scholarly journals Arylboronic acids with strong fluorescence intensity changes upon sugar binding

2012 ◽  
Vol 18 (1) ◽  
Author(s):  
Sarah Laughlin ◽  
Yingji Wang ◽  
Nanting Ni ◽  
Binghe Wang
Keyword(s):  
Fluorescence Intensity ◽  
Strong Fluorescence ◽  
Arylboronic Acids ◽  
Sugar Binding ◽  
Intensity Changes

Synthesis and Luminescence Properties of Tb3+-Doped Hydroxyapatites

2011 ◽  
Vol 399-401 ◽  
pp. 1582-1587
Author(s):  
Su Ping Huang ◽  
Jun Zhu ◽  
Ke Chao Zhou
Keyword(s):  
Aspect Ratio ◽  
Fluorescence Intensity ◽  
Doping Concentration ◽  
Doping Content ◽  
Fluorescent Properties ◽  
Strong Fluorescence ◽  
Active Growth ◽  
Ph Values ◽  
Structure Morphology ◽  
Ultraviolet Ray

In this paper, the terbium -doped nano-HA powders with strong fluorescence was prepared by hydrothermal synthesis and its crystal structure，morphology and fluorescent properties are characterized by XRD, TEM, XPS, ICP and PL spectroscopy. Results showed that with the doping concentration of Tb3+increasing, the aspect ratio of Tb3+-doped HA particles decreased, while the fluorescence intensity excited by ultraviolet ray at 272 nm is significantly enhanced. With pH values increased from 6.5 to 10.0, the aspect ratio of Tb3+-doped HA decreased greatly, and the morphology of nano-Tb:HA particles changes from rod particles to equiaxed particles and the actual doping content and the fluorescence intensity tends to increase correspondingly, which can be explained that under alkaline solution, Tb3+was more easier entering the HA crystal, and the Tb3+would substitute the Ca2+ in both hydroxyapatite Ca(Ⅰ) and Ca(Ⅱ) site, which may block the active growth sites of the seed crystals and resulted in the growth rate and the ratio of length to radius decreasing.

Properties and Synthesis of a Novel Unsymmetrical Photochromic Diarylethene Functional Material

2012 ◽  
Vol 164 ◽  
pp. 259-262
Author(s):  
Hai Chang Ding ◽  
Chun Hong Zheng ◽  
Shou Zhi Pu
Keyword(s):  
Fluorescence Intensity ◽  
Uv Light ◽  
Optoelectronic Properties ◽  
Pmma Film ◽  
Functional Material ◽  
Strong Fluorescence ◽  
Closed Ring ◽  
Hexane Solution

A new unsymmetrical photochromic diarylethene, 1-(3-thienyl)-2-(2- n-butyl-5-hydroxymethyl-3-thienyl) perfluoroncyclopentene (1a), was synthesized and its optoelectronic properties, such as photochromism and fluorescence in solution and in PMMA film were investigated. This compound exhibited remarkable photochromism, changing from colorless to pink after irradiation with UV light in hexane solution. The new diarylethene also exhibited relatively strong fluorescence by photoirradiation in solution and in PMMA film, and the fluorescence intensity decreased along with the photochromism upon irradiation 297 nm light and its closed-ring isomer showed almost no fluorescence

Synthesis of a Photochromic Diarylethene Having Thiazole and a Pyridyl Group for Optical Recording

2010 ◽  
Vol 156-157 ◽  
pp. 650-654 ◽  
Author(s):  
Hui Li ◽  
Yong Liang Xia ◽  
Shou Zhi Pu ◽  
Shi Qiang Cui
Keyword(s):  
Fluorescence Intensity ◽  
Optical Storage ◽  
Optical Recording ◽  
Pmma Film ◽  
Fluorescent Properties ◽  
Strong Fluorescence ◽  
Pyridyl Group ◽  
Open Ring

A new unsymmetrical photochromic diarylethene namly 1-(2,4-dimethyl-5- thiazolyl)-2- [(2-methyl-5-(2-pyridyl)-3-thienyl)]perfluorocyclopentene was synthesized, and its photochromic and fluorescent properties were also investigated. The compound exhibited good photochromism both in solution and in PMMA film. In PMMA film, The open-ring isomer of the diarylethene 1 exhibited relatively strong fluorescence at 427 nm when excited at 320 nm. The fluorescence intensity declined along with the photochromism upon irradiation with 297 nm light. Using this dithienylethene 1b as optical storage was performed successfully.

scholarly journals Chiral recognition and enantiomer excess determination based on emission wavelength change of AIEgen rotor

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Ming Hu ◽  
Ying-Xue Yuan ◽  
Weizhou Wang ◽  
Dong-Mi Li ◽  
Hong-Chao Zhang ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Theoretical Calculation ◽  
Fluorescence Intensity ◽  
Chiral Recognition ◽  
Natural World ◽  
Enantiomer Excess ◽  
Intensity Changes ◽  
Colour Changes ◽  
Chiral Receptors ◽  
Fluorescence Wavelength

AbstractChiral recognition, such as enantioselective interactions of enzyme with chiral agents, is one of the most important issues in the natural world. But artificial chiral receptors are much less efficient than natural ones. For tackling the chiral recognition and enantiomer excess (ee) analysis, up until now all the fluorescent receptors have been developed based on fluorescence intensity changes. Here we report that the chiral recognition of a large number of chiral carboxylic acids, including chiral agrochemicals 2,4-D, is carried out based on fluorescent colour changes rather than intensity changes of AIEgen rotors. Moreover, the fluorescence wavelength of the AIEgen rotor linearly changes with ee of the carboxylic acid, enabling the ee to be accurately measured with average absolute errors (AAE) of less than 2.8%. Theoretical calculation demonstrates that the wavelength change is ascribed to the rotation of the AIEgen rotor upon interaction with different enantiomers.

scholarly journals Two-photon microscopy of cortical NADH fluorescence intensity changes: correcting contamination from the hemodynamic response

2011 ◽  
Vol 16 (10) ◽  
pp. 106003 ◽  
Author(s):  
Edward Baraghis ◽  
Anna Devor ◽  
Qianqian Fang ◽  
Vivek J. Srinivasan ◽  
Weicheng Wu ◽  
...  
Keyword(s):  
Fluorescence Intensity ◽  
Hemodynamic Response ◽  
Two Photon Microscopy ◽  
Two Photon ◽  
Nadh Fluorescence ◽  
Intensity Changes

Synthesis and Property of a New Photochromic Diarylethene Bearing Thiophene and a Six-Membered Aryl Unit

2011 ◽  
Vol 197-198 ◽  
pp. 448-451 ◽  
Author(s):  
Hong Liang Liu ◽  
Shou Zhi Pu ◽  
Hui Li ◽  
Gang Liu
Keyword(s):  
Fluorescence Intensity ◽  
Uv Light ◽  
Amorphous Film ◽  
Solution Concentration ◽  
Fluorescent Properties ◽  
Strong Fluorescence ◽  
Photochromic Behavior

A novel photochromic diarylethene based on thiophene and a six-membered aryl moieties 1-[(2-methyl-5-(p-methylphenyl)-3-thienyl)]-2-[(2-trifluoromethylphenyl)]perfluorocyclopentene(1a) has been synthesized. Its properties, including photochromic behavior and fluorescent properties, have been investigated. The results showed that this compound exhibited reversible photochromism, changing from colorless to purple after irradiation with UV light both in solution and in PMMA amorphous film. The fluorescence intensity decreased along with the increase of solution concentration. The diarylethene exhibited relatively strong fluorescence at different solvent.

Optoelectronic Properties and Holographic Optical Recording of a Unsymmetrical Diarylethene Having a Pyrrole Unit

2011 ◽  
Vol 474-476 ◽  
pp. 1591-1594
Author(s):  
Gang Liu ◽  
Ming Liu ◽  
Qing Zhang ◽  
Shou Zhi Pu ◽  
Wei Jun Liu
Keyword(s):  
Fluorescence Intensity ◽  
Uv Light ◽  
Amorphous Film ◽  
Optical Recording ◽  
Optoelectronic Properties ◽  
Recording Medium ◽  
Strong Fluorescence ◽  
Closed Ring ◽  
Open Ring ◽  
Hexane Solution

A unsymmetrical photochromic diarylethene, 1-[2-methyl-5-(3,4-difluorophenyl) -3-thienyl]-2- (2-cyano-1,5-dimethyl-4-pyrryl) perfluorocyclopentene (1o), was synthesized, and its optoelectronic properties were also investigated. The results showed that this compound exhibited reversible photochromism changing from colorless to blue after irradiation with UV light both in solution and in PMMA amorphous film. The open-ring isomer of the diarylethene 1 exhibited relatively strong fluorescence both in hexane solution. The fluorescence intensity decreased along with the photochromism upon irradiation with 297 nm light and its closed-ring isomer showed almost no fluorescence. Using diarylethene 1 as recording medium, polarization holographic optical recording was carried out successfully.

Efficient Synthesis, Photochromism and Fluorescence Properties of a Novel Diarylethene Bearing a Naphthalene

2014 ◽  
Vol 1003 ◽  
pp. 59-62
Author(s):  
Hong Yan Xu ◽  
Le Le Ma ◽  
Shou Zhi Pu
Keyword(s):  
Fluorescence Intensity ◽  
Uv Light ◽  
Fluorescence Properties ◽  
Efficient Synthesis ◽  
Strong Fluorescence ◽  
Closed Ring ◽  
Open Ring

A new unsymmetrical photochromic diarylethene compound 1a was synthesized and its photochromism were investigated. The compound exhibited good photochromism in solution and PMMA films with alternating irradiation by UV/Vis light, and the maxima absorption of its closed-ring isomer (1b) are 536 nm in hexane and 552 nm in PMMA films. The open-ring isomer of the diarylethene 1a exhibited relatively strong fluorescence at 441 nm when excited at 290 nm. Its fluorescence intensity decreased along with the photochromism from open-ring isomers to closed-ring isomers upon irradiation with 297 nm UV light.

scholarly journals A selective fluorescent sensor for Cu(II) ion in ethanol and acetone based on BODIPY

2018 ◽  
Vol 9 (1) ◽  
pp. 63-66
Author(s):  
Zhenyu Zhang ◽  
Zhu Ming ◽  
Pengfei Li ◽  
Yongwu He ◽  
Li Bian
Keyword(s):  
Fluorescence Intensity ◽  
Fluorescent Sensor ◽  
Strong Fluorescence

A selective fluorescent sensor for Cu(II) ion in ethanol and acetone based on boradiazaindacene (BODIPY) has been studied. The selectivity towards Cu(II) ion is good over Ag(I), Cd(II), Fe(III), Hg(II), Ni(II), Pb(II), and Zn(II) ions, only Fe(III), Hg(II) and Ni(II) ions showed a slight interference. The solution showed strong fluorescence intensity after addition of triethanolamine, indicating that the Sensor 1-Cu(II) complex could be reversed by triethanolamine.

Photochromism, Kinetics and Fluorescence of 1-(2-methyl-3-benzofuranyl)-2-[2-methyl-5-(4-cyanophenyl)-3-thienyl]perfluorocyclopentene

2014 ◽  
Vol 886 ◽  
pp. 175-178
Author(s):  
Dan Dan Xue ◽  
Zhi Yuan Sun ◽  
Shou Zhi Pu
Keyword(s):  
Fluorescence Intensity ◽  
Fluorescence Spectra ◽  
Uv Light ◽  
Photochromic Properties ◽  
Strong Fluorescence ◽  
Open Ring ◽  
Kinetics Of ◽  
Hexane Solution

An unsymmetrical photochromic diarylethene compound, 1-(2-methyl-3-benzofuranyl)-2-[2-methyl-5-(4-cyanophenyl)-3-thienyperfluorocyclopentene was synthesized, and its photochromic properties, kinetics of the photochromic cyclization/cycloreversion and fluorescence were investigated in detail. The compound exhibited good photochromism, changing from colorless to red after irradiation with 297 nm UV light, in which absorption maxima were observed at 530 nm in hexane solution. Simultaneously, cyclization/cycloreversion kinetics of this diarylethene was researched. The open-ring isomer of the diarylethene exhibited relatively strong fluorescence at 377 nm in hexane solution (2 × 10-5 mol L-1), when excited at 327 nm. The fluorescence intensity decreased along with the photochromism upon irradiation with 297 nm light. The fluorescence spectra of the diarylethene are depended on the concentration.

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