Zur Darstellung und Kristallstruktur eines neuen Kupfer-Antimon-Oxomolybdats: CuSbMo2O8 / On the Synthesis and Crystal Structure of a New Copper Antimony Oxomolybdate: CuSbMo2O8
1995 ◽
Vol 50
(5)
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pp. 717-720
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Keyword(s):
X Ray
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Abstract Single crystals of the hitherto unknown compound CuSbMo2O8 were prepared by recrystallization from melts in closed copper tubes and investigated by X-ray diffractometer technique. CuSbMo2O8 crystallizes in a new structure type with monoclinic symmetry, space group C62h - I12/a1, a = 5.554(2), b = 4.916(1), c = 21.519(4) Å, β = 93.42(3)°, Z = 4. The crystal structure shows SbIII in a one-sided coordination by four oxygen. Molybdenum shows the rare octahedral coordination by oxygen. MoO6 and CuO6 octahedra form triple layers stacked and connected by Sb ions along [001].
1994 ◽
Vol 49
(3)
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pp. 350-354
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1994 ◽
Vol 49
(8)
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pp. 1145-1149
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1995 ◽
Vol 50
(8)
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pp. 1146-1150
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1995 ◽
Vol 50
(10)
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pp. 1445-1449
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1994 ◽
Vol 49
(10)
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pp. 1329-1333
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