ortho-Effects in Mass Spectra. Alteration of the Molecular-Ion Energy Distribution in Disubstituted Acetanilides
1972 ◽
Vol 27
(4)
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pp. 670-677
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Keyword(s):
Abstract Simplified quasi-equilibrium calculations performed on the mass spectra of dihalosubstituted phenyl acetates and acetanilides again uncover the same substituent effects on the rise of K with E for the loss of ketene from phenyl acetates as was determined for the monosubstituted phenyl acetates. However, a new effect is found for the disubstituted acetanilides, removal of excitation probability for low-lying energy states of the molecular ion. This effect parallels the removal of transition probability for the lowest excited state of the neutral molecule.
Keyword(s):
2008 ◽
Vol 47
(8)
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pp. 6900-6902
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Keyword(s):
1992 ◽
Vol 25
(4)
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pp. 620-633
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2014 ◽
Vol 42
(7)
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pp. 1880-1893
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2016 ◽
Vol 759
◽
pp. 012076
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