Physical properties and phase transitions of bis(guanidinium)zirconium bis(nitrilotriacetate)hydrate, [C(NH2)3]2Zr[N(CH2COO)3]2 · H2O

Author(s):  
E. Haussühl ◽  
E. Tillmanns

AbstractLarge single crystals of optical quality of bis(guanidinium)zirconium bis(nitrilotriacetate)hydrate have been grown from aqueous solutions. Complete elastic, thermoelastic and piezoelastic tensors have been determined by ultrasonic methods. In addition, the tensor of thermal expansion, refractive indices, dielectric and piezoelectric constants have been studied in the range between 210 K and 330 K. Most physical properties investigated show a strong anisotropy. The piezoelectric constant

Author(s):  
S. Haussühl ◽  
J. Schreuer

AbstractLarge single crystals of optical quality of betaine hydrogen dihydrogen iodate have been grown from aqueous solutions. An X-ray structure analysis yields space group


Author(s):  
J. Schreuer ◽  
T. Münch

AbstractLarge single crystals of optical quality of monoclinic ethylenediammonium bis(hydrogensuccinate) were grown from aqueous solutions. An X-ray structure analysis yielded space group


Author(s):  
S. Haussühl ◽  
J. Schreuer

AbstractLarge single crystals of optical quality of betaine hydrogen ammonium sulfate have been grown from aqueous solutions. An X-ray structure analysis yielded space group


Author(s):  
S. Haussühl ◽  
J. Schreuer

AbstractLarge single crystals of optical quality of (±)-tris(ethylenediamine)cobalt(III) nitrate have been grown from aequeous solutions. An X-ray structure analysis yielded space groupPyroelectric, dieletric, piezoelectric and elastic constants have been determined at room temperature. Additionally, we have studied the coefficients of thermal expansion and the thermoelastic constants in the range between 270 K and 350 K. The structure exhibits a nearly trigonal symmetry around the [unk]


1970 ◽  
Vol 33 (1) ◽  
pp. 47-54 ◽  
Author(s):  
S Ferdous ◽  
J Podder

Highly transparent and well faceted large size epsomite single crystals have been grown in pure form and doped with KCl from aqueous solutions by slow cooling and isothermal evaporation method. The optical quality of the epsomite improves on doping by KCl. Mass growth rates were found to increase with doping of lower concentrations of KCl and then decreases with the higher concentration of KCl. KCl doped epsomite crystal reveals that structures are slightly distorted due to adsorption of Cl- ion into the crystal lattice. DC conductivity along the growth axis for all of the grown crystals increases with temperature in the range of 25 to 70ºC and also increases with the KCl concentration. Dielectric constant is found to be almost independent of frequency up to range of 106Hz. The dielectric studies show the suitability of these grown crystals for optoelectronic applications. DOI: 10.3329/jbas.v33i1.2949 Journal of Bangladesh Academy of Sciences, Vol. 33, No. 1, 47-54, 2009


2005 ◽  
Vol 282 (3-4) ◽  
pp. 394-401 ◽  
Author(s):  
G. Bhagavannarayana ◽  
G.C. Budakoti ◽  
K.K. Maurya ◽  
B. Kumar

Author(s):  
Eiken Haussühl ◽  
Siegfried Haussühl ◽  
Ekkehart Tillmanns

AbstractSingle crystals of the title compounds having optical quality and dimensions up to 60 mm have been grown from aqueous solutions. X-ray crystal structure analyses of K


2000 ◽  
Vol 55 (11-12) ◽  
pp. 891-894 ◽  
Author(s):  
Z. Czapla ◽  
S. Dacko ◽  
B. Kosturek

Abstract Single crystals of pyridinium periodate were grown, and their physical properties were studied. Anomalies of the electric permittivity and birefringence were observed at TC1 = 321 K and TC2 = 211 K. These observations gave evidences for the existence of three phases denoted as I, II, and III. Hysteresis loops were observed both in phase II and III. Pyroelectric measurements showed two anomalies at TC1 and TC2 . The anomaly at TC1 is related to the transition between a para-and ferroelectric phase, and the anomaly at T cl to the transition between two ferroelectric phases.


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