Reaction between Yttrium Nitrate and 2,2':6',2"-Terpyridine (terpy) in MeCN: Preparation, Crystal Structures and Spectroscopic Characterization of [Y (NO3)3(terpy)(H2O )] and [Y(NO3)3(terpy)(H2O )] · terpy · 3 MeCN

Abstract The reaction of Y(NO3)3 · 5H2O and 2,2':6',2"-terpyridine (terpy) in MeCN leads to [Y(N03 )3(terpy)(H2O )] (1) and [Y(N03 )3(terpy)(H2O )] terpy-3MeCN (2) in good yields depending on the isolation conditions. The structures of both complexes were determined by single-crystal X-ray crystallography. The YIII atom in 1 is 9-coordinate and ligation is provided by one terdentate terpy molecule, two chelating nitrates, one monodentate nitrate and one terminal H2O molecule; the coordination polyhedron about the metal may be viewed as a tricapped trigonal prism. The YIII atom in 2 is 10-coordinate and its coordination sphere consists of three nitrogen atoms from the terdentate terpy, six oxygen atoms from the three chelating nitrates (one of them being “anisobidentate”) and one oxygen atom from a terminal H2O molecule; the polyhedron about the metal may be viewed as a distorted sphenocorona. The interstitial terpy is strongly hydrogen-bonded to the O atom of the coordinated H2O molecule to form [Y(NO3 )3(terpy)(H20)] ··· terpy pairs. The new complexes were characterized by IR and 1H NMR spectroscopies. The YIII/NO3-/terpy chemistry is compared to the already well-developed LnIII/NO3-/terpy chemistry (Ln = lanthanide).

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Preparation, Crystal Structure and Spectroscopic Characterization of [Ga(OH)(SO4)(terpy)(H2O)] · H2O (terpy=2,2’:6’,2-Terpyridine): The First Characterized Gallium(III) Sulfato Complex

Zeitschrift für Naturforschung B ◽

10.1515/znb-2004-0310 ◽

2004 ◽

Vol 59 (3) ◽

pp. 291-297 ◽

Cited By ~ 11

Author(s):

Andreas Sofetis ◽

Giannis S. Papaefstathiou ◽

Aris Terzis ◽

Catherine P. Raptopoulou ◽

Theodoros F. Zafiropoulos

Keyword(s):

Crystal Structure ◽

Hydrogen Bonding ◽

Nmr Spectroscopy ◽

Good Yield ◽

Spectroscopic Data ◽

Spectroscopic Characterization ◽

X Ray ◽

X Ray Crystallography ◽

H Nmr

The reaction of Ga2(SO4)3·18H2O and excess 2,2′:6′,2″-terpyridine (terpy) in MeOH / H2O leads to [Ga(OH)(SO4)(terpy)(H2O)]·H2O (1·H2O] in good yield. The structure of the complex has been determined by single-crystal X-ray crystallography. The GaIII atom in 1·H2O is 6-coordinate and ligation is provided by one terdentate terpy molecule, one monodentate sulfate, one terminal hydroxide and one terminal H2O molecule; the coodination polyhedron about the metal is described as a distorted octahedron. There is an extensive hydrogen-bonding network in the crystal structure which generates corrugated layers parallel to bc. The new complex was characterized by IR and 1H NMR spectroscopy. The spectroscopic data are discussed in terms of the nature of bonding

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Synthesis and structural characterization of a magnesium phthalocyanine(3–) anion

Journal of Porphyrins and Phthalocyanines ◽

10.1142/s1088424611004440 ◽

2012 ◽

Vol 16 (01) ◽

pp. 154-162 ◽

Cited By ~ 24

Author(s):

Edwin W.Y. Wong ◽

Daniel B. Leznoff

Keyword(s):

Absorption Spectrum ◽

Solid State ◽

Single Crystal ◽

Structural Characterization ◽

Heterometallic Complex ◽

State Structure ◽

Solid State Structure ◽

X Ray ◽

X Ray Crystallography

The reduction of magnesium phthalocyanine (MgPc) with 2.2 equivalents of potassium graphite in 1,2-dimethoxyethane (DME) gives [K2(DME)4]PcMg(OH)(1) in 67% yield. Compound 1 was structurally characterized using single crystal X-ray crystallography and was found to be a monomeric, heterometallic complex consisting of a μ3-OH ligand that bridges a [MgIIPc3-]- anion to two potassium cations solvated by four DME molecules. An absorption spectrum of 1 confirms the Pc ligand is singly reduced and has a 3–charge. The solid-state structure of 1 does not indicate breaking of the aromaticity of the Pc ligand. Compound 1 is only the second Pc3- complex and the first reduced MgPc to be isolated and structurally characterized.

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The Synthesis and Characterization of a Novel One-Dimensional Bismuth (III) Coordination Polymer as a Precursor for the Production of Bismuth (III) Oxide Nanorods

Crystals ◽

10.3390/cryst12010113 ◽

2022 ◽

Vol 12 (1) ◽

pp. 113

Author(s):

Younes Hanifehpour ◽

Babak Mirtamizdoust ◽

Jaber Dadashi ◽

Ruiyao Wang ◽

Mahboube Rezaei ◽

...

Keyword(s):

Single Crystal ◽

Coordination Compound ◽

Organic Ligand ◽

One Dimensional ◽

X Ray ◽

X Ray Crystallography ◽

Oxide Nanorods ◽

Pure Phase ◽

3D Framework

A novel Bi (III) coordination compound, [Bi(HQ)(Cl)4]n ((Q = pyridine-4-carbaldehyde thiosemicarbazone), was prepared in this research using a sonochemical technique. SEM, infrared spectroscopy (IR), XRD, and single-crystal X-ray analysis were utilized to analyze the Bi(III) coordination compound. The structure determined using single-crystal X-ray crystallography indicates that the coordination compound is a 1D polymer in solid state and that the coordination number of bismuth (III) ions is six, (BiSCl5), with one S donor from the organic ligand and five Cl donors from anions. It is equipped with a hemidirectional coordination sphere. It is interesting that the ligand has been protonated in the course of the reaction with a Cl- ion balancing the charge. This compound’s supramolecular properties are directed and regulated by weak directional intermolecular interactions. Through π–π stacking interactions, the chains interact with one another, forming a 3D framework. Thermolysis of the compound at 170 °C with oleic acid resulted in the formation of pure phase nanosized Bi (III) oxide. SEM technique was used to examine the morphology and size of the bismuth (III) oxide product produced.

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Synthesis, X-ray crystallography, thermogravimetric analysis and spectroscopic characterization of isostructural one-dimensional coordination polymers as sorbents for some anions

CrystEngComm ◽

10.1039/c7ce02017a ◽

2018 ◽

Vol 20 (13) ◽

pp. 1783-1796 ◽

Cited By ~ 2

Author(s):

Bahram Ghanbari ◽

Leila Shahhoseini ◽

Agata Owczarzak ◽

Maciej Kubicki ◽

Reza Kia ◽

...

Keyword(s):

Thermogravimetric Analysis ◽

Coordination Polymers ◽

Spectroscopic Characterization ◽

One Dimensional ◽

X Ray ◽

X Ray Crystallography

A new series of coordination polymers capable of adsorbing anions have been synthesized by employing a dipyridine substituted diazacrown macrocycle as linker.

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Organolanthanoids. XXI Synthesis of Bis- and Tris-(diphenylphosphinocyclopenta- dienyl)lanthanoid Compounds and the X-Ray Crystal Structures of [Ln(C5H4PPh2)3(OPPh3)]·(thf)1

Australian Journal of Chemistry ◽

10.1071/c97125 ◽

1997 ◽

Vol 50 (10) ◽

pp. 959 ◽

Cited By ~ 10

Author(s):

Glen B. Deacon ◽

Craig M. Forsyth ◽

Bryan M. Gatehouse ◽

Anna Philosof ◽

Brian W. Skelton ◽

...

Keyword(s):

Oxygen Atom ◽

Single Crystal ◽

Crystal Structures ◽

Room Temperature ◽

Central Metal ◽

Metal Oxidation ◽

X Ray

Redox transmetallation ofTl(C5H4PPh2)with an excess of Sm in refluxing thf (thf = tetrahydrofuran) or Eu indme (dme = 1,2-dimethoxyethane) at room temperature gave thelanthanoid(II) compounds[Sm(C5H4PPh2)2](1) and[Eu(C5H4PPh2)2(dme)](2). Crystallization of (1) or[Yb(C5H4PPh2)2(dme)]with OPPh3 in dme yielded[Sm(C5H4PPh2)2(OPPh3)2](3) and[Yb(C5H4PPh2)2(OPPh3)2](4). Room-temperature transmetallation ofTl(C5H4PPh2)with Nd gave the lanthanoid(III) compound[Nd(C5H4PPh2)3(thf)](5), but analogous reactions with La, Pr, Er, Gd and Y in refluxing thfgenerally gave intractable oils, although in one instance impure[La(C5H4PPh2)3(thf)]·(thf)0 · 5,namely(6)·(thf)0 · 5, wasisolated. This complex was also obtained at room temperature by usingLaI3-activated La metal. Oxidation of (1) with 1 equiv.ofTl(C5H4PPh2)in toluene yielded solvent-freeSm(C5H4PPh2)3(7). Addition of OPPh3 to these systems allowed theisolation of[Ln(C5H4PPh2)3(OPPh3)]·(thf)x(x = 0-1 · 5; Ln = La (8), Pr (9),Nd (10), Sm (11), Er (12), Y (13)). Single-crystal X-ray structuredetermination of(10)·(thf)1 · 5,(11)·(thf)1 · 5 and(12)·(thf)1 · 5revealed formally 10-coordinate complexes with an O-bondedOPPh3, threeη5-C5H4PPh2ligands and lattice thf. The centroids of the C5 ringsand the oxygen atom surround the central metal in a distorted tetrahedralarray.

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Synthesis and characterization of a new bis-NHC palladium complex and its catalytic activity in the Mizoroki–Heck reaction

Journal of Chemical Research ◽

10.1177/1747519820917883 ◽

2020 ◽

Vol 44 (11-12) ◽

pp. 684-688

Author(s):

Can Feng ◽

Cheng-xin Liu ◽

Yu-fang Wang ◽

Jin Cui ◽

Ming-jie Zhang

Keyword(s):

Palladium Complex ◽

Coupling Reaction ◽

Aryl Halides ◽

Heck Coupling ◽

X Ray ◽

X Ray Crystallography ◽

H Nmr ◽

Excellent Stability ◽

C Nmr

A new bis- N-heterocyclic carbene palladium complex, (C13H9N2F2)2PdCl2, is synthesized by a three-step reaction and characterized by 1H NMR and 13C NMR spectroscopy as well as by X-ray crystallography. This new bis- N-heterocyclic carbene palladium complex has excellent stability and is capable of efficiently catalyzing the Mizoroki–Heck coupling reaction of aryl halides with acrylates.

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Reactions of Dimethyl Sulfite with Diorganotin Oxides. One-Pot Synthesis of Methoxydiorganotin Methanesulfonates through the Arbuzov Rearrangement, Spectroscopic Characterization of These Compounds and Their Derivatives, and X-ray Crystal Structures ofn-Bu2Sn(X)OS(O)2Me (X = acac, bzbz, OH)

Inorganic Chemistry ◽

10.1021/ic981337t ◽

1999 ◽

Vol 38 (21) ◽

pp. 4777-4783 ◽

Cited By ~ 29

Author(s):

Suraj P. Narula ◽

Sukhjeevan Kaur ◽

Ravi Shankar ◽

Sushma Verma ◽

Paloth Venugopalan ◽

...

Keyword(s):

Crystal Structures ◽

Spectroscopic Characterization ◽

One Pot ◽

X Ray ◽

One Pot Synthesis

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Synthesis, Spectroscopic Characterization, and Structure of closo-1,10-B10H8F22- and Related Fluorinated Derivatives of B10H102-

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19971310 ◽

1997 ◽

Vol 62 (8) ◽

pp. 1310-1324 ◽

Cited By ~ 5

Author(s):

Sergei V. Ivanov ◽

Svetlana M. Ivanova ◽

Susie M. Miller ◽

Oren P. Anderson ◽

Nikolai T. Kuznetsov ◽

...

Keyword(s):

Nmr Spectroscopy ◽

Ir Spectroscopy ◽

Single Crystal ◽

Spectroscopic Characterization ◽

X Ray ◽

X Ray Crystallography ◽

Fluorinated Derivatives ◽

Derivatives Of

The treatment of salts of the B10H102- anion with the commercially available N-fluoro reagent 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (F-TEDA) resulted in the formation of fluorinated derivatives of this ten-vertex borane dianion. The effects of changing the solvent, temperature, and reagent stoichiometry were studied. The derivatives 1-B10H9F2-, 2-B10H9F2-, 1,2-B10H8F22-, 1,6-B10H8F22-, 1,10-B10H8F22-, and 1,2,10-B10H7F32- were examined by a combination of 11B and 19F NMR spectroscopy and by IR spectroscopy. The salt [Ph4P]2[1,10-B10H8F2] . 3 CH2Cl2 was structurally characterized by single-crystal X-ray crystallography: C51H48B10Cl6F2P2, monoclinic, C2/c, a = 13.8134(9), b = 19.141(1), c = 21.136(1) Å, β = 91.546(1)°, Z = 4, T = -100 °C, R = 0.077.

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