scholarly journals Exploring the pH-dependent kinetics, thermodynamics and photochemistry of a flavylium-based pseudorotaxane

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Rita Anastácio ◽  
André Seco ◽  
Pedro Mateus ◽  
A. Jorge Parola ◽  
Nuno Basílio
Keyword(s):  
Time Scales ◽  
Reaction Network ◽  
Molecular Switches ◽  
Molecular Switch ◽  
Stimuli Responsive ◽  
Ph Dependent ◽  
Molecular Components ◽  
Different Time Scales

Abstract Flavylium-based molecular switches are attractive molecular components to devise stimuli-responsive host-guest systems such as rotaxanes and pseudorotaxanes. These compounds display a pH-dependent reaction network of several species that reversibly interconvert within different time scales. Therefore, to explore and take profit of exceptional stimuli-responsive properties of these systems, detailed kinetic and thermodynamic characterizations are often required. In this work, we present the results of such characterization for a new flavylium compound decorated with a trimethylalkylammonium substituent designed to form a pseudorotaxane with cucurbit[7]uril (CB7). The formation of the pseudorotaxane was characterized in detail, and the thermodynamic and kinetic aspects of the flavylium interconversion reactions in the assembly were investigated and compared with the free molecular switch.

Solvatochromic, thermochromic and pH-sensory DCDHF-hydrazone molecular switch: response to alkaline analytes

RSC Advances ◽  
2016 ◽  
Vol 6 (104) ◽  
pp. 102296-102305 ◽  
Author(s):  
Tawfik A. Khattab ◽  
Brylee David B. Tiu ◽  
Sonya Adas ◽  
Scott D. Bunge ◽  
Rigoberto C. Advincula
Keyword(s):  
Molecular Switches ◽  
Molecular Switch ◽  
Stimuli Responsive

Nanostructures fabricated from multi-stimuli responsive DCDHF-hydrazone molecular switches to function as colorimetric reversible gas probes.

Agent-Based Computational Model

2017 ◽  
Author(s):  
Joshua M. Epstein
Keyword(s):  
Computational Model ◽  
Bounded Rationality ◽  
Time Scales ◽  
Spatially Explicit ◽  
Agent Based ◽  
Affective Component ◽  
Elementary Type ◽  
Social Component ◽  
Different Time Scales

This part describes the agent-based and computational model for Agent_Zero and demonstrates its capacity for generative minimalism. It first explains the replicability of the model before offering an interpretation of the model by imagining a guerilla war like Vietnam, Afghanistan, or Iraq, where events transpire on a 2-D population of contiguous yellow patches. Each patch is occupied by a single stationary indigenous agent, which has two possible states: inactive and active. The discussion then turns to Agent_Zero's affective component and an elementary type of bounded rationality, as well as its social component, with particular emphasis on disposition, action, and pseudocode. Computational parables are then presented, including a parable relating to the slaughter of innocents through dispositional contagion. This part also shows how the model can capture three spatially explicit examples in which affect and probability change on different time scales.

Green markets integration in different time scales: A regional analysis

2021 ◽  
Vol 98 ◽  
pp. 105254 ◽  
Author(s):  
Christian Urom ◽  
Hela Mzoughi ◽  
Ilyes Abid ◽  
Mariem Brahim
Keyword(s):  
Time Scales ◽  
Regional Analysis ◽  
Different Time Scales

scholarly journals Measuring chromosome dynamics on different time scales using resolvases with varying half-lives

2005 ◽  
Vol 56 (4) ◽  
pp. 1049-1061 ◽  
Author(s):  
Richard A. Stein ◽  
Shuang Deng ◽  
N. Patrick Higgins
Keyword(s):  
Time Scales ◽  
Chromosome Dynamics ◽  
Different Time Scales

scholarly journals Reservoir ecological operation considering outflow variations across different time scales

2021 ◽  
Vol 125 ◽  
pp. 107582 ◽  
Author(s):  
Yibo Wang ◽  
Pan Liu ◽  
Ming Dou ◽  
He Li ◽  
Bo Ming ◽  
...  
Keyword(s):  
Time Scales ◽  
Different Time Scales

scholarly journals Stellar noise and planet detection. I. Oscillations, granulation and sun-like spots

2010 ◽  
Vol 6 (S276) ◽  
pp. 527-529
Author(s):  
Xavier Dumusque ◽  
Nuno C. Santos ◽  
Stéphane Udry ◽  
Cristophe Lovis ◽  
Xavier Bonfils
Keyword(s):  
Radial Velocity ◽  
Time Scales ◽  
High Precision ◽  
Habitable Zone ◽  
Planet Detection ◽  
Solar Type ◽  
Physical Phenomena ◽  
Instrumental Precision ◽  
Observational Strategy ◽  
Different Time Scales

AbstractSpectrographs like HARPS can now reach a sub-ms−1 precision in radial-velocity (RV) (Pepe & Lovis 2008). At this level of accuracy, we start to be confronted with stellar noise produced by 3 different physical phenomena: oscillations, granulation phenomena (granulation, meso- and super-granulation) and activity. On solar type stars, these 3 types of perturbation can induce ms−1 RV variation, but on different time scales: 3 to 15 minutes for oscillations, 15 minutes to 1.5 days for granulation phenomena and 10 to 50 days for activity. The high precision observational strategy used on HARPS, 1 measure per night of 15 minutes, on 10 consecutive days each month, is optimized, due to a long exposure time, to average out the noise coming from oscillations (Dumusque et al. 2011a) but not to reduce the noise coming from granulation and activity (Dumusque et al. 2011a and Dumusque et al. 2011b). The smallest planets found with this strategy (Mayor et al. 2009) seems to be at the limit of the actual observational strategy and not at the limit of the instrumental precision. To be able to find Earth mass planets in the habitable zone of solar-type stars (200 days for a K0 dwarf), new observational strategies, averaging out simultaneously all type of stellar noise, are required.

scholarly journals Intercomparison of Global Sea Surface Salinity from Multiple Datasets over 2011–2018

2021 ◽  
Vol 13 (4) ◽  
pp. 811
Author(s):  
Hao Liu ◽  
Zexun Wei
Keyword(s):  
Time Scales ◽  
Correlation Coefficients ◽  
Dominant Mode ◽  
Sea Surface ◽  
Sea Surface Salinity ◽  
Surface Salinity ◽  
Ocean Data Assimilation ◽  
Multiple Datasets ◽  
Different Time Scales

The variability in sea surface salinity (SSS) on different time scales plays an important role in associated oceanic or climate processes. In this study, we compare the SSS on sub-annual, annual, and interannual time scales among ten datasets, including in situ-based and satellite-based SSS products over 2011–2018. Furthermore, the dominant mode on different time scales is compared using the empirical orthogonal function (EOF). Our results show that the largest spread of ten products occurs on the sub-annual time scale. High correlation coefficients (0.6~0.95) are found in the global mean annual and interannual SSSs between individual products and the ensemble mean. Furthermore, this study shows good agreement among the ten datasets in representing the dominant mode of SSS on the annual and interannual time scales. This analysis provides information on the consistency and discrepancy of datasets to guide future use, such as improvements to ocean data assimilation and the quality of satellite-based data.

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