Feasibility Study of Raman Spectroscopy as a Tool to Investigate the Liquid-Phase Chemistry of Aliphatic Organic Peroxides
Keyword(s):
The described investigations are focused on peroxides occurring as products in atmospheric chemical processes, namely, hydrogen peroxide, methylhydroperoxide, hydroxymethylhydroperoxide, bis-(hydroxymethyl)peroxide, 1-hydroxyethylhydroperoxide, bis-(hydroxyethyl)peroxide, and hydroxymethylmethylperoxide. The compounds are identified and determined through the position and intensity of their characteristic O–O stretching bands in the range between 767 and 878 cm−1. Time-resolved Raman spectroscopy of peroxide solutions permits the in situ investigation of pathways and kinetics of reactions between peroxides and aldehydes.
2016 ◽
Vol 16
(12)
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pp. 7218-7230
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Keyword(s):
2014 ◽
Vol 54
(6)
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pp. 1799-1802
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1999 ◽
Vol 121
(50)
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pp. 11875-11879
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2016 ◽
Vol 88
(11)
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pp. 1684-1692
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