An in Situ Radiolysis Time-Resolved ESR Study of the Kinetics of Spin Trapping by 5,5-Dimethyl-1-pyrroline-N-oxide

1999 ◽  
Vol 121 (50) ◽  
pp. 11875-11879 ◽  
Author(s):  
Hitoshi Taniguchi ◽  
Keith P. Madden
Keyword(s):  
Spin Trapping ◽  
Time Resolved ◽  
Kinetics Of

In situ Time-Resolved Small-Angle X-ray Scattering Reveals the Formation Kinetics of Polyelectrolyte Complex Micelles

2019 ◽  
Author(s):  
Hao Wu ◽  
Jeffrey Ting ◽  
Siqi Meng ◽  
Matthew Tirrell
Keyword(s):  
Small Angle ◽  
Self Assembly ◽  
Electrostatic Interactions ◽  
Polyelectrolyte Complex ◽  
Time Resolved ◽  
X Ray ◽  
X Ray Scattering ◽  
Kinetics Of ◽  
Ray Scattering

We have directly observed the <i>in situ</i> self-assembly kinetics of polyelectrolyte complex (PEC) micelles by synchrotron time-resolved small-angle X-ray scattering, equipped with a stopped-flow device that provides millisecond temporal resolution. This work has elucidated one general kinetic pathway for the process of PEC micelle formation, which provides useful physical insights for increasing our fundamental understanding of complexation and self-assembly dynamics driven by electrostatic interactions that occur on ultrafast timescales.

scholarly journals In situ structural kinetics of picosecond laser-induced heating and fragmentation of colloidal gold spheres

2020 ◽  
Vol 22 (9) ◽  
pp. 4993-5001 ◽  
Author(s):  
Anna Rosa Ziefuss ◽  
Stefan Reich ◽  
Sven Reichenberger ◽  
Matteo Levantino ◽  
Anton Plech
Keyword(s):  
Colloidal Gold ◽  
Picosecond Laser ◽  
Time Resolved ◽  
Gold Colloids ◽  
X Ray ◽  
X Ray Scattering ◽  
Kinetics Of ◽  
Ray Scattering

The structural and energetic pathway of picosecond laser fragmentation of gold colloids has been clarified by time-resolved X-ray scattering.

Kinetics of Multi-Step Redox Processes by Time-Resolved In Situ X-ray Diffraction

2016 ◽  
Vol 88 (11) ◽  
pp. 1684-1692 ◽  
Author(s):  
Lukas C. Buelens ◽  
Vladimir V. Galvita ◽  
Hilde Poelman ◽  
Christophe Detavernier ◽  
Guy B. Marin
Keyword(s):  
Redox Processes ◽  
X Ray Diffraction ◽  
Time Resolved ◽  
X Ray ◽  
Kinetics Of

Time resolved growth of membrane stabilized silver NPs and their catalytic activity

RSC Advances ◽  
2014 ◽  
Vol 4 (103) ◽  
pp. 59379-59386 ◽  
Author(s):  
Sabyasachi Patra ◽  
Debasis Sen ◽  
Ashok K. Pandey ◽  
J. Bahadur ◽  
S. Mazumder ◽  
...  
Keyword(s):  
Silver Nanoparticles ◽  
Catalytic Activity ◽  
Growth Kinetics ◽  
Nanocomposite Membranes ◽  
Time Resolved ◽  
Catalytic Application ◽  
Silver Nps ◽  
First Time ◽  
Kinetics Of

Growth kinetics of membrane stabilized silver nanoparticles have been studied for the first time with time resolved in situ SAXS. The catalytic application of nanocomposite membranes thus formed has also been explored.

Feasibility Study of Raman Spectroscopy as a Tool to Investigate the Liquid-Phase Chemistry of Aliphatic Organic Peroxides

1997 ◽  
Vol 51 (1) ◽  
pp. 74-80 ◽  
Author(s):  
Peter Jacob ◽  
Bernhard Wehling ◽  
Wieland Hill ◽  
Dieter Klockow
Keyword(s):  
Hydrogen Peroxide ◽  
Raman Spectroscopy ◽  
Liquid Phase ◽  
Chemical Processes ◽  
Organic Peroxides ◽  
Time Resolved ◽  
In Situ Investigation ◽  
Phase Chemistry ◽  
Kinetics Of

The described investigations are focused on peroxides occurring as products in atmospheric chemical processes, namely, hydrogen peroxide, methylhydroperoxide, hydroxymethylhydroperoxide, bis-(hydroxymethyl)peroxide, 1-hydroxyethylhydroperoxide, bis-(hydroxyethyl)peroxide, and hydroxymethylmethylperoxide. The compounds are identified and determined through the position and intensity of their characteristic O–O stretching bands in the range between 767 and 878 cm−1. Time-resolved Raman spectroscopy of peroxide solutions permits the in situ investigation of pathways and kinetics of reactions between peroxides and aldehydes.

A time-resolved powder diffraction study of in-situ photodimerization kinetics of 9-methylanthracene using a CCD area detector and parametric Rietveld refinement

2012 ◽  
Vol 68 (4) ◽  
pp. 424-430 ◽  
Author(s):  
Ahmed F. Mabied ◽  
Melanie Müller ◽  
Robert E. Dinnebier ◽  
Shunsuke Nozawa ◽  
Manabu Hoshino ◽  
...  
Keyword(s):  
Rietveld Refinement ◽  
Powder Diffraction ◽  
Quantitative Phase Analysis ◽  
Time Resolved ◽  
Anthracene Derivative ◽  
Area Detector ◽  
Dimensional Growth ◽  
Kinetics Of ◽  
Dimerization Process

The [4π + 4π] photodimerization process of the 9-substituted anthracene derivative crystalline 9-methylanthracene (9-MA) was investigated using time-resolved X-ray powder diffraction. The study was carried out in-situ using a CCD area detector. Sequential and parametric Rietveld refinement was applied for quantitative phase analysis. The results of traditional sequential Rietveld refinement showed that the evolution of the dimerization process can be described using the Johnson–Mehl–Avrami–Kolmogorov (JMAK) model. The parameters of the JMAK equation were obtained successfully by parametric Rietveld refinement and suggest that the reaction follows heterogeneous nucleation and one-dimensional growth with a decreasing nucleation rate.

Influence of oxygen partial pressure on the kinetics of YBa2Cu3O7−x formation

1994 ◽  
Vol 9 (2) ◽  
pp. 275-285 ◽  
Author(s):  
V. Milonopoulou ◽  
K.M. Forster ◽  
J.P. Formica ◽  
J. Kulik ◽  
J.T. Richardson ◽  
...  
Keyword(s):  
X Ray Diffraction ◽  
Decomposition Products ◽  
Time Resolved ◽  
X Ray ◽  
Formation Kinetics ◽  
Dimensional Diffusion ◽  
Diffusion Controlled ◽  
Gas Atmosphere ◽  
Kinetics Of

The YBa2Cu3O7−x formation kinetics from a spray-roasted precursor powder containing Y2O3, BaCO3, and CuO was followed via in situ, time-resolved x-ray diffraction as a function of gas atmosphere and temperature. In inert atmospheres, BaCO3 and CuO form BaCu2O2 which subsequently reacts with Y2O3 to form YBa2Cu3O6. However, YBa2Cu3O6 decomposes at temperatures exceeding 725 °C with Y2BaCuO5 being one of the decomposition products. In oxidizing atmospheres, YBa2Cu3O7−x formation involves the BaCuO2. At high temperatures (800–840 °C), oxygen increases the yield of YBa2Cu3O6. A nuclei growth model assuming two-dimensional, diffusion-controlled growth with second-order nucleation rate fits the experimental data.

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