scholarly journals Appearance of the Rebinder effect and "effect of adsorptive deployment of porous structure surface" during the coal-water fuel preparation

Author(s):  
V.S. Biletskiy ◽  
◽  
O.A. Krut ◽  
2019 ◽  
Author(s):  
Kazuki Morita ◽  
Ji-Sang Park ◽  
Sunghyun Kim ◽  
Kenji Yasuoka ◽  
Aron Walsh

The Aurivillius phases of complex bismuth oxides have attracted considerable attention due to their lattice polarization (ferroelectricity) and photocatalytic activity. We report a first-principles exploration of Bi<sub>2</sub>WO<sub>6</sub> and the replacement of W<sup>6+</sup> by pentavalent (Nb<sup>5+</sup>, Ta<sup>5+</sup>) and tetravalent (Ti<sup>4+</sup>, Sn<sup>4+</sup>) ions, with charge neutrality maintained by the formation of a mixed-anion oxyhalide sublattice. We find that Bi<sub>2</sub>SnO<sub>4</sub>F<sub>2</sub> is thermodynamically unstable, in contrast to Bi<sub>2</sub>TaO<sub>5</sub>F, Bi<sub>2</sub>NbO<sub>5</sub>F and Bi<sub>2</sub>TiO<sub>4</sub>F<sub>2</sub>. The electric dipoles introduced by chemical substitutions in the parent compound are found to suppress the spontaneous polarization from 61.55 μC/cm<sup>2</sup> to below 15.50 μC/cm<sup>2</sup>. Analysis of the trends in electronic structure, surface structure, and ionization potentials are reported. This family of materials can be further extended with control of layer thicknesses and choice of compensating halide species.<br>


2012 ◽  
Vol 27 (4) ◽  
pp. 798-805 ◽  
Author(s):  
Collin Hii ◽  
Øyvind W. Gregersen ◽  
Gary Chinga-Carrasco ◽  
Øyvind Eriksen ◽  
Kai Toven

Abstract This study shows that wet-pressing TMP and DIP with a shoe press pulse may yield similar afterpress solids, provided that an adequate shoe pulse length with similar pressure profile is applied. A wet web with more porous structure in the sheet dewatering (felt) layer seems to contribute to the increased dewatering during wet pressing. In addition, a shoe press pulse with high peak pressure at the end yields higher solids content after wet-pressing and higher bulk compared to a pulse with a peak pressure in the beginning. The increased dewatering during wet-pressing implies a reduction of steam consumption in the dryer.


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