Raman spectroscopy study of Hydrogen Plasma Treatment effect on a single layer Graphene/MoS2 hybrid structure

Author(s):  
Anishkumar Soman ◽  
Jianping Shi ◽  
Ugochukwu Nsofor ◽  
Steven Hegedus ◽  
Yanfeng Zhang ◽  
...  
2011 ◽  
Vol 1336 ◽  
Author(s):  
Amirhasan Nourbakhsh ◽  
Mirco Cantoro ◽  
Tom Vosch ◽  
Geoffrey Pourtois ◽  
Johan Hofkens ◽  
...  

ABSTRACTWe investigate the structural, optical and electrical properties of single-layer graphene exposed to oxygen plasma treatment. We find that the pristine semimetallic behavior of graphene disappears upon plasma treatment, in favour of the opening of a bandgap and the featuring of semiconducting properties. The metal-to-semiconductor transition observed appears to be dependent on the plasma treatment time. The semiconducting behavior is also confirmed by photoluminescence measurements. The opening of a bandgap in graphene is explained in terms of graphene surface functionalization with oxygen atoms, bonded as epoxy groups. Ab initio calculations of the density of states show more details about the oxygen–graphene interaction and its effects on the graphene optoelectronic properties, predicting no states near the Fermi level at increasing epoxy group density. The structural changes are also monitored by Raman spectroscopy, showing the progressive evolution of the sp2 character of pristine graphene to sp3, due to the lattice decoration with out-of-plane epoxy groups.


2016 ◽  
Vol 52 (53) ◽  
pp. 8227-8230 ◽  
Author(s):  
Weitao Su ◽  
Naresh Kumar ◽  
Ning Dai ◽  
Debdulal Roy

Non-gap TERS with a contrast of 8.5 enables TERS mapping of graphene's intrinsic defect with a spatial resolution of 20 nm.


2019 ◽  
Vol 114 (16) ◽  
pp. 161907
Author(s):  
Y. Shen ◽  
E. Dai ◽  
X. Liu ◽  
W. Pan ◽  
H. Yang ◽  
...  

Carbon ◽  
2015 ◽  
Vol 90 ◽  
pp. 53-62 ◽  
Author(s):  
Jie Jiang ◽  
Ruth Pachter ◽  
Faisal Mehmood ◽  
Ahmad E. Islam ◽  
Benji Maruyama ◽  
...  

2010 ◽  
Vol 10 (11) ◽  
pp. 7481-7484 ◽  
Author(s):  
Caiyu Qiu ◽  
Haiqing Zhou ◽  
Minjiang Chen ◽  
Zheng Liu ◽  
Lianfeng Sun

2010 ◽  
Vol 645-648 ◽  
pp. 565-568 ◽  
Author(s):  
Rositza Yakimova ◽  
Chariya Virojanadara ◽  
Daniela Gogova ◽  
Mikael Syväjärvi ◽  
D. Siche ◽  
...  

We are aiming at understanding the graphene formation mechanism on different SiC polytypes (6H, 4H and 3C) and orientations with the ultimate goal to fabricate large area graphene (up to 2 inch) with controlled number of monolayers and spatial uniformity. To reach the objectives we are using high-temperature atmospheric pressure sublimation process in an inductively heated furnace. The epitaxial graphene is characterized by ARPES, LEEM and Raman spectroscopy. Theoretical studies are employed to get better insight of graphene patterns and stability. Reproducible results of single layer graphene on the Si-face of 6H and 4H-SiC polytypes have been attained. It is demonstrated that thickness uniformity of graphene is very sensitive to the substrate miscut.


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