Applications of metal selenium/tellurium compounds in materials science

Metal chalcogenides are technologically important materials. Physical, chemical, electrical and mechanical properties of these materials can be fine-tuned by manipulating their shape, size and composition. Although several methods are employed for their synthesis, single-source molecular precursor route has emerged as a versatile strategy for their synthesis and in controlling shape, size and composition of the material under moderate conditions. This chapter gives a brief coverage on the design and development of single-source molecular precursors which have been employed for the preparation of metal selenide/telluride nanocrystals and for deposition of thin films. The discussion includes synthesis of transition-, main group and f-block metal chalcogenolate and/or chalcogenide clusters as precursors and their conversion into metal chalcogenides in the form of thin films and nanostructures. Precursors for ternary metal chalcogenides are also included.