XAFS Study of Molten ZrCl4 in LiCl-KCl Eutectic
2002 ◽
Vol 57
(5)
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pp. 277-280
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Keyword(s):
X Ray
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The local structure of motlen ZrCl4 in LiCl-KCl eutectic was investigated by using an X-ray absorption fine structure (XAFS) of the Zr K-absorption edge. The nearest Zr4+-Cl- distance and coordination number from the curve fitting analysis were (2.51±0.02) Å and 5.9±0.6, respectively. These suggest that a 6-fold coordination (ZrCl6)2- is predominant in the molten mixture.
1983 ◽
Vol 82
(2)
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pp. 299-312
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