Production and study of chemical properties of superheavy elements

2019 ◽  
Vol 107 (7) ◽  
pp. 587-602 ◽  
Author(s):  
Christoph E. Düllmann
Keyword(s):  
Chemical Properties ◽  
Superheavy Elements ◽  
Fusion Reactions ◽  
Chemical Studies ◽  
Heaviest Elements ◽  
And Chemical Properties

Abstract Some highlight examples on the study of production and chemical properties of heaviest elements carried out mostly at GSI Darmstadt are presented. They focus on the production of some of the heaviest known elements (114Fl, 115Mc, and 117Mc), studies of non-fusion reactions, and on chemical studies of 114Fl. This is the heaviest element, for which chemical studies have been performed to date.

Relativity in the electronic structure of the heaviest elements and its influence on periodicities in properties

2019 ◽  
Vol 107 (9-11) ◽  
pp. 833-863 ◽  
Author(s):  
Valeria Pershina
Keyword(s):  
Periodic Table ◽  
Chemical Properties ◽  
Relativistic Effects ◽  
Experimental Investigations ◽  
Close Link ◽  
Chemical Studies ◽  
Heaviest Elements ◽  
Chemical Groups ◽  
Physical And Chemical ◽  
And Chemical Properties

AbstractTheoretical chemical studies demonstrated crucial importance of relativistic effects in the physics and chemistry of superheavy elements (SHEs). Performed, with many of them, in a close link to the experimental research, those investigations have shown that relativistic effects determine periodicities in physical and chemical properties of the elements in the chemical groups and rows of the Periodic Table beyond the 6thone. They could, however, also lead to some deviations from the established trends, so that the predictive power of the Periodic Table in this area may be lost. Results of those studies are overviewed here, with comparison to the recent experimental investigations.

scholarly journals PHYSICAL AND CHEMICAL STUDIES OF OVERROOF ROCKS OF CLAY SHALES OF THE DZHERDANAK DEPOSIT

2021 ◽  
pp. 16-21
Keyword(s):  
Electron Microscopy ◽  
Fine Structure ◽  
Chemical Properties ◽  
Mineralogical Composition ◽  
Physical And Chemical Properties ◽  
X Ray ◽  
Clay Shales ◽  
Chemical Studies ◽  
Physical And Chemical ◽  
And Chemical Properties

The purpose of this study is study of the physical and chemical properties of the overburden of the Dzherdanak deposit. The chemical and mineralogical composition of the overburden of the Djerdanak deposit has been studied by the methods of X-ray and thermography, electron microscopy and infrared spectroscopy. The main phases are quartz, kaolinite and muscovite. The study of the fine structure of the rock under an electron microscope showed the homogeneity of the rock with pronounced uniform inclusions, which is preserved even after firing. Changes in the rock after firing at 1050 °C have been determined. The formation of mullite at this temperature has been established.

scholarly journals The periodic table – an experimenter’s guide to transactinide chemistry

2019 ◽  
Vol 107 (9-11) ◽  
pp. 865-877 ◽  
Author(s):  
Robert Eichler
Keyword(s):  
Research And Development ◽  
Gas Phase ◽  
Periodic Table ◽  
Chemical Properties ◽  
Superheavy Elements ◽  
Experimental Results ◽  
Chemical Studies ◽  
Phase Chemical

Abstract The fundamental principles of the periodic table guide the research and development of the challenging experiments with transactinide elements. This guidance is elucidated together with experimental results from gas phase chemical studies of the transactinide elements with the atomic numbers 104–108 and 112–114. Some deduced chemical properties of these superheavy elements are presented here in conjunction with trends established by the periodic table. Finally, prospects are presented for further chemical investigations of transactinides based on trends in the periodic table.

scholarly journals Synthesis and Study of the New Superheavy Elements of D.I. Mendeleev Periodic Table of the Elements

Vestnik RFFI ◽  
2019 ◽  
pp. 87-104
Author(s):  
Yuri Ts. Oganessian
Keyword(s):  
Periodic Table ◽  
Nuclear Reactions ◽  
Chemical Properties ◽  
Nuclear Research ◽  
Superheavy Elements ◽  
Fusion Reactions ◽  
Flerov Laboratory ◽  
The Sixties ◽  
Experimental Complex ◽  
Physical And Chemical

In the sixties of the XX century, the possibility of existence of the region of increased stability of superheavy nuclei in the vicinity of Z | 114 and N | 184 was proved. For the first time a successful synthesis of superheavy elements was carried out in the Flerov Laboratory of Nuclear Reactions of the Joint Institute for Nuclear Research (JINR). Superheavy elements of D.I. Mendeleev Periodic Table of the Elements with atomic numbers 114–118 were synthesized in the fusion reactions of the nuclei of the transuranic elements with calcium-48 nuclei. The article deals with the choice of reactions for the synthesis of new elements, methods of studying their nuclear-physical and chemical properties. The experimental complex “Factory of superheavy elements” created in JINR and prospects of further research development are described.

Chemical Studies on Tobacco Smoke: XXI: Correlation and Multiple Regression among Selected Cigarette-Smoke Constituents and Leaf Characteristics of Bright Tobacco

1973 ◽  
Vol 7 (3) ◽  
Author(s):  
T.C. Tso ◽  
D. Hoffmann ◽  
G Rathkamp
Keyword(s):  
Multiple Regression ◽  
Chemical Properties ◽  
Regression Equations ◽  
Physical And Chemical Properties ◽  
Simple Correlation ◽  
Leaf Characteristics ◽  
Correlation Data ◽  
Chemical Studies ◽  
Physical And Chemical ◽  
And Chemical Properties

AbstractSimple correlation and multiple regressions among 160 variables of leaf characteristics and smoke constituents were calculated, based on experimental cigarettes made from 4 cultivars of bright-type tobacco, each from 8 stalk positions. Smoke composition is a function of the botanical, physical, and chemical properties of leaf tobacco used to make the cigarette. Detailed simple correlation data, multiple-regression equations, and expressions of variety and stalk position as factors of TPM and BaP formation are presented.

scholarly journals Superheavy elements

2019 ◽  
Vol 89 (6) ◽  
pp. 563-570
Author(s):  
Yu. Ts. Oganessian
Keyword(s):  
Periodic Table ◽  
Nuclear Reactions ◽  
Nuclear Research ◽  
Superheavy Elements ◽  
Superheavy Nuclei ◽  
Fusion Reactions ◽  
Nuclear Theory ◽  
Oak Ridge ◽  
Flerov Laboratory ◽  
Heaviest Elements

Synthesis of superheavy elements predicted by microscopic nuclear theory is investigated. The heaviest elements with Z = 114–118 were synthesized by fusion reactions of actinide nuclei with 48Ca ions accelerated using the U-400 complex at the Flerov Laboratory of Nuclear Reactions (FLNR), one of seven laboratories that comprise the Joint Institute for Nuclear Research (JINR) located in Dubna, Russia. The experiments were carried out in collaboration with physicists and chemists working at the Livermore and Oak Ridge national laboratories in located in California and Tennessee, respectively. Discovery of these elements allowed completion of the seventh period of the periodic table. The microscopic nuclear theory’s fundamental predictions about the possible existence of superheavy elements received the experimental confirmation. A new laboratory, i.e., the "STE Factory" associated with the JINR FLNR, has been established to research superheavy nuclei.

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