Ramie fiber reinforced composites with flame retardant structure design: flammability, smoke suppression, and mechanical properties

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Chenkai Zhu ◽  
Lei Nie ◽  
Xiaofei Yan ◽  
Jiawei Li ◽  
Dongming Qi

Abstract In this work, the structure of composite was designed as Core Stack and Surface Stack, which was treated with the expandable graphite (EG) and metal oxides such as iron oxide (IO), hydroxyapatite (HA), and aluminum tri-hydroxide (ATH). The mechanical performance of composites was characterized via flexural performance and interlaminar shear strength analysis. The flame retardance and smoke suppression of composite was explored in detail by LOI, UL-94, and cone calorimeter test. The findings presented that flexural properties of composites were observed to decrease due to delamination of surface stack, whilst no significant effect on interlaminar shear strength. In comparison with control composite, the loading of metal oxide into composite Surface Stack led to the reduction of peak heat release rate, total heat release, and fire growth index effectively. Moreover, the remarkable decrease in total smoke production could be observed due to the addition of iron oxide and the flame retardant mechanism was discussed. This study was the preliminary exploration of composite with flame retardant design which could be potential solution to improve flame retardancy and smoke suppression of composite with better mechanical structure preservation.

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Xiaofei Yan ◽  
Jie Fang ◽  
Chenkai Zhu ◽  
Jiawei Li ◽  
Dongmin Qi

Abstract The ramie plain-woven fabric-reinforced epoxy composites with iron oxide (IO) powders and expandable graphite (EG) particles were fabricated by the hand lay-up and vacuum bagging pressing. The flame retardant layers with IO powders and EG particles have been designed on the surface of the composite structure, to improve the composites flame retardancy. The flame retardancy property of the composites was discussed from the limited oxide index (LOI), vertical burning test, and cone calorimeter test, while the flexural property and interlaminar shear strength of the composites were also investigated through the three-point flexural tests, respectively. It was found that the flame retardancy property of the composites, which contains both IO powders and EG particles, can be greatly improved. However, IO powders and EG particles have a negative effect on flexural properties and interlaminar shear strength of the composites. Also, prepreg with IO powders or EG particles which laminated on the surface layer of the composite with different orders would result in different performances.


2021 ◽  
pp. 096739112098651
Author(s):  
Saeedeh Saadatyar ◽  
Mohammad Hosain Beheshty ◽  
Razi Sahraeian

Unidirectional carbon fiber-reinforced epoxy (UCFRE) is suffering from weak transverse mechanical properties and through-thickness properties. The effect of different amount (0.1, 0.3 and 0.5 phr which is proportional to 0.09, 0.27 and 0.46 wt%, respectively) of multiwall carbon nanotube (MWCNT), on transverse tensile properties, flexural strength, fracture toughness in transverse and longitudinal fiber directions, interlaminar shear strength and lap shear strength of UCFRE has been investigated. Dicyandiamide was used as a thermal curing agent of epoxy resin. MWCNT was dispersed in the epoxy resin by ultrasonic instrument and their dispersion state was investigated by scanning electron microscopy (SEM). The curing behavior of epoxy resin and its nanocomposites was assessed by differential scanning calorimetry. Results show that transverse tensile strength, modulus and strain-at-break were increased by 28.5%, 25% and 14%, respectively by adding 0.1 phr of MWCNT. Longitudinal flexural properties of UCFRE was not changed by adding different amount of MWCNT. Although longitudinal flexural strength was increased by 5% by adding 0.1 phr of MWCNT. Fracture toughness in transverse and longitudinal fiber directions was increased by 39% and 9%, respectively at 0.3 phr of MWCNT. Results also show that interlaminar shear strength and lap shear strength were increased at 0.3 phr of MWCNT by 8% and 5%, respectively. These increases in mechanical properties were due to the good adhesion of fibers to the matrix, interlocking and toughening action of MWCNT as revealed by SEM.


2021 ◽  
Vol 266 ◽  
pp. 113779
Author(s):  
Qiuyu Miao ◽  
Zhihong Dai ◽  
Guangyi Ma ◽  
Fangyong Niu ◽  
Dongjiang Wu

2009 ◽  
Vol 79-82 ◽  
pp. 497-500 ◽  
Author(s):  
Lei Chen ◽  
Zhi Wei Xu ◽  
Jia Lu Li ◽  
Xiao Qing Wu ◽  
Li Chen

The γ-ray co-irradiation method was employed to study the effect of diethanolamine modification on the surface of carbon fiber (CF) and the interfacial properties of CF/epoxy composites. Compared with the original carbon fiber, the surface of modified fibers became rougher. The amount of oxygen-containing functional groups was increased and the nitrogen element was detected after irradiation grafting. The interlaminar shear strength (ILSS) of composites reinforced by carbon fibers irradiated in diethanolamine solution was increased and then decreased as the irradiation dose increased. The ILSS of CF/epoxy composites was enhanced by 16.1% at 200kGy dose, compared with that of untreated one. The γ-ray irradiation grafting is expected to be a promising method for the industrialized modification of carbon fibers.


Author(s):  
S. M. Spiessberger ◽  
K. Humer ◽  
H. W. Weber ◽  
E. K. Tschegg ◽  
H. Gerstenberg ◽  
...  

Nanomaterials ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 894 ◽  
Author(s):  
Hongjiao Lin ◽  
Hejun Li ◽  
Qingliang Shen ◽  
Xiaohong Shi ◽  
Tao Feng ◽  
...  

An in-situ, catalyst-free method for synthesizing 3C-SiC ceramic nanowires (SiCNWs) inside carbon–carbon (C/C) composites was successfully achieved. Obtained samples in different stages were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and Raman scattering spectroscopy. Results demonstrated that the combination of sol-gel impregnation and carbothermal reduction was an efficient method for in-situ SiCNW synthesis, inside C/C composites. Thermal properties and mechanical behaviors—including out-of-plane and in-plane compressive strengths, as well as interlaminar shear strength (ILLS) of SiCNW modified C/C composites—were investigated. By introducing SiCNWs, the initial oxidation temperature of C/C was increased remarkably. Meanwhile, out-of-plane and in-plane compressive strengths, as well as interlaminar shear strength (ILLS) of C/C composites were increased by 249.3%, 109.2%, and 190.0%, respectively. This significant improvement resulted from simultaneous reinforcement between the fiber/matrix (F/M) and matrix/matrix (M/M) interfaces, based on analysis of the fracture mechanism.


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