Darstellung und Kristallstruktur von Barium-Quecksilber-Thiostannat(IV), BaHgSnS4 / Preparation and Crystal Structure of Barium-Mercury-Thiostannate(IV), BaHgSnS4

1980 ◽  
Vol 35 (1) ◽  
pp. 7-11 ◽  
Author(s):  
Chr. L. Teske
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Two Dimensional ◽  
Space Group ◽  
X Ray ◽  
First Time ◽  
Ray Methods

Abstract BaHgSnS4 was prepared for the first time and the crystal structure determined by using single crystal X-ray methods, a = 1080,4, b = 1084,o, c = 661,3 pm. Space group: C102V-Pnn2 (No. 34) orthorhombic. There are pairs of edge-sharing tetrahedra linked together to form two-dimensional net works. The crystal structure is similar to that of BaCdSnS4 [1].

scholarly journals Ba2ZnGe2S6O: Ein neues Oxidsulfid mit Tetraedergerüststruktur/On Ba2ZnGe2S6O. A New Oxide Sulfide with Tetrahedral Framework Structure

1980 ◽  
Vol 35 (6) ◽  
pp. 672-675 ◽  
Author(s):  
Chr. L. Teske
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Coordination Sphere ◽  
Framework Structure ◽  
Tetrahedral Framework ◽  
Space Group ◽  
X Ray ◽  
Lattice Constants ◽  
First Time ◽  
Ray Methods

Abstract Ba2ZnGe2S6O was prepared for the first time and the crystal structure determined by using single crystal X-ray methods. The space group is D32d-P4̄21m, tetragonal (No. 113). Lattice constants: a = 963.59 ± 0.22; c = 645.06 ± 0.25 pm. The tetrahedral framework structure is described and discussed. Zn is linked only to sulfur. The oxygen belongs to the coordination sphere of Ge and Ba.

Notizen: Die Kristallstruktur von Rb2Ca(N3)4 · 4 H2O / The Crystal Structure of RB2Ca(N3)4 · 4 H2O

1988 ◽  
Vol 43 (4) ◽  
pp. 497-498
Author(s):  
Franz A. Mautner ◽  
Harald Krischner ◽  
Christoph Kratky
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Orthorhombic Space Group ◽  
Space Group ◽  
X Ray ◽  
Ray Methods

Abstract The crystal structure of Rb2Ca(N3)4 · 4H2O has been determined by single crystal X-ray methods. The compound is isotypic with K2Ca(N3)4 · 4 H2O and crystallizes in the orthorhombic space group Ccca, Z = 4, a = 1949.1(12) pm, b = 1099.5(3) pm, c - 622.2(1) pm.

scholarly journals Die Kristallstruktur des Cyano-Elpasoliths [N(CH3)4]2CsFe(CN)6 / The Crystal Structure of the Cyano Elpasolite [N(CH3)4]2CsFe(CN)6

1982 ◽  
Vol 37 (12) ◽  
pp. 1534-1539 ◽  
Author(s):  
D. Babel
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
The Other ◽  
Methyl Groups ◽  
Orientational Disorder ◽  
Space Group ◽  
X Ray ◽  
Ray Methods ◽  
The Ideal

The crystal structure of the cubic compound [N(CH3)4]2CsFe(CN)6 was determined by X-ray methods: a = 2527.4(6) pm, space group Fd3c, Z = 32, Rg = 0.028 (260 independent single crystal reflections). The resulting distances within the practically undistorted Fe (CN)63- - octahedron are Fe-C = 193.4(6) and C-N = 115.7(7) pm. Compared to the ideal elpasolite structure of space group Fm3m, Z = 4, the octahedra are rotated by 7.4° through their 3 axis. This is discussed as caused by steric requirements of the tetramethylammonium groups (N-C = 148.4(10) and 149.1(38) pm, resp.). Three quarters of them, of which also the hydrogen positions could be located, are well oriented. The remaining quarter shows orientational disorder to approach similar contact distances as the other N(CH3)4+ ion exhibits between the methyl groups and the nitrogen ends of the anions

Darstellung und Kristallstruktur von Silber-Barium-Thiogermanat(IV). Ag2BaGeS4 / Preparation and Crystal Structure of Silver-Barium-Thiogermanate(IV). Ag2BaGeS4

1979 ◽  
Vol 34 (4) ◽  
pp. 544-547 ◽  
Author(s):  
Chr. L. Teske
Keyword(s):  
Crystal Structure ◽  
Interatomic Distances ◽  
Space Group ◽  
X Ray ◽  
First Time ◽  
Ray Methods ◽  
Atomic Parameters

Abstract Ag2BaGeS4 was prepared for the first time and the crystal structure determined using X-ray methods, a - b = 682,g; c = 801,7 pm, Space group I4̅2 m (No. 121) tetragonal. The atomic parameters and interatomic distances are reported and the structure is discussed.

Die Kristallstruktur von Ytterbiumdisulfid: YbS2 / The Crystal Structure of Ytterbiumdisulfide: YbS2

1974 ◽  
Vol 29 (1-2) ◽  
pp. 16-19 ◽  
Author(s):  
Christoph L. Teske
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Monoclinic Space Group ◽  
Structural Element ◽  
Thermal Synthesis ◽  
Space Group ◽  
X Ray ◽  
First Time ◽  
Atomic Parameters

X-ray investigations are described using a single crystal of YbS2 for the first time which formed during a ammono thermal synthesis. It crystallizes in the monoclinic space group C2h6-C2/c with a = 9,326, b = 4,754, c = 9,025 and β = 118,39°. The atomic parameters and a detailed description of the crystal structure are given. Especially the sulfur-sulfurbridges (dS-S = 2,11 A) represent a characteristic structural element in the a lattice of the genuine disulfide.

Crystal structure of an inclusion complex between chiral monoaza-15-crown-5 and S(–)-1-phenyl-ethyl ammonium percholorate

2003 ◽  
Vol 218 (5) ◽  
Author(s):  
Süheyla Özbey ◽  
F. B. Kaynak ◽  
M. Toğrul ◽  
N. Demirel ◽  
H. Hoşgören
Keyword(s):  
Crystal Structure ◽  
Inclusion Complex ◽  
Single Crystal ◽  
X Ray Diffraction ◽  
Space Group ◽  
X Ray ◽  
New Type

AbstractA new type of inclusion complex, S(–)-1 phenyl ethyl ammonium percholorate complex of R-(–)-2-ethyl - N - benzyl - 4, 7, 10, 13 - tetraoxa -1- azacyclopentadecane, has been prepared and studied by NMR, IR and single crystal X-ray diffraction techniques. The compound crystallizes in space group

Single-crystal investigation of Ce5AgxGe4−x (x = 0.1−1.08) with Sm5Ge4 type

2020 ◽  
Vol 75 (8) ◽  
pp. 765-768
Author(s):  
Bohdana Belan ◽  
Dorota Kowalska ◽  
Mariya Dzevenko ◽  
Mykola Manyako ◽  
Roman Gladyshevskii
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Diffraction Data ◽  
Binary Compound ◽  
Lattice Parameters ◽  
X Ray Diffraction ◽  
Space Group ◽  
X Ray

AbstractThe crystal structure of the phase Ce5AgxGe4−x (x = 0.1−1.08) has been determined using single-crystal X-ray diffraction data for Ce5Ag0.1Ge3.9. This phase is isotypic with Sm5Ge4: space group Pnma (No. 62), Pearson code oP36, Z = 4, a = 7.9632(2), b = 15.2693(5), c = 8.0803(2) Å; R1 = 0.0261, wR2 = 0.0460, 1428 F2 values and 48 variables. The two crystallographic positions 8d and 4c show Ge/Ag mixing, leading to a slight increase in the lattice parameters as compared to those of the pure binary compound Ce5Ge4.

scholarly journals β-Y(BO2)3 – a new member of the β-Ln(BO2)3 (Ln=Nd, Sm, Gd–Lu) structure family

2017 ◽  
Vol 72 (12) ◽  
pp. 983-988 ◽  
Author(s):  
Martin K. Schmitt ◽  
Hubert Huppertz
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Lattice Parameters ◽  
X Ray Diffraction ◽  
Orthorhombic Space Group ◽  
Space Group ◽  
X Ray

Abstractβ-Y(BO2)3 was synthesized in a Walker-type multianvil module at 5.9 GPa/1000°C. The crystal structure has been elucidated through single-crystal X-ray diffraction. β-Y(BO2)3 crystallizes in the orthorhombic space group Pnma (no. 62) with the lattice parameters a=15.886(2), b=7.3860(6), and c=12.2119(9) Å. Its crystal structure will be discussed in the context of the isotypic lanthanide borates β-Ln(BO2)3 (Ln=Nd, Sm, Gd–Lu).

scholarly journals CRYSTAL STRUCTURE OF THE NEW SILICIDE Lu3Ni11.74(2)Si4

2020 ◽  
Vol 86 (5) ◽  
pp. 3-12
Author(s):  
Bohdana Belan ◽  
Mykola Manyako ◽  
Mariya Dzevenko ◽  
Dorota Kowalska ◽  
Roman Gladyshevskii
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Type Structure ◽  
X Ray Diffraction ◽  
Space Group ◽  
X Ray ◽  
Arc Melting ◽  
Pearson Symbol ◽  
Ternary Silicide

The new ternary silicide Lu3Ni11.74(2)Si4 was synthesized from the elements by arc-melting and its crystal structure was determined by the single-crystal X-ray diffraction. The compound crystallizes in the Sc3Ni11Ge4-type: Pearson symbol hP37.2, space group P63/mmc (No. 194), a = 8.0985(16), c = 8.550(2) Å, Z = 2; R = 0.0244, wR = 0.0430 for 244 reflections. The silicide Lu3Ni11.74(2)Si4 is new member of the EuMg5.2-type structure family.

Redetermination of Co4Nb2O9 by single-crystal X-ray methods

2006 ◽  
Vol 62 (5) ◽  
pp. i117-i119 ◽  
Author(s):  
María A. Castellanos R. ◽  
Sylvain Bernès ◽  
Marina Vega-González
Keyword(s):  
Single Crystal ◽  
High Precision ◽  
Cation Distribution ◽  
Crystal Data ◽  
Space Group ◽  
X Ray ◽  
Ray Methods

A high-precision structure of tetracobalt diniobium nonaoxide, Co4Nb2O9, is presented, based on X-ray single-crystal data. The space group and cation distribution previously obtained from powder data [Bertaut, Corliss, Forrat, Aleonard & Pauthenet (1961). J. Phys. Chem. Solids, 21, 234–251] are confirmed.

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