Kerr Constant Measurement of Water- Acetone System and Molecular Structure in Solution

2012 ◽  
Vol 3 (4) ◽  
pp. 431-434
Author(s):  
R. K. KHANNA R. K. KHANNA ◽  
◽  
GEETA GARG
Keyword(s):  
Molecular Structure ◽  
Kerr Constant ◽  
Constant Measurement ◽  
Structure In Solution ◽  
Acetone System

Mixed-Oxidation Divanadium(IV,V) Compound with Ligand Asymmetry: Electronic and Molecular Structure in Solution and in the Solid State

1999 ◽  
Vol 38 (9) ◽  
pp. 1982-1988 ◽  
Author(s):  
Subodh Kanti Dutta ◽  
Satyabrata Samanta ◽  
Sujit Baran Kumar ◽  
Oc Hee Han ◽  
Pannee Burckel ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Solid State ◽  
Mixed Oxidation ◽  
Structure In Solution

Triferrocenylborane – Molecular Structure in Solution and in the Solid State

1995 ◽  
Vol 50 (2) ◽  
pp. 201-204 ◽  
Author(s):  
Bernd Wrackmeyer ◽  
Udo Dörfler ◽  
Wolfgang Milius ◽  
Max Herberhold
Keyword(s):  
Molecular Structure ◽  
Solid State ◽  
Low Temperature ◽  
Single Crystal ◽  
Nmr Spectra ◽  
The Other ◽  
X Ray ◽  
Single Diastereomer ◽  
Structure In Solution ◽  
C Nmr

According to a single crystal X-ray structure determination all three ferrocenyl substituents of triferrocenylborane (1) adopt the same orientation with respect to the BC3-plane [P21/c monoclinic; Z = 4; a = 1353.5(3), b = 1695.6(3), c = 1056.4(2) pm, β = 109.27(3)°]. The simulated X-ray powder pattern of the single crystal is identical with the powder diagram of a macroscopic sample, indicating the presence of a single diastereomer (1a) in the solid state. However, at low temperature (< - 95 °C) in solution, the 13C NMR spectra suggest the presence of the second diastereomer (1b) in which one ferrocenyl group is oriented opposite to the other two with respect to the central BC3-plane.

Étude structurale d'une imidazolylcétone l'isopropyl-1-phényl-2-diaza-1,3-one-6-bicyclo[3,3,0]octène-2

1990 ◽  
Vol 68 (12) ◽  
pp. 2192-2197
Author(s):  
Jean-Pierre Reboul ◽  
Pierre Brouant ◽  
Jacques Barbe ◽  
Claude Caranoni ◽  
Catherine Soula ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Crystal Structure ◽  
Nuclear Magnetic Resonance ◽  
Solid State ◽  
Magnetic Resonance ◽  
Resonance Spectroscopy ◽  
X Ray Diffraction ◽  
X Ray ◽  
Structure In Solution ◽  
State Configuration

The solid state configuration of 1-isopropyl-2-phenyl-1,3-diaza-6-one-bicyclo[3.3.0]oct-2-ene was determined from X-ray diffraction data (a = 10.039(3) Å; b = 8.683(3) Å; c = 15.505(6) Å; β = 90.72(9)°; P21/c;R = 0.047). This structure is compared to those of three other related (Δ-2)-imidazolines. Molecular structure in solution was investigated by 1H nuclear magnetic resonance spectroscopy. Results clearly indicate that the title compound has the same structure in the solid state as in solution. On the contrary, this configuration differs appreciably from those of other (Δ-2)-imidazolines considered in this report. Keywords: (Δ-2)-imidazolines, crystal structure, NMR, conformations.

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