Synthesis, X-ray crystallography, thermogravimetric analysis and spectroscopic characterization of isostructural one-dimensional coordination polymers as sorbents for some anions

CrystEngComm ◽  
2018 ◽  
Vol 20 (13) ◽  
pp. 1783-1796 ◽  
Author(s):  
Bahram Ghanbari ◽  
Leila Shahhoseini ◽  
Agata Owczarzak ◽  
Maciej Kubicki ◽  
Reza Kia ◽  
...  
Keyword(s):  
Thermogravimetric Analysis ◽  
Coordination Polymers ◽  
Spectroscopic Characterization ◽  
One Dimensional ◽  
X Ray ◽  
X Ray Crystallography

A new series of coordination polymers capable of adsorbing anions have been synthesized by employing a dipyridine substituted diazacrown macrocycle as linker.

scholarly journals The Synthesis and Characterization of a Novel One-Dimensional Bismuth (III) Coordination Polymer as a Precursor for the Production of Bismuth (III) Oxide Nanorods

Crystals ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 113
Author(s):  
Younes Hanifehpour ◽  
Babak Mirtamizdoust ◽  
Jaber Dadashi ◽  
Ruiyao Wang ◽  
Mahboube Rezaei ◽  
...  
Keyword(s):  
Single Crystal ◽  
Coordination Compound ◽  
Organic Ligand ◽  
One Dimensional ◽  
X Ray ◽  
X Ray Crystallography ◽  
Oxide Nanorods ◽  
Pure Phase ◽  
3D Framework

A novel Bi (III) coordination compound, [Bi(HQ)(Cl)4]n ((Q = pyridine-4-carbaldehyde thiosemicarbazone), was prepared in this research using a sonochemical technique. SEM, infrared spectroscopy (IR), XRD, and single-crystal X-ray analysis were utilized to analyze the Bi(III) coordination compound. The structure determined using single-crystal X-ray crystallography indicates that the coordination compound is a 1D polymer in solid state and that the coordination number of bismuth (III) ions is six, (BiSCl5), with one S donor from the organic ligand and five Cl donors from anions. It is equipped with a hemidirectional coordination sphere. It is interesting that the ligand has been protonated in the course of the reaction with a Cl- ion balancing the charge. This compound’s supramolecular properties are directed and regulated by weak directional intermolecular interactions. Through π–π stacking interactions, the chains interact with one another, forming a 3D framework. Thermolysis of the compound at 170 °C with oleic acid resulted in the formation of pure phase nanosized Bi (III) oxide. SEM technique was used to examine the morphology and size of the bismuth (III) oxide product produced.

Synthesis, Characterization and Crystal Structure of Coordination Polymers Developed as Anion Receptor

2018 ◽  
Vol 273 ◽  
pp. 134-139
Author(s):  
M.A. Kadir ◽  
Christopher J. Sumby
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Cadmium Nitrate ◽  
Two Dimensional ◽  
Anion Receptor ◽  
Slow Evaporation ◽  
One Dimensional ◽  
X Ray ◽  
X Ray Crystallography ◽  
Good Potential

Reaction of diamide ligand, namelyN,N’-2,6-bis (4-pyridylmethyl) pyridine dicarboxamide (L) with cadmium nitrate and cadmium perchlorate has given rise to the formation of two types coordination polymers. Compound (CP1-Cd) with formula molecule {[Cd (L)2(H2O)2](NO3)2·6H2O}nis a one-dimensional coordination polymer while compound (CP2-Cd), with formula molecule {[Cd (L)2(H2O)2](ClO4)2·31⁄2H2O.CH3OH}n, is a two dimensional coordination polymer. These coordination polymers were preparedviaslow evaporation methods and completely characterized by combination of solid state techniques such as Fourier Transform Infrared (FTIR) spectroscopy, elemental analysis and X-ray crystallography. This study revealed that coordination polymers derived fromN,N’-2,6-bis (4-pyridylmethyl) pyridine dicarboxamide can accommodate anions with different sizes, showing good potential as anion receptor.

scholarly journals Solvothermal Synthesis, Crystal Structure, and Characterization of a Heterometallic Iodoplumbate

Crystals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 305
Author(s):  
Le-Qing Fan ◽  
Xiao-Tong Zhu
Keyword(s):  
Crystal Structure ◽  
Thermogravimetric Analysis ◽  
Solvothermal Synthesis ◽  
Solvothermal Reaction ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
Design And Synthesis ◽  
Yellow Compound

The design and synthesis of heterometallic iodoplumbates have attracted much interest due to the diverse structures and significant physical properties. A Pb/CuI/I heterometallic iodoplumbate, [PbCu2I4(bipy)]n (1) (bipy = 2,2′-bipyridine), has been synthesized by solvothermal reaction of PbI2, Cu(NO3)2, bipy, and HI, and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, and thermogravimetric analysis. This compound exhibits one-dimensional neutral structure, which is built upon the linkages of Pb/I chains, Cu/I chains, and Cu(bipy) units. The yellow compound has an optical bandgap of 2.32 eV and shows fluorescent emission at 610 nm which is assigned to iodide-to-copper charge transfer.

scholarly journals Structural features and near infra-red (NIR) luminescence of isomeric Yb(iii) bipyridyl-N,N′-dioxide coordination polymers

2015 ◽  
Vol 44 (29) ◽  
pp. 13378-13383 ◽  
Author(s):  
Gail M. Sequeira ◽  
Wayne Y. Tan ◽  
Evan G. Moore
Keyword(s):  
Coordination Polymers ◽  
Structural Characterization ◽  
Lanthanide Complexes ◽  
Structural Features ◽  
X Ray ◽  
X Ray Crystallography ◽  
Infra Red ◽  
Nir Luminescence

The synthesis and structural characterization of a series of lanthanide complexes formed from YbX3 salts (X = NO3− or CF3SO3−) and the isomeric 4,4′-bipyridine-N,N′-dioxide (4,4′-bpdo) or 3,3′-bipyridine-N,N′-dioxide (3,3′-bpdo) ligands has been undertaken by X-ray crystallography.

Preparation, Crystal Structure and Spectroscopic Characterization of [Ga(OH)(SO4)(terpy)(H2O)] · H2O (terpy=2,2’:6’,2-Terpyridine): The First Characterized Gallium(III) Sulfato Complex

2004 ◽  
Vol 59 (3) ◽  
pp. 291-297 ◽  
Author(s):  
Andreas Sofetis ◽  
Giannis S. Papaefstathiou ◽  
Aris Terzis ◽  
Catherine P. Raptopoulou ◽  
Theodoros F. Zafiropoulos
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Nmr Spectroscopy ◽  
Good Yield ◽  
Spectroscopic Data ◽  
Spectroscopic Characterization ◽  
X Ray ◽  
X Ray Crystallography ◽  
H Nmr

The reaction of Ga2(SO4)3·18H2O and excess 2,2′:6′,2″-terpyridine (terpy) in MeOH / H2O leads to [Ga(OH)(SO4)(terpy)(H2O)]·H2O (1·H2O] in good yield. The structure of the complex has been determined by single-crystal X-ray crystallography. The GaIII atom in 1·H2O is 6-coordinate and ligation is provided by one terdentate terpy molecule, one monodentate sulfate, one terminal hydroxide and one terminal H2O molecule; the coodination polyhedron about the metal is described as a distorted octahedron. There is an extensive hydrogen-bonding network in the crystal structure which generates corrugated layers parallel to bc. The new complex was characterized by IR and 1H NMR spectroscopy. The spectroscopic data are discussed in terms of the nature of bonding

Cadmium Carboxylate Chemistry: Preparation, Crystal Structure, and Thermal and Spectroscopic Characterization of the One-dimensional Polymer [Cd(O2CMe)(O2CPh)(H2O)2]n

2003 ◽  
Vol 58 (11) ◽  
pp. 1045-1054 ◽  
Author(s):  
Theocharis C. Stamatatos ◽  
Eugenia Katsoulakoua ◽  
Vassilios Nastopoulos ◽  
Catherine P. Raptopoulou ◽  
Evy Manessi-Zoupa ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Spectroscopic Characterization ◽  
One Dimensional ◽  
X Ray Crystallography ◽  
Anhydrous Compound ◽  
Trigonal Prismatic Coordination ◽  
The One ◽  
Trigonal Prismatic ◽  
Preparative Route

Compound [Cd(O2CMe)(O2CPh)(H2O)2]n (1) was initially obtained in a serendipitous way during efforts to prepare a CdII /PhCO2 −/bepy complex (bepy = 2-benzoylpyridine). With the identity of 1 established by single-crystal X-ray crystallography, a rational preparative route to this complex was designed and carried out by reacting Cd(O2CMe)2·2H2O with a slight excess of PhCOOH in MeCN under reflux. The crystal structure of 1 consists of isolated zig-zag chains. The CdII atom is coordinated to five carboxylate and two aqua oxygen atoms creating a distorted, capped trigonal prismatic coordination polyhedron. The acetate group exhibits the η1:η2:μ2 coordination mode, while the benzoate ligand is chelating. There is an extensive hydrogen-bonding network which reinforces the chains and also links them generating sheets. The new complex was characterized by IR, far-IR, Raman, CP MAS and solution 113Cd NMR spectroscopy. The spectroscopic data are discussed in terms of the nature of bonding and the known structure. An anhydrous compound with the empirical formula Cd(O2CMe)(O2CPh) was isolated during the thermal decomposition of 1; the vibrational study of this thermally stable intermediate supports an 1D polymeric structure with 6-coordinate CdII ions.

Confirmation of the Structure of Trans -Cyclic Azobenzene by X-Ray Crystallography and Spectroscopic Characterization of Cyclic Azobenzene Analogs

2018 ◽  
Vol 3 (9) ◽  
pp. 2697-2701 ◽  
Author(s):  
Meesook Jun ◽  
Dhruval K. Joshi ◽  
Ravi S. Yalagala ◽  
Jesse Vanloon ◽  
Razvan Simionescu ◽  
...  
Keyword(s):  
Spectroscopic Characterization ◽  
X Ray ◽  
X Ray Crystallography

Reaction between Yttrium Nitrate and 2,2':6',2"-Terpyridine (terpy) in MeCN: Preparation, Crystal Structures and Spectroscopic Characterization of [Y (NO3)3(terpy)(H2O )] and [Y(NO3)3(terpy)(H2O )] · terpy · 3 MeCN

2001 ◽  
Vol 56 (2) ◽  
pp. 122-128 ◽  
Author(s):  
Athanassios K. Boudalis ◽  
Vassilios Nastopoulos ◽  
Aris Terzis ◽  
Catherine P. Raptopoulou ◽  
Spyros P. Perlepes
Keyword(s):  
Oxygen Atom ◽  
Single Crystal ◽  
Crystal Structures ◽  
Spectroscopic Characterization ◽  
Yttrium Nitrate ◽  
X Ray ◽  
X Ray Crystallography ◽  
H Nmr ◽  
Tricapped Trigonal Prism

Abstract The reaction of Y(NO3)3 · 5H2O and 2,2':6',2"-terpyridine (terpy) in MeCN leads to [Y(N03 )3(terpy)(H2O )] (1) and [Y(N03 )3(terpy)(H2O )] terpy-3MeCN (2) in good yields depending on the isolation conditions. The structures of both complexes were determined by single-crystal X-ray crystallography. The YIII atom in 1 is 9-coordinate and ligation is provided by one terdentate terpy molecule, two chelating nitrates, one monodentate nitrate and one terminal H2O molecule; the coordination polyhedron about the metal may be viewed as a tricapped trigonal prism. The YIII atom in 2 is 10-coordinate and its coordination sphere consists of three nitrogen atoms from the terdentate terpy, six oxygen atoms from the three chelating nitrates (one of them being “anisobidentate”) and one oxygen atom from a terminal H2O molecule; the polyhedron about the metal may be viewed as a distorted sphenocorona. The interstitial terpy is strongly hydrogen-bonded to the O atom of the coordinated H2O molecule to form [Y(NO3 )3(terpy)(H20)] ··· terpy pairs. The new complexes were characterized by IR and 1H NMR spectroscopies. The YIII/NO3-/terpy chemistry is compared to the already well-developed LnIII/NO3-/terpy chemistry (Ln = lanthanide).

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