Application of a Spectroscopic Infrared Focal Plane Array Sensor for On-Line Identification of Plastic Waste

1997 ◽  
Vol 51 (6) ◽  
pp. 856-865 ◽  
Author(s):  
W. H. A. M. Van Den Broek ◽  
D. Wienke ◽  
W. J. Melssen ◽  
R. Feldhoff ◽  
T. Huth-Fehre ◽  
...  

A spectroscopic near-infrared imaging system, using a focal plane array (FPA) detector, is presented for remote and on-line measurements on a macroscopic scale. On-line spectroscopic imaging requires high-speed sensors and short image processing steps. Therefore, the use of a focal plane array detector in combination with fast chemometric software is investigated. As these new spectroscopic imaging systems generate so much data, multivariate statistical techniques are needed to extract the important information from the multidimensional spectroscopic images. These techniques include principal component analysis (PCA) and linear discriminant analysis (LDA) for supervised classification of spectroscopic image data. Supervised classification is a tedious task in spectroscopic imaging, but a procedure is presented to facilitate this task and to provide more insight into and control over the composition of the datasets. The identification system is constructed, implemented, and tested for a real-world application of plastic identification in municipal solid waste.

2008 ◽  
Vol 62 (11) ◽  
pp. 1200-1208 ◽  
Author(s):  
O. Kolomiets ◽  
U. Hoffmann ◽  
P. Geladi ◽  
H. W. Siesler

Over the last decade Fourier transform infrared (FT-IR) and near-infrared (NIR) spectroscopic imaging with focal plane array (FPA) detectors have proved powerful techniques for the rapid visualization of samples by a combination of spectroscopic and spatial information. Using these methods, selected sample areas can be analyzed with reference to the identification and localization of chemical species by FT-IR spectroscopy in the transmission or attenuated total reflection (ATR) mode and by NIR spectroscopy in diffuse reflection with a lateral resolution in the micrometer range. The present communication focuses on the quantitative determination of the active ingredient composition of a solid drug formulation by NIR spectroscopic imaging with a focal plane array detector and the results obtained are compared to the quantitative data obtained by conservative light-fiber NIR spectroscopic diffuse reflection measurements with a single-element detector. The communication also addresses the issue of penetration depth of NIR radiation into the investigated solid material.


1995 ◽  
Vol 49 (5) ◽  
pp. 672-678 ◽  
Author(s):  
E. Neil Lewis ◽  
Ira W. Levin

A different approach toward mid-infrared spectroscopic imaging microscopy is introduced in which instrumentation is designed about an InSb multichannel, focal-plane array detector and a variable-bandpass dielectric filter. The system may be configured for either macroscopic or microscopic applications, and high-fidelity, chemically specific images may be acquired in real time. With the dielectric filter used in this assembly, continuous tuning is provided for the infrared 4000–2320 cm−1 spectral region with spectral resolutions of approximately 35–18 cm−1 at the extremes of this wavelength interval. The functioning of the imaging microscope is demonstrated with samples including polystyrene microspheres, preparations of lipids and an amino acid embedded in KBr disks, and a tissue sample derived from a coronal slice of a monkey cerebellum.


1997 ◽  
Vol 51 (4) ◽  
pp. 563-567 ◽  
Author(s):  
E. Neil Lewis ◽  
Linda H. Kidder ◽  
John F. Arens ◽  
Michael C. Peck ◽  
Ira W. Levin

An instrument is described that simultaneously records images and spectra of materials in the infrared fingerprint region using a long-wavelength infrared focal-plane array detector, a step-scan Michelson interferometer, and an infrared microscope. With the combination of step-scan Fourier transform (FT) Michelson interferometry and arsenic-doped silicon (Si: As) focal-plane array image detection, an infrared spectroscopic imaging system has been constructed that maintains both an instrumental multiplex and multichannel advantage and operates from approximately 4000 to 400 cm−1. With this method of mid-infrared spectroscopic imaging, the fidelity of the generated spectral images recorded through the microscope is solely determined by the number of pixels on the focal-plane array detector, and only a few seconds of data acquisition time are required for spectral image acquisition. This seamless combination of spectroscopy for molecular analysis and the power of visualization represents the future of infrared microscopy. Step-scan imaging principles, the operation and characteristics of long-wavelength array detectors, and instrument design details are outlined, and infrared chemical imaging results are presented. The results are discussed with respect to their implications for the chemical analysis of a variety of solid-state materials.


1995 ◽  
Vol 67 (19) ◽  
pp. 3377-3381 ◽  
Author(s):  
E. Neil. Lewis ◽  
Patrick J. Treado ◽  
Robert C. Reeder ◽  
Gloria M. Story ◽  
Anthony E. Dowrey ◽  
...  

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