scholarly journals Use of Algae in Active Biomonitoring of Surface Waters

2015 ◽  
Vol 21 (4) ◽  
pp. 561-576 ◽  
Author(s):  
Małgorzata Rajfur ◽  
Andrzej Kłos
Keyword(s):  
Surface Waters ◽  
Quantitative Assessment ◽  
Sea Water ◽  
Absorption Spectrometry ◽  
Palmaria Palmata ◽  
Spectrometry Method ◽  
Active Biomonitoring ◽  
Heavy Metal Concentrations ◽  
Limit Of Determination ◽  
Sorption Characteristics

Abstract Biomonitoring studies have been carried out in three retention reservoirs located in the Opole Province (southern Poland): Turawa reservoir, Nysa reservoir and Otmuchow reservoir. The increases of concentrations of Mn, Fe, Cu, Zn, Cd and Pb in fresh water algae Spirogyra sp. and sea water Palmaria palmata (Linnaeus) Weber & Mohr, exposed in the analysed waters, were determined by the atomic absorption spectrometry method (AAS). Also the waters pH, conductivity and Mn and Fe concentrations were determined. The concentrations of Cu, Zn, Cd and Pb in the analysed waters were lower than the method limit of determination. The analyses were carried out during the period from June to July 2014. The differences between the increases of heavy metal concentrations in the samples of algae found along the coastline were indicated; they result from different distances from the pollution sources, such as sediments or drainage from the areas adjacent to the reservoirs. Better sorption characteristics of Palmaria palmata in comparison to Spirogyra sp. were indicated. An empirical interrelation was also tested, the application of which after modification may enable the quantitative assessment of waters pollution with heavy metals, based on the analysis of the concentration of the element in the algae thallus.

scholarly journals Application of algae in active biomonitoring of the selected holding reservoirs in swietokrzyskie province

2016 ◽  
Vol 23 (2) ◽  
pp. 237-247 ◽  
Author(s):  
Małgorzata Rajfur ◽  
Paweł Krems ◽  
Andrzej Kłos ◽  
Rafał Kozłowski ◽  
Małgorzata A. Jóźwiak ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Atomic Absorption Spectrometry ◽  
Sea Water ◽  
Absorption Spectrometry ◽  
Palmaria Palmata ◽  
Artificial Lake ◽  
Spectrometry Method ◽  
Active Biomonitoring ◽  
Industrial Plants ◽  
Heavy Metal Concentrations

Abstract During the years 2014-2015, biomonitoring studies were carried out at three holding reservoirs located in Swietokrzyskie Province (central Poland): Kielce artificial lake, Chancza reservoir and Sielpia reservoir. In sea water algae Palmaria palmata (Linnaeus) Weber & Mohr, exposed in the analysed waters, the increases of concentrations were determined by the atomic absorption spectrometry method (AAS), of the following: Mn, Fe, Cu, Zn, Cd and Pb. Conductivity and pH were also determined in the reservoirs waters. The differences between the increases of heavy metal concentrations in the samples of algae found along the coastline were indicated; they result from different distances from the pollution sources, such as resorts, communication routes and industrial plants.

scholarly journals Mosses as Biomonitor of Air Pollution with Analytes Originating from Tobacco Smoke

2018 ◽  
Vol 23 (1-2) ◽  
pp. 127-136 ◽  
Author(s):  
Małgorzata Rajfur ◽  
Paweł Świsłowski ◽  
Filip Nowainski ◽  
Bogusław Śmiechowicz
Keyword(s):  
Heavy Metals ◽  
Air Pollution ◽  
Tobacco Smoke ◽  
Absorption Spectrometry ◽  
Pleurozium Schreberi ◽  
Spectrometry Method ◽  
Active Biomonitoring ◽  
Metal Concentrations ◽  
Heavy Metal Concentrations ◽  
Hair Samples

Abstract The aim of the carried out research was the assessment of the possibility to use a popular bioindicator - Pleurozium schreberi mosses as a biosensor of the air pollution in living quarters with the analytes originating from tobacco smoke. The moss bag method of active biomonitoring, popular in environmental studies, was applied; the method is based on exposing mosses collected in clean areas in the locations polluted with, for example, heavy metals. However, this experiment involved exposing mosses in living quarters, in which approximately 10 cigarettes were smoked daily (first room - kitchen). For the purpose of comparison, moss samples were also placed in another room (bedroom), which was potentially not polluted. After three months of exposure, the following heavy metals were determined in mosses: Mn, Fe, Ni, Cu, Zn, Cd, Pb and Hg, using the atomic absorption spectrometry method. Additionally, these analytes were also determined in hair samples from the persons smoking in the room and from other smokers; the determined metal concentrations were compared with the results of the studies carried out using hair samples collected from non-smokers. On the basis of carried out research it was confirmed that, among others, the mosses exposed in living quarters accumulate heavy metals, such as Ni, Zn, Pb and Hg, which originate from tobacco smoke. Higher heavy metal concentrations were determined in hair samples from smokers, compared to hair samples from non-smokers.

DEVELOPMENT OF INTEGRATED MONITORING NETWORK FOR MEASURING SALINITY OF SEA WATER

2018 ◽  
pp. 18-26
Author(s):  
Sima Ajdar qizi Askerova
Keyword(s):  
Surface Waters ◽  
Sea Water ◽  
Water Environment ◽  
Monitoring Network ◽  
Monitoring Networks ◽  
The Caspian Sea ◽  
Integrated Monitoring ◽  
Ecological Control ◽  
Different Depths ◽  
Optimal Construction

Monitoring of sea water condition is one of major requirements for carrying out the reliable ecological control of water environment. Monitoring networks contain such elements as sea buoys, beacons, etc. and are designated for measuringvarious hydrophysical parameters, including salinity of sea water. Development of specialized network and a separate buoy system for measuring thesea water salinity at different depths makes it possible to determine major regularities of processes of pollution and self-recovery of the sea waters. The article describes the scientific and methodological basics for development of this specialized network and questions of its optimal construction. It is well-known that at a depth of 30-45 m of the Caspian Sea salinity decreases and then at a depth of 45-60 m salinity is fully recovered. The mentioned changes of salinity at the relatively upper layer of sea waters is of special interest for studying the effect of ocean-going processes on the climate forming in the Caspian area. In terms of informativeness of measurements of surface waters salinity, the most informative is a layer ata 30-60 m depth, where inversion and recovery of salinity take place. It is shown that in most informative subrange of measurements, i. e. at a depth of 30-60 m optimization of regime of measurements complex should be carried out in order to increase the effectiveness of held researches. It is shown that at a depth of 35-50 m choice of the optimum regime of measurements makes it possible to obtain the maximum amount of information.

scholarly journals The Use of Bark in Biomonitoring Heavy Metal Pollution of Forest Areas on the Example of Selected Areas in Poland

2020 ◽  
Vol 27 (2) ◽  
pp. 195-210
Author(s):  
Paweł Świsłowski ◽  
Jan Kříž ◽  
Małgorzata Rajfur
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Seasonal Changes ◽  
Betula Pendula ◽  
Absorption Spectrometry ◽  
Heating Season ◽  
Spectrometry Method ◽  
Białowieża Forest ◽  
North Eastern ◽  
Heavy Metal Deposition

AbstractIn the year 2016, passive biomonitoring studies were conducted in the forest areas of southern and north-eastern Poland: the Karkonosze Mountains (Kark), the Beskidy Mountains (Beskid), Borecka Forest (P. Bor), Knyszynska Forest (P. Kny), and Białowieza Forest (P. Bia). This study used bark from the tree, Betula pendula Roth. Samples were collected in spring (Sp), summer (Su), and autumn (Au). Concentrations of Mn, Fe, Ni, Cu, Zn, Cd, and Pb were determined for the samples using the atomic absorption spectrometry method with flame excitation (F-AAS). Based on the obtained results, the studied areas were ranked according to level of heavy-metal deposition: forests of southern Poland > forests of north-eastern Poland. Some seasonal changes in the concentrations of metals accumulated in bark were also indicated, which is directly related to their changing concentrations in the air during the calendar year, for instance, the winter heating season produces higher concentrations of heavy metals in the bark samples taken in spring. When deciding to do biomonitoring studies using bark, but also other biological materials, it is necessary to take into account the period in which the conducted research is done and the time when the samples are taken for analysis, because this will have a significant impact on the obtained results.

scholarly journals Determination of Chromium in Biological Material by Electrothermal Atomic Absorption Spectrometry Method

2012 ◽  
Vol 56 (4) ◽  
pp. 585-589 ◽  
Author(s):  
Agnieszka Nawrocka ◽  
Józef Szkoda
Keyword(s):  
Atomic Absorption Spectrometry ◽  
Atomic Absorption ◽  
Certified Reference Materials ◽  
Graphite Furnace ◽  
Electrothermal Atomic Absorption Spectrometry ◽  
Absorption Spectrometry ◽  
Magnesium Nitrate ◽  
Spectrometry Method ◽  
Total Chromium

Abstract Procedure for determination of chromium in biological materials by Zeeman graphite furnace atomic absorption spectrometry method using a Perkin-Elmer spectrometer equipped with hollow-cathode lamp at 357.9 nm was developed. The samples of animal tissues, food, and feed were digested in muffle furnace at 450ºC. The ash was dissolved in 1 N hydrochloric acid and the final solution was diluted in 0.2% nitric acid. Magnesium nitrate (1%) was used as a matrix modifier. The method was validated in terms of basic analytical parameters. The mean recoveries of chromium was 84.4% for muscle, 79.0% for canned meat, and 80.2% for feed, and analytical detection limit was 0.003 μg/g. Certified reference materials were used for analytical quality assurance. The proposed analytical procedure is well adapted for monitoring chromium content in food and feedstuffs. Content of total chromium in the tested samples (animal muscles and liver) was low and was situated in the range of 0.031-0.101 mg/kg (muscles) and 0.047-0.052 mg/kg (liver).

scholarly journals Evidence for significant protein-like dissolved organic matter accumulation in Sea of Okhotsk sea ice

2015 ◽  
Vol 56 (69) ◽  
pp. 1-8 ◽  
Author(s):  
Mats A. Granskog ◽  
Daiki Nomura ◽  
Susann Müller ◽  
Andreas Krell ◽  
Takenobu Toyota ◽  
...  
Keyword(s):  
Organic Matter ◽  
Dissolved Organic Matter ◽  
Sea Ice ◽  
Surface Waters ◽  
Sea Of Okhotsk ◽  
Sea Water ◽  
First Year ◽  
Ice Melt ◽  
Ultraviolet Range ◽  
Considerable Excess

AbstractAbsorption and fluorescence of chromophoric dissolved organic matter (CDOM) in sea ice and surface waters in the southern Sea of Okhotsk was examined. Sea-water CDOM had featureless absorption increasing exponentially with shorter wavelengths. Sea ice showed distinct absorption peaks in the ultraviolet, especially in younger ice. Older first-year sea ice had relatively flat absorption spectra in the ultraviolet range. Parallel factor analysis (PARAFAC) identified five fluorescent CDOM components, two humic-like and three protein-like. Sea water was largely governed by humic-like fluorescence. In sea ice, protein-like fluorescence was found in considerable excess relative to sea water. The accumulation of protein-like CDOM fluorescence in sea ice is likely a result of biological activity within the ice. Nevertheless, sea ice does not contribute excess CDOM during melt, but the material released will be of different composition than that present in the underlying waters. Thus, at least transiently, the CDOM introduced during sea-ice melt might provide a more labile source of fresher protein-like DOM to surface waters in the southern Sea of Okhotsk.

A simple and direct atomic absorption spectrometry method for the direct determination of Hg in dried blood spots and dried urine spots prepared using various microsampling devices

2020 ◽  
Vol 35 (1) ◽  
pp. 136-144 ◽  
Author(s):  
Flávio V. Nakadi ◽  
Raúl Garde ◽  
Márcia A. M. S. da Veiga ◽  
Julio Cruces ◽  
Martín Resano
Keyword(s):  
Atomic Absorption Spectrometry ◽  
Atomic Absorption ◽  
Direct Determination ◽  
Absorption Spectrometry ◽  
Direct Analysis ◽  
Dried Blood Spots ◽  
Spectrometry Method ◽  
Blood Spots

Production of dried blood spots and dried urine spots of known volume enables their direct analysis aiming at the fast quantification of Hg.

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