Lithium Uptake and the Accelerated Corrosion of Zirconium Alloys

Author(s):  
N Ramasubramanian ◽  
N Precoanin ◽  
VC Ling

Author(s):  
A. P. Ponomarev ◽  
L. G. Kolyada ◽  
E. V. Tarasyuk

Metal products are subjected to atmospheric corrosion during transportation and storing. An important way to prevent this negative phenomenon is application of special packing materials, in particular materials, containing volatile inhibitors of corrosion, which protect metal against various corrosion agents. To protect metal effectively it is necessary to provide a definite level of operating characteristics of packing materials. The purpose of the work was the study of operating properties of inhibited crepe, inhibited and laminated polyethylene film, inhibited crepe and reinforced by polypropylene web papers, manufactured by OJSC “PP TechnoKhim”, Magnitogorsk, used for packing of metals. Structural and dimensional, sorption, deformation and strength characteristics, of the studied anticorrosion papers are presented, the characteristics being calculated based on the results of measurements. To determine their physical-mechanical and anticorrosion properties, standard methods and methodologies were used. To evaluate impact of moisture and transportation conditions, indices of water adsorption and wear of the studied papers were determined. Inhibitor content in these materials was determined by thermogravimetric analysis method. Their protective ability was studied on samples of low carbon steel strip. For accelerated corrosion tests the strip samples were degreased by alcohol, dried in air and packed in the studied anticorrosion papers, after that they were exposed under increased temperatures and moisture conditions. It was determined, that among the materials under the study, the inhibited crepe paper, reinforced by polypropylene web, hhas the best complex of physical-mechanical and anticorrosion properties. It provides a higher level of prevention corrosion of metal l and surpasses other materials in a number of deformation and strength characteristics. Recommendations were proposed to improve qquality of produced anticorrosion papers.



Author(s):  
Shubham N. Dadgal ◽  
Shrikant Solanke

In modern days for structures in coastal areas it has been observed that the premature structural failures are occurs due to corrosion of the reinforcements of the designed structural member. The corrosion causes the structural damage which in turn leads to reduction in the bearing capacity of the concerned structural members. The aim of this study was to study the effect of partial replacement of fly ash to minimize the corrosion effect. Beams were designed and corroded by using artificial method known accelerated corrosion method. The beams were then tested for flexural and bond strength. Also the weight loss of the reinforced bars was been determined using electrical resistivity method. The fly ash will replace by 10% and 15%.The strength will calculate at varying percentage of corrosion at 10% and 15%. Beams will cast at M25 grade concrete. The flexural strength will test by using UTM and the bond strength will calculate using pullout test.



2020 ◽  
Vol 86 (8) ◽  
pp. 32-37
Author(s):  
V. V. Larionov ◽  
Xu Shupeng ◽  
V. N. Kudiyarov

Nickel films formed on the surface of zirconium alloys are often used to protect materials against hydrogen penetration. Hydrogen adsorption on nickel is faster since the latter actively interacts with hydrogen, oxidizes and forms a protective film. The goal of the study is to develop a method providing control of hydrogen absorption by nickel films during vacuum-magnetron sputtering and hydrogenation via measuring thermoEMF. Zirconium alloy E110 was saturated from the gas phase with hydrogen at a temperature of 350°C and a pressure of 2 atm. A specialized Rainbow Spectrum unit was used for coating. It is shown that a nickel film present on the surface significantly affects the hydrogen penetration into the alloy. A coating with a thickness of more than 2 μm deposited by magnetron sputtering on the surface of a zirconium alloy with 1% Nb, almost completely protects the alloy against hydrogen penetration. The magnitude of thermoemf depends on the hydrogen concentration in the zirconium alloy and film thickness. An analysis of the hysteresis width of the thermoEMF temperature loop and a method for determining the effective activation energy of the conductivity of a hydrogenated material coated with a nickel film are presented. The results of the study can be used in assessing the hydrogen concentration and, hence, corrosion protection of the material.



2014 ◽  
Vol 51 (9) ◽  
pp. 656-674 ◽  
Author(s):  
A. V. Flores ◽  
A. G. Gomez ◽  
G. A. Juarez ◽  
N. Loureiro ◽  
R. I. Samper ◽  
...  
Keyword(s):  




2001 ◽  
Author(s):  
Brian E. Placzankis ◽  
Chris E. Miller ◽  
Paul F. Buckley ◽  
John H. Beatty




Sign in / Sign up

Export Citation Format

Share Document