One Electron Transitions in the Haloforms

1986 ◽  
Vol 41 (9) ◽  
pp. 1091-1093 ◽  
Author(s):  
R. Tate ◽  
D. C. Driscoll ◽  
G. Stauf

We have investigated the optical absorption of CHCl3, CHBr3, and CHI3 in the vacuum ultraviolet, using synchrotron radiation as the light source. A number of absorption features have been observed and are assigned to n - σ*, n - s, n - p, and n - d, one electron excitations.

Author(s):  
Domenik Schleier ◽  
Engelbert Reusch ◽  
Marius Gerlach ◽  
Tobias Preitschopf ◽  
Deb Pratim Mukhopadhyay ◽  
...  

The reaction kinetics of the isomers of the methylallyl radical with molecular oxygen has been studied in a flow tube reactor at the vacuum ultraviolet (VUV) beamline of the Swiss Light Source storage ring.


Open Physics ◽  
2011 ◽  
Vol 9 (2) ◽  
Author(s):  
Aleksandr Kalinko ◽  
Alexey Kotlov ◽  
Alexei Kuzmin ◽  
Vladimir Pankratov ◽  
Anatoli Popov ◽  
...  

AbstractThe photoluminescence spectra and luminescence excitation spectra of pure microcrystalline and nano-sized ZnWO4 as well as the ZnxNi1−x WO4 solid solutions were studied using vacuum ultraviolet (VUV) synchrotron radiation. The samples were also characterized by x-ray powder diffraction. We found that: (i) the shape of the photoluminescence band at 2.5 eV, being due to radiative electron transitions within the [WO6]6− anions, becomes modulated by the optical absorption of Ni2+ ions in the ZnxNi1−x WO4 solid solutions; and (ii) no significant change in the excitation spectra of Zn0.9Ni0.1WO4 is observed compared to pure ZnWO4. At the same time, a shift of the excitonic bands to smaller energies and a set of peaks, attributed to the one-electron transitions from the top of the valence band to quasi-localized states, were observed in the excitation spectrum of nano-sized ZnWO4.


1985 ◽  
Vol 41 (5) ◽  
pp. 527-533 ◽  
Author(s):  
Takashi Inagaki ◽  
Atsushi Ito ◽  
Masatsugu Motosuga ◽  
Kotaro Hieda ◽  
Katsumi Kobayashi ◽  
...  

2011 ◽  
Vol 94 (5) ◽  
pp. 53001 ◽  
Author(s):  
T. Dandl ◽  
H. Hagn ◽  
T. Heindl ◽  
R. Krücken ◽  
J. Wieser ◽  
...  

1997 ◽  
Vol 68 (5) ◽  
pp. 1945-1951 ◽  
Author(s):  
P. A. Heimann ◽  
M. Koike ◽  
C. W. Hsu ◽  
D. Blank ◽  
X. M. Yang ◽  
...  

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