IR-Spektren von Platin(II)-Komplexen mit Glycin, Glycin-und Glycylglycinethylester [1]/IR-Spectra of Platinum(ll) Complexes with Glycine, Glycine Ethyl Ester and Glycylglycine Ethyl Ester [1]

Abstract The infrared spectra (200-4000 cm-1) of trans- and cis-Pt(NX2CH2COO)2 (X = H, D), trans- and cis-PtCl2(NH2CH2COOH)2, trans-PtCl2(NH2CH2CO2Et)2, cis-PtCl2(NX2CH2CO2Et)2, cis-PtCl2(NX2CH2NXCH2CO2Et)2 (X = H, D) and cis-PtY2(NH2CH2NHCH2CO2Et)2 (Y = Br, I) including 15N derivatives have been studied. There is no appreciable change of vibrational frequencies for corresponding cis- and trans- complexes which could be attributed to the trans-influence of different ligands. Due to lower symmetry most of the absorptions of the cis-complexes are split into doublets compared with the trans-compounds.

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The Interpretation of the Infrared Spectra of Conjugated Polyenes in the 1000–900 cm−1 Region

Applied Spectroscopy ◽

10.1366/000370271779949285 ◽

1971 ◽

Vol 25 (3) ◽

pp. 368-371 ◽

Cited By ~ 8

Author(s):

N. B. Colthup

Keyword(s):

Fatty Acids ◽

Ir Spectra ◽

Infrared Spectra ◽

Conjugated Polyenes ◽

Cis And Trans

The ir spectra of conjugated polyenes such as fatty acids and derivatives are known to have band patterns in the 1000–900 cm−1 region which are characteristic for various arrangements of cis and trans groups within the different polyenes. This paper presents an interpretation of these bands and also predicts absorption patterns for less commonly observed polyenes with cis or trans groups.

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Arrhenius parameters for the alkaline hydrolysis of glycine ethyl ester, in aqueous solution, and thermodynamic functions for its ionisation as an acid

Journal of the Chemical Society B Physical Organic ◽

10.1039/j29670001265 ◽

1967 ◽

pp. 1265 ◽

Cited By ~ 5

Author(s):

Margaret Robson Wright

Keyword(s):

Aqueous Solution ◽

Ethyl Ester ◽

Thermodynamic Functions ◽

Alkaline Hydrolysis ◽

Arrhenius Parameters ◽

Glycine Ethyl Ester ◽

Hydrolysis Of

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Infrared Spectra and Density Functional Theory Calculations on Transition Metal Nitrosyls. Vibrational Frequencies of Unsaturated Transition Metal Nitrosyls

Chemical Reviews ◽

10.1021/cr0000729 ◽

2002 ◽

Vol 102 (4) ◽

pp. 885-912 ◽

Cited By ~ 160

Author(s):

Lester Andrews ◽

Angelo Citra

Keyword(s):

Density Functional Theory ◽

Transition Metal ◽

Infrared Spectra ◽

Density Functional ◽

Density Functional Theory Calculations ◽

Vibrational Frequencies ◽

Functional Theory ◽

Metal Nitrosyls

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An inverse, linear correlation of cis and trans influence

Inorganic and Nuclear Chemistry Letters ◽

10.1016/0020-1650(74)80111-x ◽

1974 ◽

Vol 10 (5) ◽

pp. 373-376 ◽

Cited By ~ 9

Author(s):

Keith R. Dixon ◽

Kenneth C. Moss ◽

Martin A.R. Smith

Keyword(s):

Linear Correlation ◽

Trans Influence ◽

Cis And Trans

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Some metabolites of 1-bromobutane in the rabbit and the rat

Biochemical Journal ◽

10.1042/bj1090727 ◽

1968 ◽

Vol 109 (5) ◽

pp. 727-736 ◽

Cited By ~ 29

Author(s):

Sybil P. James ◽

D. A. Jeffery ◽

Rosemary H. Waring ◽

P. B. Wood

Keyword(s):

Lactic Acid ◽

Ethyl Ester ◽

Rat Liver ◽

Hydroxy Acid ◽

Rabbit Liver ◽

Mercapturic Acid ◽

Acid Form ◽

Rat Urine ◽

Glycine Ethyl Ester

1. Rabbits and rats dosed with 1-bromobutane excrete in urine, in addition to butylmercapturic acid, (2-hydroxybutyl)mercapturic acid, (3-hydroxybutyl)mercapturic acid and 3-(butylthio)lactic acid. 2. Although both species excrete both the hydroxybutylmercapturic acids, only traces of the 2-isomer are excreted by the rabbit. The 3-isomer has been isolated from rabbit urine as the dicyclohexylammonium salt. 3. 3-(Butylthio)lactic acid is formed more readily in the rabbit; only traces are excreted by the rat. 4. Traces of the sulphoxide of butylmercapturic acid have been found in rat urine but not in rabbit urine. 5. In the rabbit about 14% and in the rat about 22% of the dose of 1-bromobutane is excreted in the form of the hydroxymercapturic acids. 6. Slices of rat liver incubated with S-butylcysteine or butylmercapturic acid form both (2-hydroxybutyl)mercapturic acid and (3-hydroxybutyl)mercapturic acid, but only the 3-hydroxy acid is formed by slices of rabbit liver. 7. S-Butylglutathione, S-butylcysteinylglycine and S-butylcysteine are excreted in bile by rats dosed with 1-bromobutane. 8. Rabbits and rats dosed with 1,2-epoxybutane excrete (2-hydroxybutyl)mercapturic acid to the extent of about 4% and 11% of the dose respectively. 9. The following have been synthesized: N-acetyl-S-(2-hydroxybutyl)-l-cysteine [(2-hydroxybutyl)mercapturic acid] and N-acetyl-S-(3-hydroxybutyl)-l-cysteine [(3-hydroxybutyl)mercapturic acid] isolated as dicyclohexylammonium salts, N-toluene-p-sulphonyl-S-(2-hydroxybutyl)-l-cysteine, S-butylglutathione and N-acetyl-S-butylcysteinyl-glycine ethyl ester.

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Hydrogen bonding and conformation in cis- and trans-2-alkoxy-3-hydroxytetrahydrofurans

Canadian Journal of Chemistry ◽

10.1139/v68-004 ◽

1968 ◽

Vol 46 (1) ◽

pp. 21-24 ◽

Cited By ~ 5

Author(s):

W. W. Zajac Jr. ◽

F. Sweet ◽

R. K. Brown

Keyword(s):

Hydrogen Bonding ◽

Infrared Spectra ◽

Hydroxyl Absorption ◽

Cis And Trans ◽

In Cis ◽

Infrared Data ◽

Hydrogen Bonded

Infrared spectra show both free and hydrogen bonded hydroxyl absorption in several trans-2-alkoxy-3-hydroxytetrahydrofurans. The extent of non-bonded hydroxyl is greater than that of bonded hydroxyl. Suggestions are made of possible conformations which might account for the infrared data.

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