Synthesis, Crystal Structure and Luminescence Properties of the Inorganic-Organic Hybrid Compound [FTMA]2[CdI4] (FTMA = Ferrocenylmethyltrimethylammonium Cation)
The title compound [FTMA]2[CdI4] has been synthesized from [FTMA]I (ferrocenylmethyltrimethylammonium iodide) and 3CdSO4・8H2O and was characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The Cd(II) atom has a slightly distorted tetrahedral coordination sphere. In the solid state there are C-H・ ・ ・π interactions between adjacent ferrocenyl cations to generate a chain structure. The luminescence properties of the title compound were investigated in the solid state at room temperature
2013 ◽
Vol 68
(4)
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pp. 345-350
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