DETECTION OF NMR LARMOR AND DOUBLE LARMOR FREQUENCY OF PROTONS BY A SQUID

Keyword(s):  
Geophysics ◽  
2016 ◽  
Vol 81 (4) ◽  
pp. WB33-WB48 ◽  
Author(s):  
Denys Grombacher ◽  
Mike Müller-Petke ◽  
Rosemary Knight

To produce reliable estimates of aquifer properties using surface nuclear magnetic resonance (NMR), an accurate forward model is required. The standard surface NMR forward model assumes that excitation occurs through a process called on-resonance excitation, which occurs when the transmit frequency is set to the Larmor frequency. However, this condition is often difficult to satisfy in practice due to the challenge of accurately determining the Larmor frequency within the entire volume of investigation. As such, in situations where an undesired offset is present between the assumed and true Larmor frequency, the accuracy of the forward model is degraded. This is because the undesired offset leads to a condition called off-resonance excitation, which impacts the signal amplitude, phase, and spatial distribution in the subsurface, subsequently reducing the accuracy of surface NMR estimated aquifer properties. Our aim was to reduce the impact of an undesired offset between the assumed and true Larmor frequency to ensure an accurate forward model in the presence of an uncertain Larmor frequency estimate. We have developed a methodology where data are collected using two different transmit frequencies, each an equal magnitude above and below the assumed Larmor frequency. These data are combined, through a method we refer to as frequency cycling, in a manner that allow the component well-described by our estimate of the Larmor frequency to be stacked coherently, whereas the component related to the presence of an undesired offset is combined destructively. In synthetic and field studies, we have determined that frequency cycling is able to mitigate the influence of an undesired offset providing more accurate estimates of aquifer properties. Furthermore, the frequency-cycling method stabilized the complex inversion of surface NMR data, allowing advantages associated with complex inversion to be exploited.


2019 ◽  
Vol 85 (3) ◽  
Author(s):  
A. A. Schekochihin ◽  
Y. Kawazura ◽  
M. A. Barnes

It is shown that in low-beta, weakly collisional plasmas, such as the solar corona, some instances of the solar wind, the aurora, inner regions of accretion discs, their coronae and some laboratory plasmas, Alfvénic fluctuations produce no ion heating within the gyrokinetic approximation, i.e. as long as their amplitudes (at the Larmor scale) are small and their frequencies stay below the ion-Larmor frequency (even though their spatial scales can be above or below the ion Larmor scale). Thus, all low-frequency ion heating in such plasmas is due to compressive fluctuations (‘slow modes’): density perturbations and non-Maxwellian perturbations of the ion distribution function. Because these fluctuations energetically decouple from the Alfvénic ones already in the inertial range, the above conclusion means that the energy partition between ions and electrons in low-beta plasmas is decided at the outer scale, where turbulence is launched, and can be determined from magnetohydrodynamic (MHD) models of the relevant astrophysical systems. Any additional ion heating must come from non-gyrokinetic mechanisms such as cyclotron heating or the stochastic heating owing to distortions of ions’ Larmor orbits. An exception to these conclusions occurs in the Hall limit, i.e. when the ratio of the ion to electron temperatures is as low as the ion beta (equivalently, the electron beta is order unity). In this regime, slow modes couple to Alfvénic ones well above the Larmor scale (viz., at the ion inertial or ion sound scale), so the Alfvénic and compressive cascades join and then separate again into two cascades of fluctuations that linearly resemble kinetic Alfvén and ion-cyclotron waves, with the former heating electrons and the latter ions. The two cascades are shown to decouple, scalings for them are derived and it is argued physically that the two species will be heated by them at approximately equal rates.


1983 ◽  
Vol 38 (3) ◽  
pp. 317-321 ◽  
Author(s):  
E. Haid ◽  
D. Köhnlein ◽  
G. Kössler ◽  
O. Lutz ◽  
W. Messner ◽  
...  

Abstract45Sc NMR chemical shifts, linewidths, and longitudinal relaxation rates have been measured in aqueous solutions of scandium chloride and sulphate as a function of the appropriate acid. A common typical behaviour of these parameters without sudden changes has been observed. Also signals in the basic range have been obtained. H2O -D2O solvent isotope effects on Larmor frequency and relaxation rates are presented.


2020 ◽  
Vol 6 (1) ◽  
Author(s):  
D. Cohen ◽  
T. Gefen ◽  
L. Ortiz ◽  
A. Retzker

Abstract The ultimate precision limit in estimating the Larmor frequency of N unentangled qubits is well established, and is highly important for magnetometers, gyroscopes, and other types of quantum sensors. However, this limit assumes perfect projective measurements of the quantum registers. This requirement is not practical in many physical systems, such as NMR spectroscopy, where a weakly interacting external probe is used as a measurement device. Here, we show that in the framework of quantum nano-NMR spectroscopy, in which these limitations are inherent, the ultimate precision limit is still achievable using control and a finely tuned measurement.


1973 ◽  
Vol 28 (1-2) ◽  
pp. 59-62 ◽  
Author(s):  
G. Held ◽  
F. Noack ◽  
V. Pollak ◽  
B. Melton

The frequency dependence of the proton spin relaxation in muscle tissue shows that the mobility of the muscle water must be described by a continuous distribution of jumping times instead of the usually assumed two-phase model. Measurements on frog muscles (rana esculenta and rana pipiens, gastrocnemius) in the Larmor frequency range 3 kHz to 75 MHz can be understood quantitatively by a log-gaussian distribution, which supports a close relation to protein solutions.


1997 ◽  
Vol 52 (11) ◽  
pp. 757-764 ◽  
Author(s):  
M. T. Myaing ◽  
L. Šekarić ◽  
P. A. Beckmann

Abstract We have measured the temperature dependence of the proton spin-lattice relaxation rate R at 8.50 and 22.5 MHz in solid 1,3,5-tri-ethyl-benzene and solid 1,2,4-tri-ethyl-benzene. Analysis of the data strongly suggests that we are studying amorphous states in these slowly solidified organic solids (that are liquids at room temperature). The ethyl groups are static on the Larmor frequency time-scale. There are no simple-model interpretations of the data, but a reasonable model for the dominantly-occurring amorphous state data observed with 1,3,5-tri-ethyl-benzene suggests that two of the three methyl groups are reorienting and the third is static on the proton Larmor frequency time scale. The same approach for the two amorphous states observed in 1,2,4-tri-ethyl-benzene suggests that all three methyl groups are reorienting in one state and that three of the six methyl groups in each pair of molecules are turned off in a second state. We discuss that, whereas specific dynamical statements are model dependent, the proton spin relaxation technique does make some general qualitative statements about the mesostructure of the solid.


1990 ◽  
Vol 45 (9-10) ◽  
pp. 1077-1084 ◽  
Author(s):  
D. Pusiol ◽  
F. Noack ◽  
C. Aguilera

Abstract Field-cycling and standard pulsed NMR techniques have been used to study the frequency dependence of the longitudinal proton spin relaxation time T x in the crystalline estradiol compound (+)3,1,7-ß-bis-(4n-butoxybenzoyloxy)-estra-1,3,5-(10)-trien or BET, which is a mesogenic material with a chiral molecular structure. From the measured Larmor frequency and temperature depen-dences we conclude that, at low NMR frequencies in the cholesteric phase, T1 reflects in addition to the relaxation process familiar from nematic liquid crystals (director fluctuation modes) another slow mechanism theoretically predicted for cholesteric systems, namely diffusion induced rotational molecular reorientation. These relaxation processes are not or much less effective in the crystalline and glassy state, where they are frozen. Also the high NMR frequency relaxation dispersion strongly differs between the cholesteric mesophase and the not liquid crystalline samples. This is interpreted by a change from essentially translational self-diffusion to rotational diffusion controlled proton relaxation.


1973 ◽  
Vol 51 (9) ◽  
pp. 1005-1011 ◽  
Author(s):  
A. Watton ◽  
H. E. Petch ◽  
M. M. Pintar

Proton spin–lattice relaxation of the Zeeman reservoir in the laboratory and rotating frames and of the dipolar reservoir have been studied in ferroelectric colemanite. These studies indicate the presence of two relaxation mechanisms which can be related to motions of the water molecules. The first, referred to as the flip mode and identified with 180° flips of the water molecules about their H—O—H bisectrices, is characterized by a correlation time and U-shaped relaxation minimum expected for a normal thermally activated process. The second, referred to as the jump mode and associated with a structural configuration change, produces a cusp-shaped dip in the relaxation over a very small temperature range in the vicinity of the phase transition. Above the transition temperature, the jump mode frequency is higher than the Larmor frequency and the relaxation behavior is that expected for two thermally activated processes in the white spectral region. However, in the vicinity of the phase transition, the water molecules are tightly coupled to the structure as a whole and the jump mode frequency is determined by the structural stability of the crystal. In this region its behavior is no longer that of a thermally activated process for an isolated molecular group and its frequency approaches zero critically near the phase transition.


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