. Wunderlin ◽  
Gabriela E. Feresin ◽  
Ana N. Santiago

New antifungal agrochemicals, derived from 2-(benzylsulfonyl)benzothiazole were synthesized by an environmentally friendly method, using water as reaction medium.


RSC Advances ◽  
2016 ◽  
Vol 6 (25) ◽  
pp. 20687-20694 ◽  
Author(s):  
R. Tayebee ◽  
B. Maleki ◽  
F. M. Zonoz ◽  
R. M. Kakhki ◽  
T. Kunani

H7[(P2W17O61)FeIII(H2O)] is introduced as an effective catalyst for the one-pot synthesis ofN,N′-alkylidenebisamides. The catalyst could be easily separated without noticeable reduction in activity.


2017 ◽  
Vol 19 (23) ◽  
pp. 5683-5690 ◽  
Author(s):  
Giovanna Bosica ◽  
Roderick Abdilla

An environmentally friendly one-pot multicomponent synthesis of 3-substituted indoles, catalysed by silicotungstic acid on Amberlyst 15 under green, neat conditions.


2021 ◽  
Vol 11 (1) ◽  
pp. 3208-3217

An environmentally friendly one-pot three-component strategy synthesizing a series of 2-Amino-5-oxo-4,5-dihydropyrano[3,2-c]chromene-3-carbonitrile derivatives has been successfully performed in water. The products were obtained through conventional and microwave irradiation, which involving aldehyde, malononitrile, and 4-hydroxy coumarin, resulting in a green synthetic protocol with a high atom economy. The reaction was catalyzed by a water-soluble and reusable catalyst, i.e., cobalt doped iron (III) tartrate complex. The catalyst was recovered and efficiently reused.


2017 ◽  
Vol 14 (6) ◽  
pp. 904-911 ◽  
Author(s):  
Ramin Ghorbani-Vaghei ◽  
Jafar Mahmoodi ◽  
Yaser Maghbooli ◽  
Azadeh Shahriari

Background: The synthesis of 3,4-dihydropyrano[3,2-c]chromenes via the one-pot three-component reactions of various aldehydes, malononitrile, and 4-hydroxycumarin at 60 °C in water as a solvent by the magnetic nanoparticles tag: piperidinium benzene-1,3-disulfonate ionic liquid as a green and efficient catalyst. Some benefits of the presented technique are significant cost impact, impressive catalysis and the ability to reuse of the catalyst. The current procedure offers high yield, short reaction times, neat reaction and simple reusable catalyst. Objective: A magnetic nanoparticles tag: piperidinium benzene-1,3-disulfonate ionic liquid as a green, efficient, reusable and heterogeneous catalyst was used for the synthesis of 3,4-dihydropyrano[3,2-c]chromenes. Method: We have described an efficient and green process for the synthesis of the one-pot three-component synthesis of 3,4-dihydropyrano[3,2-c]chromenes from the reaction between 4-hydroxy-coumarin with malononitrile and aldehydes in the presence of catalytic amount of magnetic nanoparticles tag: piperidinium benzene-1,3-disulfonate ionic liquid as a novel and powerful nano ionic liquid with good to excellent yields and in a short reaction time in water solvent at 60 °C. Result: The main advantage of this process is the simplicity of the work-up and the products can be isolated without chromatography. Conclusion: We suggest that the method has also various additional advantages such as low loading of catalyst, clean reaction, which makes it a suitable and noteworthy approach for the synthesis of 3,4- dihydropyrano[3,2-c]chromenes.


2015 ◽  
Vol 3 (45) ◽  
pp. 11945-11952 ◽  
Author(s):  
Wei Lyu ◽  
Jiangtao Feng ◽  
Wei Yan ◽  
Charl FJ Faul

An environmentally friendly method is developed to explore the self-assembly of Ph/NH2-capped tetra(aniline) nanowires in acidic aqueous medium with ultrasonic irradiation.


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